• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

New Generation Stimuli-Responsive Polymers: Various Thermosensitive polymers and Alternating Copolymers with Highly Selective Acid-Degradability

Research Project

Project/Area Number 22350051
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionOsaka University

Principal Investigator

AOSHIMA Sadahito  大阪大学, 大学院・理学研究科, 教授 (50183728)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2012: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywordsリビングカチオン重合 / 自然調和型材料 / 温度応答性ポリマー / ブロックポリマー / 交互型ポリマー / 抗菌活性ポリマー / 精密分解ポリマー / 温度応答性フィルム / 刺激応答性ポリマー / 自然調和型ポリマー / 精密分解型ポリマー / リビング重合開始剤系 / ビニルエーテル / スチレン類 / スマートフィルム / グラフトポリマー / 星型ポリマー / モノマー選択重合 / リビング開始剤系 / UCST型相分離 / 含Fビニルエーテルの重合 / 交互型リビングポリマー / ケミカルリユース
Research Abstract

The precision synthesis via living cationic polymerization has created new thermosensitive polymers exhibiting an upper critical solution temperature-type phase separation in water or various organic solvents. The antibacterial and hemolytic activities were examined using a series of amphiphilic block copolymers with amino side groups. The controlled alternating copolymerization of vinyl ethers and various aldehydes was also achieved under appropriate reaction conditions, to produce copolymers with highly selective acid-degradability. Furthermore, highly effective and facile one-step synthesis of star-shaped polymers was demonstrated.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report

Research Products

(104 results)

All 2014 2012 2011 2010 Other

All Journal Article (42 results) (of which Peer Reviewed: 42 results) Presentation (51 results) (of which Invited: 2 results) Book (6 results) Remarks (5 results)

  • [Journal Article] Well-Defined Polymeric Ionic Liquids with an Upper Critical Solution Temperature in Water2012

    • Author(s)
      H. Yoshimitsu, A. Kanazawa, S. Kanaoka, and S. Aoshima
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 9427-9434

    • DOI

      10.1021/ma301746u

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure Effects of Lewis Acids on the Living Cationic Polymerization of pMethoxystyrene: Distinct Difference in Polymerization Behavior from Vinyl Ethers2012

    • Author(s)
      A. Kanazawa, S. Shibutani, N. Yoshinari, T.Konno, S. Kanaoka, and S. Aoshima
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 7749-7757

    • DOI

      10.1021/ma301505j

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Biologically Synthesized or Bioinspired Process-Derived Iron Oxides as Catalysts for Living Cationic Polymerization of Vinyl Ether2012

    • Author(s)
      A. Kanazawa, S. Kanaoka, N. Yagita, Y.Oaki, H. Imai, M. Oda, A. Arakaki, T. Matsunaga, and S. Aoshima
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 10904-10906

    • DOI

      10.1039/c2cc36218j

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Domino Synthesis of Star-Shaped Polymers Based on Monomer Selective Living Cationic Polymerization: Highly Controlled Star Polymer Formation2012

    • Author(s)
      S. Kanaoka, M. Yamada, J. Ashida, A.Kanazawa, and S. Aoshima
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 50 Pages: 4589-4593

    • DOI

      10.1002/pola.26304

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Degradable Alternating Copolymers from Naturally Occurring Aide hydes : Well-defined Cationic Copolymerization and Complete Degradation2012

    • Author(s)
      Yasushi Ishido, Arihiro Kanazawa, Shykyoku Kanaoka, Sadahito Aoshima
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 4060-4068

    • DOI

      10.1021/ma3004828

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Acid-Specific Polymerization Behaviors in Living Cationic Polymerization of Vinyl Ether with a Malonate Group2012

    • Author(s)
      Y. Oda, T. Tsujino, S. Kanaoka, and S.Aoshima
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 50 Pages: 2993-2998

    • DOI

      10.1002/pola.26088

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Copolymerization of 1,1-Diphenylethylene with p-Substituted Styrenes2012

    • Author(s)
      Kosaku Yasuoka
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 50 Pages: 2758-2761

    • DOI

      10.1002/pola.26073

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Synthesis of Heteroarm Star-Shaped Polymers using Polymer-Linking Reaction and Their Characteristic Stimuli-Responsive Behaviors2012

    • Author(s)
      Y.Oda, T.Shibata, H.Tsujimoto, S.Kanaoka, S.Aoshima
    • Journal Title

      Polym. J.

      Volume: 44(印刷中)(未定) Pages: 541-549

    • DOI

      10.1038/pj.2012.23

    • NAID

      10030599046

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precision Synthesis of Polar-Functional Star-Shaped Polymers by Fast Living Cationic Polymerization2012

    • Author(s)
      織田ゆか里
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 69 Issue: 6 Pages: 291-296

    • DOI

      10.1295/koron.69.291

    • NAID

      10030772951

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermo-Responsive Films Obtained from Various Block Copolymers by Living Cationic Polymerization: Smart Films with Various Transition Patterns2012

    • Author(s)
      瀧下大貴
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 69 Issue: 6 Pages: 300-304

    • DOI

      10.1295/koron.69.300

    • NAID

      10030772975

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design and Synthesis of Thermo-Responsive Films with High Sensitivity: Effects of Primary Architectures of Diblock Copolymers and Conditions for Film Formation2012

    • Author(s)
      瀧下大貴
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 69 Issue: 6 Pages: 305-308

    • DOI

      10.1295/koron.69.305

    • NAID

      10030772993

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Graft Copolymers Based on Selective Living Cationic Polymerization Using an Acetal Group with a Combination of Lewis Acids2012

    • Author(s)
      Hiroaki Shimomoto
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 50 Pages: 3703-3709

    • DOI

      10.1002/pola.26186

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis of End-Functionalized Thermosensitive Poly(vinyl ether)s by Living Cationic Polymerization2012

    • Author(s)
      Hiroaki Shimomoto
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 50 Pages: 4137-4144

    • DOI

      10.1002/pola.26219

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Addition Polymerization of 1,4-Dioxene Using GaCl3 as Lewis Acid Catalyst: Long-Lived Species-Mediated Polymerization2012

    • Author(s)
      Kyohei Uchigami
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem.

      Volume: 50 Pages: 4571-4578

    • DOI

      10.1002/pola.26271

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Cationic Polymerization of Vinyl Ethers with a Naphthyl Group: Decisive Effect of the Substituted Position on Naphthalene Ring2012

    • Author(s)
      Yu Shinke
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 50 Pages: 5041-5048

    • DOI

      10.1002/pola.26347

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Separation Dynamics of Aqueous Poly[2-(2-ethoxy)ethoxyethyl vinyl ether] Solutions as Explored using the Laser T-Jump Technique Combined with Photometry2012

    • Author(s)
      Y.Tsuboi, K.Kikuchi, N.Kitamura, H.Shimomoto, S.Kanaoka, S.Aoshima
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 213 Pages: 374-381

    • DOI

      10.1002/macp.201100540

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Fluorine-Containing Star-Shaped Poly(vinyl ether)s via Arm-Linking Reactions in Living Cationic Polymerization2012

    • Author(s)
      H.Shimomoto, D.Fukami, T.Irita, K.Katsukawa, T.Nagai, S.Kanaoka, S.Aoshima
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 50 Pages: 1547-1555

    • DOI

      10.1002/pola.25922

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リビングカチオン重合による温度応答性フィルムの創製:様々な応答パターンを有するスマートフィルム2012

    • Author(s)
      瀧下大貴, 青島貞人, ら
    • Journal Title

      高分子論文集

      Volume: 69(印刷中)(未定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高速リビングカチオン重合による極性官能基を有する星型ポリマーの精密合成2012

    • Author(s)
      織田ゆか里, 青島貞人, ら
    • Journal Title

      高分子論文集

      Volume: 69(印刷中)(未定)

    • NAID

      10030772951

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高感度温度応答性フィルムの創製:ブロックコポリマー構造設計およびフィルム作成条件の影響2012

    • Author(s)
      瀧下大貴, 青島貞人, ら
    • Journal Title

      高分子論文集

      Volume: 69(印刷中)(未定)

    • NAID

      10030772993

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective Living Cationic Polymerization of Vinyl Ether with a Potential Chelating Function : Lewis Acid-Specific Polymerization Behaviors2012

    • Author(s)
      Y.Oda, S.Aoshima, et al
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 50(in press)(未定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Block versus Random Amphiphilic Copolymers as Antibacterial Agents2011

    • Author(s)
      Y.Oda, S.Kanaoka, S.Aoshima, K.Kuroda
    • Journal Title

      Biomacromolecules

      Volume: 12 Pages: 3581-3591

    • DOI

      10.1021/bm200780r

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetoresponsive On-Demand Release of Hybrid Liposomes Formed with Fe_3O_4, Nanoparticles and Thermosensitive Block Copolymers2011

    • Author(s)
      K.Katagiri, S.Aoshima, et al
    • Journal Title

      Small

      Volume: 7 Pages: 1683-1689

    • DOI

      10.1002/smll.201002180

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorinated Vinyl Ether Homopolymers and Copolymers : Living Cationic Polymerization and Temperature-Induced Solubility Transitions in Various Organic Solvents Including Perfluoro Solvents2011

    • Author(s)
      H.Shimomoto, S.Aoshima, et al
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 49 Pages: 2051-2058

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Cationic Polymerization of Vinyl Ether with a Lewis Acid/Acetylacetone Initiating System-The Role of Acetylacetone as a Protogen and a Ligand2011

    • Author(s)
      金岡鐘局, 青島貞人, ら
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 68 Issue: 5 Pages: 349-351

    • DOI

      10.1295/koron.68.349

    • NAID

      130004489330

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterogeneous Living Cationic Polymerization of Vinyl Ether Using a Heteropoly Acid2011

    • Author(s)
      金岡鐘局, 青島貞人, ら
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 68 Issue: 4 Pages: 176-181

    • DOI

      10.1295/koron.68.176

    • NAID

      130004489309

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Polymerization of .BETA.-Methylstyrenes2011

    • Author(s)
      安岡幸作, 青島貞人, ら
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 68 Issue: 7 Pages: 517-519

    • DOI

      10.1295/koron.68.517

    • NAID

      130004489343

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multi-Functional Liposomes Having Temperature-Triggered Release and Magnetic Resonance Imaging for Tumor-Specific Chemotherapy2011

    • Author(s)
      K.Kono, S.Aoshima, et al.
    • Journal Title

      Biomaterials

      Volume: 32 Pages: 1387-1395

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorine Containing Vinyl Ether Poiymers : Living Cationic Polymerization in Fluorinated Solvents as New Media and Unique Solubility Characteristics in Organic Solvents2011

    • Author(s)
      H.Shimomoto, S.Aoshima, et al.
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 49 Pages: 1174-1182

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorinated Vinyl Ether Homopolymers and Copolymers : Living Cationic Polymerization and Temperature-Induced Solubility Transitions in Various Organic Solvents Including Perfluoro Solvents2011

    • Author(s)
      H.Shimomoto, S.Aoshima, et al.
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 49(in press) Pages: 2051-2058

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ヘテロポリ酸によるビニルエーテルの不均一リビングカチオン重合2011

    • Author(s)
      金岡鐘局, 青島貞人, ら
    • Journal Title

      高分子論文集

      Volume: 68(in press)

    • NAID

      10028221793

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetoresponsive On-Demand Release of Hybrid Liposomes Formed with Fe_3 O_4 Nanoparticles and Thermosensitive Block Copolymers2011

    • Author(s)
      K.Katagiri, S.Aoshima, et al.
    • Journal Title

      Small

      Volume: 7(in press 未定)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chain Multiplying Controlled Cationic Polymerization of Isobutyl Vinyl Ether Using Pyrrole: Increment of Propagating Chains by Efficient "Initiator-Like"Transfer Agent"2010

    • Author(s)
      A. Kanazawa, S. Kanaoka, and S. Aoshima
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 3682-3689

    • DOI

      10.1021/ma100182b

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Well-Defined Alternating Copolymers of Benzaldehydes with Vinyl Ethers: Precision Synthesis by Cationic Copolymerization and Quantitative Degradation to Cinnamaldehydes2010

    • Author(s)
      Y. Ishido, R. Aburaki, S. Kanaoka, and S. Aoshima
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 3141-3144

    • DOI

      10.1021/ma902840d

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Cationic Polymerization of Vinyl Ether with Methanol/Metal Chloride Initiating Systems : Relationship between Polymerization Behavior and the Nature of Lewis Acids2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 2739-2747

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Well-Defined Alternating Copolymers of Benzaldehydes with Vinyl Ethers : Precision Synthesis by Cationic Copolymerization and Quantitative Degradation to Cinnamaldehydes2010

    • Author(s)
      Y.Ishido, S.Aoshima, et al.
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 3141-3144

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlled Cationic Copolymerization of Benzaldehyde with Isobutyl Vinyl Ether Using Base-Assisting System2010

    • Author(s)
      Y.Ishido, S.Aoshima, et al.
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 48 Pages: 1838-1843

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chain Multiplying Cotrolled Cationic Polymerization of lsobutyl Vinyl Ether Using Pyrrole : Increment of Propagating Chains by Efficient "Initiator-Like" Transfer Agent2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 3682-3689

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Polymerization of Isobutyl Vinyl Ether Using Alcohols Both as Cationogen and Catalyst-Modifying Reagent : Effect of Lewis Acids and Alcohols on Living Nature2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 48 Pages: 2509-2516

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Temperatur-Sensitive Liposomes Based on a Thermosensitive Block Copolymer, for Tumor-Specific Chemotherapy2010

    • Author(s)
      K.Kono, S.Aoshima, et al.
    • Journal Title

      Biomaterials

      Volume: 31 Pages: 7096-7105

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Stepping Stone to Stereospecific Living Cationic Polymerization : Cationic Polymerization of Vinyl Ethers Using Iron(II) Sulfate2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem.

      Volume: 48 Pages: 3702-3708

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent Progress in Living Cationic Polymerization of Vinyl Ethers2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Journal Title

      Chemistry Letters

      Volume: 39 Pages: 1232-1237

    • NAID

      10027468055

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 新しい手法を用いたリビングカチオン重合による星型ポリマーの精密合成2014

    • Author(s)
      織田ゆか里、青島貞人, ら
    • Organizer
      高分子ゲル研究討論会
    • Place of Presentation
      東大山上会館(東京都)
    • Year and Date
      2014-01-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] Monomer-Selective Living Cationic Polymerization for Precision Synthesis of Block Copolymers and Star Polymers via Seamless Domino-type Reaction2012

    • Author(s)
      S. Kanaoka, M. Yamada, R. Kimura, J.Ashida, A. Kanazawa, and S. Aoshima
    • Organizer
      The 9th SPSJ International Polymer Conference (IPC2012)
    • Place of Presentation
      Kobe
    • Year and Date
      2012-12-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 水/有機層間を移動可能なフッ素セグメントをコアとする高分子ミセルの創製及び層間シャトルへの試み2012

    • Author(s)
      山中悠司,金澤有紘,金岡鐘局,青島貞人
    • Organizer
      第61回高分子討論会,名古屋工業大学
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] リビングカチオン重合によるビニルエーテルとスチレン誘導体のブロック共重合体の精密合成およびそのフィルム表面特性2012

    • Author(s)
      吉崎友哉,金澤有紘,金岡鐘局,青島貞人
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学,名古屋
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 酸分解型結合を交互に配列した温度応答性ポリマーの精密合成及びその選択的分解2012

    • Author(s)
      松本涼香, 石堂泰志, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2012-05-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 新しいリビングカチオン重合および刺激応答性ポリマーの精密合成2012

    • Author(s)
      青島貞人, ら
    • Organizer
      高分子学会東海シンポジウム
    • Place of Presentation
      名古屋国際会議場(愛知県)(招待講演)
    • Year and Date
      2012-01-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Fluorine-Containing Star-Shaped Polymers by Living Cationic Polymerization and Unique Temperature-Induced Solubility Transitions in Various Organic Solvents2011

    • Author(s)
      H.Shimomoto, S.Aoshima, et al
    • Organizer
      12th Pacific Polymer Conference
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2011-11-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Fluorinated Vinyl Ether Polymers and Characteristics of Their Surface Properties2011

    • Author(s)
      T.Irita, S.Aoshima, et al
    • Organizer
      12th Pacific Polymer Conference
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Star-Shaped Polymers with Amino and Carboxy Groups by Living Cationic Polymerization and Their Stimuli-Responsive Behaviors2011

    • Author(s)
      Y.Oda, S.Aoshima, et al
    • Organizer
      12th Pacific Polymer Conference
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 星型ポリマーの簡易ワンステップ精密合成法 モノマー選択性を用いたドミノ合成2011

    • Author(s)
      山田麻友香, 芦田淳, 金岡鐘局, 青島貞人
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 星型ポリマーの簡易ワンステップ精密合成法2011

    • Author(s)
      山田麻友香、青島貞人, ら
    • Organizer
      第60回高分子学会討論会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Fluorine-Containing Star-Shaped Polymers by Living Cationic Polymerization2011

    • Author(s)
      H.Shimomoto, S.Aoshima, et al
    • Organizer
      第60回高分子学会討論会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fluorine-Containing Vinyl Ether Polymers : Precision Synthesis and Ucst-Type Phase Separation2011

    • Author(s)
      S.Kanaoka, S.Aoshima, et al
    • Organizer
      242^<nd> ACS National Meeting
    • Place of Presentation
      Denver (USA)
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] Degradable Alternating Copolymers from Plant-Derived Aldehydes with Vinyl Ethers : Precision Synthesis and Selective Acid Hydrolysis2011

    • Author(s)
      Y.Ishido, S.Aoshima, et al
    • Organizer
      242^<nd> ACS National Meeting
    • Place of Presentation
      Denver (USA)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Self-Assembly of Block Copolymers with a UCST-Type Thermoresponsive Segment2011

    • Author(s)
      H.Yoshimitsu, S.Aoshima, et al
    • Organizer
      242^<nd> ACS National Meeting
    • Place of Presentation
      Denver (USA)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Novel Methods for Star Polymers Synthesis by Living Cationic Polymerization2011

    • Author(s)
      K.Ono, S.Aoshima, et al
    • Organizer
      242^<nd> ACS National Meeting
    • Place of Presentation
      Denver (USA)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Stimuli Responsive Films Obtained from Various Block and Heteroarm Star Copolymers : Smart Films Exhibiting Multistep Thermosensitivity2011

    • Author(s)
      H.Takishita, S.Aoshima, et al
    • Organizer
      242^<nd> ACS National Meeting
    • Place of Presentation
      Denver (USA)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of Initiating Systems for Living Cationic Polymerization and Synthesis of Various Stimuli-Responsive Polymers2011

    • Author(s)
      S. Aoshima and S. Kanaoka
    • Organizer
      International Symposium on Ionic Polymerization (IP'11)
    • Place of Presentation
      Akron, USA
    • Year and Date
      2011-07-11
    • Related Report
      2012 Final Research Report
  • [Presentation] Development of Initiating Systems for Living Cationic Polymerization and Synthesis of Various Stimuli-Responsive Polymers2011

    • Author(s)
      S.Aoshima, et al
    • Organizer
      IUPAC International Symposium on Ionic Polymerization
    • Place of Presentation
      Akron (USA)(招待講演)
    • Year and Date
      2011-07-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 新規リビングカチオン重合系の開拓および刺激応答性ポリマーの精密合成2011

    • Author(s)
      青島貞人
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 一次構造の設計による様々な新規刺激応答性フィルムの創製-多段階の刺激応答性を示すフィルム-2011

    • Author(s)
      瀧下大貴, 辻本浩行, 金岡鐘局, 青島貞人
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 新規リビングカチオン重合系の開拓および刺激応答性ポリマーの精密合成2011

    • Author(s)
      青島貞人
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)(招待(受賞)講演)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 一次構造の設計による様々な新規刺激応答性フィルムの創製2011

    • Author(s)
      瀧下大貴、青島貞人, ら
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Precision Synthesis of Degradable Alternating Copolymers from Naturally Occurring Aldehydes with Vinyl Ethers2011

    • Author(s)
      Y.Ishido, S.Aoshima, et al
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Well-Defined Multibranched Polymers by Base-Assisting Living Cationic Polymeri-zation : Selective Synthesis of Star and Flower-shaped Polymers of Vinyl Ethers2010

    • Author(s)
      S.Kanaoka, S.Aoshima, et al.
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Metal Oxides for Green Precision polymer Synthesis Liveing Cationic Polymerization and Other Possibilities2010

    • Author(s)
      A.Kanazawa, S.Aoshima, et al.
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Series of Stimuli Responsive Polymers with Various Shapes and Different Sequence Distributions2010

    • Author(s)
      S.Aoshima, et al.
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precision Synthesis of Copolymers of Benzaldehydes and Their Complete Degradation to Conjugated Aldehydes : Controlled and Alternating Cationic Copolymerization of Benzaldehyde Derivatives with Vinyl Ether2010

    • Author(s)
      S.Kanaoka, S.Aoshima, et al.
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Series of Stimuli-Responsive Polymers with Various Shapes and Different Sequence Distributions2010

    • Author(s)
      S. Aoshima and S. Kanaoka
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-07
    • Related Report
      2012 Final Research Report
  • [Presentation] リビングカチオン重合による種々の両親媒性ポリマーの合成: 抗菌活性制御のための分子設計2010

    • Author(s)
      織田ゆか里, L. M. Thoma, 黒田賢一, 金岡鐘局, 青島貞人
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学, 札幌
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 水溶液中でUCST型相分離を示す温度応答性ポリマーの精密合成2010

    • Author(s)
      吉満隼人, 金岡鐘局, 青島貞人
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学, 札幌
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of Various pH-Responsive Polymers Having Naphthalene Rings and Acid Pendants by Living Cationic Polymerization2010

    • Author(s)
      Y.Shinke, S.Aoshima, et al.
    • Organizer
      Macro 2010
    • Place of Presentation
      Glasgow(UK)
    • Year and Date
      2010-07-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Controlled Cationic Polymerization of Benzaldehyde Derivatives with Vinyl Ethers : Evolutionary Chemical Cycle of Precision Synthesis and Complete Degradation Another Aldehyde Monomer2010

    • Author(s)
      Y.Ishido, S.Aoshima, et al.
    • Organizer
      Macro 2010
    • Place of Presentation
      Glasgow(UK)
    • Year and Date
      2010-07-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Initiating Systems for Living Cationic Polymerization and Synthesis of Stimuli-Responsive Polymers2010

    • Author(s)
      S.Aoshima, et al.
    • Organizer
      Inaugural International Conference on Molecular & Functional Catalysis(ICMFC-1)
    • Place of Presentation
      Singapore(Singapore)(招待講演)
    • Year and Date
      2010-07-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新しいリビングカチオン重合および刺激応答性ポリマーの合成2010

    • Author(s)
      青島貞人, ら
    • Organizer
      10-1高分子学会講演会
    • Place of Presentation
      九州大学(福岡県)(招待講演)
    • Year and Date
      2010-07-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新しいリビングカチオン重合-開始剤系の進化と刺激応答性ポリマーの新設計-2010

    • Author(s)
      青島貞人, ら
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川県)(招待講演)
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precision Synthesis of Fluorine-Containing Vinyl Ether Polymers and Study of Their Surface Properties

    • Author(s)
      Sadahito Aoshima
    • Organizer
      IUPAC World Polymer Congress
    • Place of Presentation
      Virginia, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of Thermo-Responsive Fluorine-Containing Polymers and Their Application

    • Author(s)
      Sadahito Aoshima
    • Organizer
      20th Intetrnational Symposium on Fluorine Chemistry 2012
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Annual Research Report
  • [Presentation] Monomer-Selective Living Cationic Polymerization for Precision Synthesis of Block Copolymers and Star Polymers via Seamless Domino-Type Reaction

    • Author(s)
      Sadahito Aoshima
    • Organizer
      The 9th SPSJ International Polymer Conference
    • Place of Presentation
      Kobe
    • Related Report
      2012 Annual Research Report
  • [Presentation] Design of Degradable Alternating Copolymers with Functional Groups by Controlled Cationic Polymerization

    • Author(s)
      Sadahito Aoshima
    • Organizer
      The 9th SPSJ International Polymer Conference
    • Place of Presentation
      Kobe
    • Related Report
      2012 Annual Research Report
  • [Presentation] Precise Synthesis of Alternating Copolymers by Controlled Cationic Polymerization of Aldehyde and Vinyl Ether: Dual Responsive Polymer with Thermosensitivity and Selective Acid Degradability

    • Author(s)
      Sadahito Aoshima
    • Organizer
      The 9th SPSJ International Polymer Conference
    • Place of Presentation
      Kobe
    • Related Report
      2012 Annual Research Report
  • [Presentation] リビングカチオン重合開始剤系の開拓と刺激応答性ポリマーの精密合成

    • Author(s)
      青島貞人
    • Organizer
      触媒学会重合触媒設計研究会セミナー
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 精密重合法の開拓および新規刺激応答性材料の設計・合成

    • Author(s)
      青島貞人
    • Organizer
      高分子学会九州支部フォーラム
    • Place of Presentation
      福岡
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 側鎖にアミノ基ないしカルボキシ基を交互に有するポリマーの合成および選択的分解

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 植物由来アルデヒドとビニルエーテルの制御カチオン交互共重合-側鎖構造の共重合に及ぼす影響

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 種々のルイス酸触媒を用いたp-メトキシスチレンのカチオン重合 -リビング重合可能な金属塩化物触媒系の設計

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] UCST型およびLCST型セグメントを有する二重温度応答性ブロックコポリマーの精密合成と水中における自己組織化挙動

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高選択的重合開始反応を用いた精密ポリマー構造変換 -ポリマー中アセタール基からのリビングカチオン重合による選択的合成-

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] ケミカルリサイクルに向けた酸分解性交互共重合体の制御カチオン重合による合成およびその刺激応答挙動

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水/有機層間を移動可能なフッ素セグメントをコアとする高分子ミセルの創製及び層間シャトルへの試み

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] アルキル置換ベンゼン誘導体を用いた開始剤系によるβ-ピネンおよびビニルシクロヘキサンの制御カチオン重合:モノマーの反応性に適した開始剤系の設計

    • Author(s)
      青島貞人
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Book] Cationic Polymerization of Polar Monomers2012

    • Author(s)
      S. Kanaoka and S. Aoshima
    • Total Pages
      7750
    • Related Report
      2012 Final Research Report
  • [Book] Well-Defined FluorineContaining Star Polymers of Vinyl Ethers: Precision Synthesis by Base-Assisting Living Cationic Polymerization and Thermoresponsive Solubility Transitions2012

    • Author(s)
      S. Kanaoka, H. Shimomoto, D. Fukami, and S. Aoshima
    • Total Pages
      224
    • Related Report
      2012 Final Research Report
  • [Book] カチオン重合2012

    • Author(s)
      青島貞人, 金岡鐘局
    • Total Pages
      138
    • Publisher
      共立出版
    • Related Report
      2012 Final Research Report
  • [Book] Polymer Science: A Comprehensive Reference, Vol. 32012

    • Author(s)
      Shokyoku Kanaoka
    • Publisher
      Elsevier BV
    • Related Report
      2012 Annual Research Report
  • [Book] Advances in Fluorine-Containing Polymers2012

    • Author(s)
      Shokyoku Kanaoka
    • Total Pages
      224
    • Publisher
      ACS Books
    • Related Report
      2012 Annual Research Report
  • [Book] Comprehensive Polymer Science : Cationic Polymerization of Polar Monomers2012

    • Author(s)
      S.Kanaoka, S.Aoshima
    • Publisher
      Elsevier(分担、in press)(未定)
    • Related Report
      2011 Annual Research Report
  • [Remarks] 青島貞人, 高分子学会賞(科学部門), "新規リビングカチオン重合系の開拓および刺激応答性ポリマーの精密合成", 高分子学会, 2011年5月26日

    • Related Report
      2012 Final Research Report
  • [Remarks] ホームページ

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 青島研究室ホームページ

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2011 Annual Research Report
  • [Remarks] 研究内容研究成果のURL

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-22   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi