Molecular structure and carrier dynamics at the interface betweenorganic semiconductor and insulator
| Project/Area Number |
22245001
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (A)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Physical chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
TAKEYA Junichi 大阪大学, 産業科学研究所, 教授 (20371289)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
WATANABE Kazuya 京都大学, 大学院・理学研究科, 准教授 (30300718)
NAKAI Ikuyo 京都大学, 大学院・理学研究科, 助教 (30446257)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥49,140,000 (Direct Cost: ¥37,800,000、Indirect Cost: ¥11,340,000)
Fiscal Year 2012: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Fiscal Year 2011: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2010: ¥33,410,000 (Direct Cost: ¥25,700,000、Indirect Cost: ¥7,710,000)
|
|---|
| Keywords | 有機半導体 / 表面・界面 / 非線形分光 / キャリアダイナミックス / 電界効果トランジスタ / 変調分光スペクトル / 正孔 / 電荷移動度 / ルブレン / 電場変調分光 / 和周波振動分光 / 多重反射 |
|---|
| Research Abstract |
It is vital to clarify the charge transfer mechanism in organic semiconductors. In this study, we explored the electronic structures of holes injected at the interface between organic semiconductor and insulator by charge modulation spectroscopy (CMS). We developed a method to apply CMS to opaque devices that cannot be probed by the conventional transmittance configuration. In addition, we found that the CM spectra of holes in DNTT thin film transistors depend on the alkyl chain length introduced both ends of the molecule. A theoretical analysis of the spectra allowed us to deduce a correlation between charge transfer probability and molecular configurations.
|
Report
(4 results)
Research Products
(37 results)
-
-
-
-
-
[Journal Article] High-performance organic transistors with high-k dielectrics: A comparative study on solution processedsingle crystals and vacuum-deposited polycrystalline films of 2,9-didecyldinaphtho[2,3- b:2' ,3'-f]thieno[3,2-b]thiophene2012
Author(s)
W. Ou-Yang, T. Uemura, K. Miyake, S. Onish, T. Kato, M. Katayama, M. Kang, K.Takimiya, M. Ikeda, H. Kuwabara, M. Hamada, and J. Takeya
-
Journal Title
Appl.Phys. Lett
Volume: 101
Issue: 22
Pages: 223304-5
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
[Presentation] 電荷変調分光による有機半導体・絶縁体界面に注入された正孔の非局在化の観察2013
Author(s)
宮田潔志, 田中駿介, 杉本敏樹, 渡邊一也, 三輪一元, 植村隆文, 姜明辰, 瀧宮和男, 桑原博一,濱田雅裕, 竹谷純一, 松本吉泰
Organizer
日本化学会
Place of Presentation
草津市
Year and Date
2013-03-22
Related Report
-
[Presentation] 電荷変調分光による有機半導体・絶縁体界面に注入された正孔の非局在化の観察2013
Author(s)
宮田 潔志, 田中駿介, 杉本敏樹, 渡邊 一也, 三輪 一元, 植村 隆文, 姜明辰, 瀧宮和男, 桑原博一, 濱田雅裕, 竹谷 純一, 松本 吉泰
Organizer
日本化学会年会
Place of Presentation
草津市
Related Report
-
[Presentation] ジナフトチエノチオフェン薄膜・絶縁体界面に注入されたホールの電子吸収スペクトルにおける分子集合構造依存性2012
Author(s)
宮田潔志, 石野雄太, 杉本敏樹, 渡邊一也,三輪一元, 植村隆文, 姜明辰, 瀧宮和男, 桑原博一, 濱田雅裕, 竹谷純一, 松本吉泰
Organizer
表面・界面スペクトロスコピー
Place of Presentation
吹田市
Year and Date
2012-12-07
Related Report
-
[Presentation] ジナフトチエノチオフェン薄膜トランジスタ中のキャリアの吸収スペクトルにおける分子集合構造の影響2012
Author(s)
宮田潔志, 石野雄太, 杉本敏樹, 渡邊一也,三輪一元, 植村隆文, 姜明辰, 瀧宮和男, 桑原博一,濱田雅裕, 竹谷純一, 松本吉泰
Organizer
分子科学討論会
Place of Presentation
東京都
Year and Date
2012-09-18
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
