A new aspect of in-situ powder x-ray diffraction technique by developing the high precision oscillating system for the sample under high pressure

• Project/Area Number: 22340164
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: National Institute for Materials Science
• Principal Investigator: YUSA Hitoshi 独立行政法人物質・材料研究機構, 先端材料プロセスユニット, 主幹研究員 (10343865)
• Co-Investigator(Kenkyū-buntansha): HIRAO Naohisa (公財)高輝度光科学研究センター, 利用研究促進部門, 研究員 (70374915)
• Co-Investigator(Renkei-kenkyūsha): OHISHI Yasuo (公財)高輝度光科学研究センター, 利用研究促進部門, 主幹研究員 (20344400)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000); Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2010: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
• Keywords: 鉱物物理 / X線回折技術 / 高圧物質科学 / X線結晶学 / 極限物性 / 高圧力科学

Research Abstract

A multi-axis oscillation system for a diamond anvil cell (DAC) is developed for the improvement of quality in X-ray powder diffraction profiles. The large opening conical DAC is also newly designed for the system. We installed and tested the system in the beam lines (BL04B2 and BL10XU) at SPring-8. The Gandolfi camera-like motion given for the sample in DAC contributes a drastic improvement for the statistics of the particles satisfying the Bragg condition.

Research Products

• [Journal Article] Perovskite to postperovskite transitions in NaNiF3 and NaCoF3, and disproportionation of NaCoF3 postperovskite under high pressure and high temperature (2012)
  • Author(s): H. Yusa, Y. Shirako, M. Akaogi, H. Kojitani, N. Hirao, Y. Ohishi, T. Kikegawa
  • Journal Title: Inorganic. Chemistry Volume: 12 Issue: 12 Pages: 6559-6566
  • DOI: 10.1021/ic300118d
  • Peer Reviewed
• [Journal Article] Synthesis of rhenium nitride crystals with MoS2 structure (2012)
  • Author(s): F. Kawamura, H. Yusa, T. Taniguchi
  • Journal Title: Applied Physics Letters Volume: 100 Issue: 25 Pages: 251910-251910
  • DOI: 10.1063/1.4729586
  • Peer Reviewed
• [Journal Article] 高圧実験と計算の協奏研究:セスキ酸化物の高密度高配位相探索 (2012)
  • Author(s): 遊佐 斉
  • Journal Title: マテリアルインテグレーション Volume: 25 Pages: 40-45
  • URL: http://www.tic-mi.com/publ/book.cgi?pg_1211
  • Peer Reviewed
• [Journal Article] A perovskitic lower mantle inferred from high-pressure, high-temperature sound velocity data (2012)
  • Author(s): Murakami, M., Ohishi, Y., Hirao, N., Hirose, K.
  • Journal Title: Nature Volume: 485 Issue: 7396 Pages: 90-94
  • DOI: 10.1038/nature11004
  • Peer Reviewed
• [Journal Article] Identification of superlattice structure cI16 of phosphorus P-VI phase at 340 Gpa (2012)
  • Author(s): T. Sugimoto, Y. Akahama, H. Fujihisa, Y. Ozawa, H. Fukui, N. Hirao, Y. Ohishi
  • Journal Title: Physical Review B Volume: 86
  • Peer Reviewed
• [Journal Article] 高圧実験と計算の協奏研究：セスキ酸化物の高密度高配位相探索 (2012)
  • Author(s): 遊佐 斉
  • Journal Title: マテリアルインテグレーション Volume: 25 Pages: 40-45
  • Peer Reviewed
• [Journal Article] Identification of superlattice structure cI16 of phosphorus P-VI phase at 340 GPa (2012)
  • Author(s): T. Sugimoto, Y. Akahama, H. Fujihisa, Y. Ozawa, H. Fukui, N. Hirao, Y. Ohishi
  • Journal Title: Physical Review B Volume: 86 Issue: 2 Pages: 24109-24109
  • DOI: 10.1103/physrevb.86.024109
  • Peer Reviewed
• [Journal Article] Phase transition of FeO and stratification in Earth's outer core (2011)
  • Author(s): H.Ozawa, F.Takahashi, K.Hirose, Y.Ohishi, N.Hirao
  • Journal Title: Science Volume: 334 Issue: 6057 Pages: 792-794
  • DOI: 10.1126/science.1208265
  • Peer Reviewed
• [Journal Article] Perovskite, LinbO3, corundum, and hexagonal polymorph of (In(1-x)M(x)MO(3)) (2011)
  • Author(s): A. A. Belik, T. Furubayashi, H. Yusa, E. Takayama-Muromachi
  • Journal Title: Journal of the American Chemical Society Volume: 133 Pages: 9405-9412
  • Peer Reviewed
• [Journal Article] Structural and electrical transport properties of FeHx under high- pressures and low-temperatures (2011)
  • Author(s): T. Matsuoka, N. Hirao, Y. Ohishi, K. Shimizu, A. Machida, K. Aoki
  • Journal Title: High Pressure Research Volume: 31 Issue: 1 Pages: 64-67
  • DOI: 10.1080/08957959.2010.522447
  • Peer Reviewed
• [Journal Article] Perovskite, LiNbO3, Corundum, and Hexagonal Polymorphs of (In1–xMx)MO3 (2011)
  • Author(s): A. A. Belik
  • Journal Title: Journal of the American Chemical Society Volume: 133 Issue: 24 Pages: 9405-9412
  • DOI: 10.1021/ja2010362
  • Peer Reviewed
• [Journal Article] 高水素中における金属水素化物の電気抵抗測定技術及び鉄水素化物の電気伝導特性と結晶構造 (2011)
  • Author(s): 松岡岳洋、平尾直久、大石泰生、清水克哉、町田晃彦、青木勝敏
  • Journal Title: 高圧力の科学と技術 Volume: 21 Pages: 190-196
  • Peer Reviewed
• [Journal Article] Compression of Fe88.1Ni9.1S2.8 alloy up to the pressure of Earth's inner core (2011)
  • Author(s): Sakai T., Ohtani E., Kamada S., Terasaki H., Hirao N.
  • Journal Title: Journal of Geophysical Research Volume: 117 Issue: B2 Pages: 7-7
  • DOI: 10.1029/2011jb008745
  • Peer Reviewed
• [Journal Article] Structural and electrical transport properties of FeHx under high-pressures and low-temperatures (2011)
  • Author(s): T.Matsuoka, N.Hirao, Y.Ohishi, K.Shimizu, A.Machida, K.Aoki
  • Journal Title: High Pressure. Research Volume: 31 Pages: 64-67
  • Peer Reviewed
• [Journal Article] Dense yttria phase eclipsing the A-type sesquioxide structure: high-pressure experiments and ab initio calculations (2010)
  • Author(s): H. Yusa, T. Tsuchiya, N. Sata, Y. Ohishi
  • Journal Title: Inorganic Chemistry Volume: 49 Issue: 10 Pages: 4478-4485
  • DOI: 10.1021/ic100042z
  • Peer Reviewed
• [Journal Article] Pressure-induced spin state transition in BiCoO3 (2010)
  • Author(s): K. Oka, M. Azuma, W. Chen, H. Yusa, A. A. Belik, E. Muromachi, J. Mizumaki, N. Ishimatsu, N. Hiraoka, M. Tsujimaoto, M. G. Tucker, Y. Shimakawa
  • Journal Title: Journal of the American Chemical Society Volume: 132 Pages: 9438-9443
  • Peer Reviewed
• [Journal Article] Liquidus and solidus temperatures of a Fe-O-S alloy up to the pressures of the outer core: Implication for the thermal structure of the Earth's core (2010)
  • Author(s): H. Terasaki, S. Kamada, T. Sakai, E. Ohtani, N. Hirao, Y. Ohishi
  • Journal Title: Earth and Planetary Science Letters Volume: 304 Pages: 559-564
  • Peer Reviewed
• [Journal Article] Thermoelastic properties of ice VII and its high-pressure polymorphs (2010)
  • Author(s): Y. Asahara, K. Hirose, Y. Ohishi, N. Hirao
  • Journal Title: Implications for dynamics of cold slab subduction in the lower mantle Volume: 299 Pages: 474-482
  • Peer Reviewed
• [Journal Article] Dense yttria phase eclipsing the A-type sesquioxide structure : high-pressure experiments and ab initio calculations (2010)
  • Author(s): H.Yusa, T.Tsuchiya, N.Sata, Y.Ohishi
  • Journal Title: Inorganic Chemistry Volume: 49 Pages: 4478-4485
  • Peer Reviewed
• [Journal Article] Pressure-induced spin state transition in BiCoO_3 (2010)
  • Author(s): K.Oka, M.Azuma, W.Chen, H.Yusa, A.A.Belik, E.Muromachi, J.Mizumaki, N.Ishimatsu, N.Hiraoka, M.Tsujimaoto, M.G.Tucker, Y.Shimakawa
  • Journal Title: Journal of the American Chemical Society Volume: 132 Pages: 9438-9443
  • Peer Reviewed
• [Journal Article] Liquidus and solidus temperatures of a Fe-O-S alloy up to the pressures of the outer core : Implication for the thermal structure of the Earth's core (2010)
  • Author(s): H.Terasaki, S.Kamada, T.Sakai, E.Ohtani, N.Hirao, Y.Ohishi
  • Journal Title: Earth and Planetary Science Letters Volume: 304 Pages: 559-564
  • Peer Reviewed
• [Journal Article] Thermoelastic properties of ice VII and its high-pressure polymorphs : Implications for dynamics of cold slab subduction in the lower mantle (2010)
  • Author(s): Y.Asahara, K.Hirose, Y.Ohishi, N.Hirao
  • Journal Title: Earth and Planetary Science Letters Volume: 299 Pages: 474-482
  • Peer Reviewed
• [Journal Article] X-ray diffraction studies on solid hydrogen at pressures up to 183 GPa : Evidence of orientational ordering in phase III (2010)
  • Author(s): Y.Akahama, M.Nishimura, H.Kawamura, N.Hirao, Y.Ohishi, K.Takemura
  • Journal Title: Physical Review Letters B Volume: 82 Pages: 60101-60101
  • Peer Reviewed
• [Journal Article] Fe-Mg partitioning between post-perovskite and ferropericlase in the lowermost mantle (2010)
  • Author(s): T.Sakai, E.Ohtani, H.Terasaki, M.Miyahara, M.Nishijima, N.Hirao, Y.Ohishi, N.Sata
  • Journal Title: Physics and Chemistry of Minerals Volume: 37 Pages: 487-496
  • Peer Reviewed
• [Presentation] NaMF3(M=Co,Ni)のポストペロブスカイト転移 (2012)
  • Author(s): 遊佐斉、白子雄一、赤荻正樹、 糀谷浩、平尾直久、大石泰生、 亀掛川卓美
  • Organizer: 第53回高圧討論会
  • Place of Presentation: 大阪大学会館(大阪市)
  • Year and Date: 2012-11-09
• [Presentation] DAC粉末X線回折における試料の多軸揺動効果 (2012)
  • Author(s): 遊佐斉、平尾直久、大石泰生、森嘉久、瀬戸雄介
  • Organizer: 第53回高圧討論会
  • Place of Presentation: 大阪大学会館(大阪市)
  • Year and Date: 2012-11-08
• [Presentation] 高圧下複分解反応における窒化タングステン結晶合成 (2012)
  • Author(s): 川村史朗、遊佐斉、谷口尚
  • Organizer: 第53回高圧討論会
  • Place of Presentation: 大阪大学会館(大阪市)
  • Year and Date: 2012-11-07
• [Presentation] Recent progresses in high-pressure research with diamond-anvil cell at SPring-8 (2012)
  • Author(s): N. Hirao, Y. Ohishi
  • Organizer: Joint 2012 COMPRES Annual Meeting & High-Pressure Mineral Physics Seminar 8 (HPMPS8)
  • Place of Presentation: Lake Tahoe, CA (USA)
  • Year and Date: 2012-07-09
• [Presentation] DAC多軸揺動X線回折装置の開発 (2012)
  • Author(s): 遊佐斉、平尾直久、大石泰生、森嘉久
  • Organizer: 日本地球惑星連合 2012年大会
  • Place of Presentation: 幕張メッセ国際会議場(千葉市)
  • Year and Date: 2012-05-20
• [Presentation] Pressure-induced magnetic transition in iron hydride (2012)
  • Author(s): N.Hirao, Y.Ohishi, T.Mitsui, T.Matsuoka
  • Organizer: Joint symposium Misasa-2012 and Geofluid-2
  • Place of Presentation: ブランナールみささ(三朝町)(招待講演)
  • Year and Date: 2012-03-22
• [Presentation] 鉄水素化物のメスバウワー分光-金属格子の膨張による強磁性の復活 (2012)
  • Author(s): 平尾直久
  • Organizer: 第25回日本放射光学会年会・放射光科学合同シンポジウム
  • Place of Presentation: 鳥栖市民文化会館(鳥栖市)(招待講演)
  • Year and Date: 2012-01-07
• [Presentation] DAC多軸揺動X線回折装置の開発 (2012)
  • Author(s): 遊佐 斉、平尾直久、大石泰生、森 嘉久
  • Organizer: 日本地球惑星連合 2012年大会
  • Place of Presentation: 幕張メッセ国際会議場（千葉市）
• [Presentation] DAC粉末X線回折における試料の多軸揺動効果 (2012)
  • Author(s): 遊佐 斉、平尾直久、大石泰生、森 嘉久、瀬戸雄介
  • Organizer: 第53回高圧討論会
  • Place of Presentation: 大阪大学会館(大阪市）
• [Presentation] NaMF3(M=Co,Ni)のポストペロブスカイト転移 (2012)
  • Author(s): 遊佐斉、白子雄一、赤荻正樹、 糀谷浩、平尾直久、大石泰生、 亀掛川卓美
  • Organizer: 第53回高圧討論会
  • Place of Presentation: 大阪大学会館(大阪市）
• [Presentation] Recent progresses in high-pressure research with diamond-anvil cell at SPring-8 (2012)
  • Author(s): N. Hirao, Y. Ohishi
  • Organizer: Joint 2012 COMPRES Annual Meeting & High-Pressure Mineral Physics Seminar-8 (HPMPS8)
  • Place of Presentation: Lake Tahoe, CA (USA)
  • Invited
• [Presentation] 高圧下X線回折用ガンドルフィカメラ型揺動装置の開発 (2011)
  • Author(s): 遊佐斉、平尾直久、大石泰生、森嘉久
  • Organizer: 平成23年度日本結晶学会年会
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2011-11-24
• [Presentation] 重希土類セスキ酸化物における高圧下逐次相転移の再考 (2011)
  • Author(s): 遊佐斉、土屋卓久、平尾直久、大石泰生、亀掛川卓美
  • Organizer: 第52回高圧討論会
  • Place of Presentation: 沖縄キリスト教学院(那覇市)
  • Year and Date: 2011-11-11
• [Presentation] 高圧X線回折・エネルギードメイン放射光57鉄メスバウアー分光同時測定システムの開発 (2011)
  • Author(s): 平尾直久、大石泰生、三井隆也、松岡岳洋、増田亮、境毅、大谷栄治
  • Organizer: 第52回高圧討論会
  • Place of Presentation: 沖縄キリスト教学院(那覇市)
  • Year and Date: 2011-11-11
• [Presentation] 巨大な体積変化を伴うBiCo3の構造相転移 (2011)
  • Author(s): 岡研吾、東正樹、陳威廷、辻本将彦、島川祐一、遊佐斉、Alexei Belik,水牧仁一朗、石松直樹、平岡望、Mattew Tucker, Paul Attfield
  • Place of Presentation: 沖縄キリスト教学院(那覇市)
  • Year and Date: 2011-11-11
• [Presentation] 粉末X線回折用DAC多軸揺動装置の開発 (2011)
  • Author(s): 遊佐斉、平尾直久、大石泰生、森嘉久
  • Organizer: 第52回高圧討論会
  • Place of Presentation: 沖縄キリスト教学院(那覇市)
  • Year and Date: 2011-11-09
• [Presentation] 高圧下複分解反応による新規5d遷移金属窒化物合成 (2011)
  • Author(s): 川村史朗、遊佐斉、谷口尚
  • Organizer: 第52回高圧討論会
  • Place of Presentation: 沖縄キリスト教学院(那覇市)
  • Year and Date: 2011-11-09
• [Presentation] Structural, magnetic and electrical properties of iron-hydride (2011)
  • Author(s): N.Hirao, Y.Ohishi, T.Matsuoka, T.Mitsui, K.Takemura, K.Shimizu, A.Machida, K.Aoki
  • Organizer: XXII Congress and General Assembly of the IUCr (IUCr 2011)
  • Place of Presentation: Municipal Conference Centre (Madrid, SPAIN)(招待講演)
  • Year and Date: 2011-08-25
• [Presentation] 希土類セスキ酸化物の高圧相転移 (2011)
  • Author(s): 遊佐斉、亀掛川卓美、土屋卓久
  • Organizer: 第28回PFシンポジウム
  • Place of Presentation: つくば国際会議場(つくば市)
  • Year and Date: 2011-07-13
• [Presentation] High-Pressure Raman Study of Al14N and Al15N Epitaxial Thin Films on Sapphire Substrates (2010)
  • Author(s): H. Yusa, T. Ohgaki, N. Ohashi, I. Sakaguchi, H. Haneda
  • Organizer: ICC3 3rd International Congress on Ceramics
  • Place of Presentation: International Convention Center (Osaka)
  • Year and Date: 2010-11-16
• [Presentation] High-Pressure Raman Study of Al14N and Al15N Epitaxial Thin Films on Sapphire Substrates (2010)
  • Author(s): H.Yusa, T.Ohgaki, N.Ohashi, I.Sakaguchi, H.Haneda
  • Organizer: ICC3 3^<rd> International Congress on Ceramics
  • Place of Presentation: 大阪市(大阪府)
  • Year and Date: 2010-11-16
• [Presentation] イットリア(Y2O3)の新高密度高圧相 (2010)
  • Author(s): 遊佐斉,土屋卓久,佐多永吉,大石泰生
  • Organizer: 第51回高圧討論会
  • Place of Presentation: 戦災復興記念館(仙台市)
  • Year and Date: 2010-10-21
• [Presentation] イットリア(Y2O3)の新高密度高圧相 (2010)
  • Author(s): 遊佐斉, 土屋卓久, 佐多永吉, 大石泰生
  • Organizer: 第51回高圧討論会
  • Place of Presentation: 仙台市(宮城県)
  • Year and Date: 2010-10-21
• [Presentation] 強磁性hcp-FeHxの高圧合成と磁気転移 (2010)
  • Author(s): 平尾直久・大石泰生・三井隆也・松岡岳洋・瀬戸誠・青木勝敏・竹村謙一・山上浩志
  • Organizer: 第51回高圧討論会
  • Place of Presentation: 仙台市(宮城県)
  • Year and Date: 2010-10-21
• [Presentation] Energy-domain synchrotron radiation Mossbauer spectroscopy in the multimegabar pressure range and its application to Fe (2010)
  • Author(s): N.Hirao, T.Mitsui, Y.Ohishi, M.Seto
  • Organizer: 2010 IUCr-HP Meeting
  • Place of Presentation: Gatlinburg (USA)
  • Year and Date: 2010-09-23
• [Presentation] High-pressure phase transitions in Bi-based perovskites (2010)
  • Author(s): H. Yusa, A. A. Belik, E. Muromachi, N. Hirao, Y. Ohishi
  • Organizer: 48th EHPRG Conference 2010
  • Place of Presentation: Uppsala (Sweden)
  • Year and Date: 2010-07-27
• [Presentation] Synthesis and characteristics of hcp iron hydride at high pressure (2010)
  • Author(s): N.Hirao, Y.Ohishi, T.Mitsui, T.Matsuoka, M.Seto, K.Aoki, K.Takemura, H.Yamagami
  • Organizer: International symposium on metal-hydrogen systems MH 2010
  • Place of Presentation: Moscow (Russia)
  • Year and Date: 2010-07-21
• [Patent(Industrial Property Rights)] 六方晶窒化タングステンの合成方法 (2013)
  • Inventor(s): 川村史朗、遊佐斉、谷口尚
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2013-023983
  • Filing Date: 2013-02-12
• [Patent(Industrial Property Rights)] 六方晶窒化タングステンの合成方法及び六方晶窒化タングステン (2012)
  • Inventor(s): 川村史朗、遊佐斉、谷口尚
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-226541
  • Filing Date: 2012-10-12
• [Patent(Industrial Property Rights)] X線回析試料揺動装置、X線回析装置及びX線回析パターンの測定方法 (2011)
  • Inventor(s): 遊佐斉
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 2011-225394
  • Filing Date: 2011-10-13
• [Patent(Industrial Property Rights)] 高窒素含有遷移金属窒化物の製造方法及び高窒素含有遷移金属窒化物 (2011)
  • Inventor(s): 川村史朗、谷口尚、遊佐斉、櫻井裕也
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 2011-155185
  • Filing Date: 2011-07-13
• [Patent(Industrial Property Rights)] 高窒素含有遷移金属窒化物の製造方法及び高窒素含有遷移金属窒化物 (2011)
  • Inventor(s): 川村史郎、谷口尚、遊佐斉、櫻井裕也
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 2011-155185
  • Filing Date: 2011-07-13
• [Patent(Industrial Property Rights)] 硫化ガドリニウム型酸化イットリウム及びその製造法 (2010)
  • Inventor(s): 遊佐斉
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 2010-089993
  • Filing Date: 2010-04-09
• [Patent(Industrial Property Rights)] 硫化ガドリニウム型酸化イットリウム及びその製造方法 (2010)
  • Inventor(s): 遊佐斉
  • Industrial Property Rights Holder: 物質・材料研究機構(潮田資勝)
  • Industrial Property Number: 2010-089993
  • Filing Date: 2010-04-09