Synthesis of unusual conducting nano-ribbons by catenating non-planar singlet biradicals
Project/Area Number |
22350058
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials chemistry
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
ITO Shigekazu 東京工業大学, 大学院・理工学研究科, 准教授 (00312538)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
|
Keywords | 電気 / 磁気的機能 / 一重項ビラジカル / 複素環化学 / 結晶構造 / 有機エレクトロニクス / 電気・磁気的機能 / 電気化学 / 超分子 / 有機元素化学 / 複素環構造 / 酸化還元特性 / 有機典型元素化学 / 静電相互作用 / 結晶構造解析 / 電荷移動錯体 |
Research Abstract |
Highly stabilized localized biradicals composed of the four-membered phosphorus heterocycle skeleton possess three-dimensional characteristics and exhibit remarkably high electron-donating ability. In this project we examined molecular design and synthesis of oligo(biradicals) using catenation of the P-heterocyclic biradical units, which induces through-space electrostatic intramolecular interaction. Characterization of the corresponding mixed-valent radical cations upon oxidation was also performed.
|
Report
(4 results)
Research Products
(38 results)
-
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Intensive NMR Study of 1-t-Buty1-3-methy1-2,4-bis(2,4,6-tri-t-butylphenyl)-1,3-diphosphacyclobutane'2,4-diyl2011
Author(s)
M.Yoshifuji, S.T.Osborn, A.J.Arduengo, III, K.A.Belmore, S.Ito
-
Journal Title
Heteroat.Chem
Volume: 22
Pages: 331-338
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-