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Development of organic integrated circuit by patterning of p-type/n-type properties in monolithic organic semiconductor material

Research Project

Project/Area Number 22350084
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

AOYAMA Tetsuya  独立行政法人理化学研究所, 内山元素化学研究室, 専任研究員 (50342738)

Project Period (FY) 2010-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2010: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Keywords有機半導体素子 / 有機トランジスタ / チエノキノイド / 量子化学計算
Outline of Final Research Achievements

Organic devices with a quinoidal oligothiophene derivative (QQT(CN)4) have been developed and the structure-property relationship in organic semiconductor has been investigated. A simple and versatile solution-processing method based on molecular self-assembly was used to fabricate one dimensional organic single crystal microwires of QQT(CN)4. The single crystal microwires exhibited excellent ambipolar transport properties. The molecular packing plays a key-role in a large range of organic optoelectronics devices. A combination of X-ray diffraction technique, atomic force microscopy, quantum chemical calculation and transistor characterization could provide significant insights into the interplay between molecular packing and charge transport properties in organic thin films.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (26 results)

All 2015 2014 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results,  Open Access: 2 results) Presentation (19 results) (of which Invited: 3 results)

  • [Journal Article] Ambipolar organic field-effect transistors based on solution-processed single crystal microwires of a quinoidal oligothiophene derivative2015

    • Author(s)
      J. C. Ribierre, L. Zhao, S. Furukawa, T. Kikitsu, D. Inoue, A. Muranaka, K. Takaishi, T. Muto, S. Matsumoto, D. Hashizume, M. Uchiyama, P. Andre, C. Adachi, T. Aoyama
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 27 Pages: 5836-5839

    • DOI

      10.1039/c4cc09608h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Influence of the grain orientation on the charge transport properties of organic field-effect transistors2014

    • Author(s)
      J. C. Ribierre, Y. Yokota, M. Sato, A. Ishizuka, T. Tanaka, S. Watanabe, M. Matsumoto, A. Muranaka, S. Matsumoto, M. Uchiyama, T. Aoyama
    • Journal Title

      RSC Adv.

      Volume: 4 Issue: 69 Pages: 36729-36737

    • DOI

      10.1039/c4ra04964k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Non-volatile organic memory with sub-millimetre bending radius2014

    • Author(s)
      R. H. Kim, H. J. Kim, I. Bae, S. K. Hwang, D. B. Velusamy, S. M. Cho, K. Takaishi, T. Muto, D. Hashizume, M. Uchiyama, P. Andre´, F. Mathevet, B. Heinrich, T. Aoyama, D. E. Kim, H. Lee, J. C. Ribierre, C. Park
    • Journal Title

      Nature Commun.

      Volume: - Issue: 1 Pages: 1-12

    • DOI

      10.1038/ncomms4583

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Influence of gate dielectric on the ambipolar characteristics of solution-processed organic field-effect transistors2011

    • Author(s)
      J. C. Ribierre, S. Ghosh, K. Takaishi, T. Muto, T. Aoyama
    • Journal Title

      Journal of Physics D : Applied Physics

      Volume: 44 Issue: 20 Pages: 205102-205102

    • DOI

      10.1088/0022-3727/44/20/205102

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Flexible organic field-effect transistors and complementary inverters based on a solution-processable quinoidal oligothiophene derivative2011

    • Author(s)
      J. C. Ribierre, K. Takaishi, T. Muto, T. Aoyama
    • Journal Title

      Optical Materials

      Volume: 33 Issue: 9 Pages: 1415-1418

    • DOI

      10.1016/j.optmat.2011.03.015

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thickness Dependence of the Ambipolar Charge Transport Properties in Organic Field-Effect Transistors based on a Quinoidal Oligothiophene Derivative2011

    • Author(s)
      J. C. Ribierre, S. Watanabe, M. Matsumoto, T. Muto, D. Hashizume, T. Aoyama
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 115 Issue: 42 Pages: 20703-20709

    • DOI

      10.1021/jp206129g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Flexible organic field-effect transistors and complementary inverters based on a solution-processable quinoidal oligothiophene derivative

    • Author(s)
      Jean-Charles RIBIERRE
    • Journal Title

      Optical Materials

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機半導体材料における分子パッキング制御と光電子デバイスへの応用2014

    • Author(s)
      青山哲也
    • Organizer
      平成26年度理研シンポジウム「有機エレクトロニクスの実用化に向けた次世代製造技術」
    • Place of Presentation
      理化学研究所(埼玉県和光市)
    • Year and Date
      2014-12-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Control of molecular packing and grain orientation for organic optoelectronic devices2014

    • Author(s)
      T. Aoyama
    • Organizer
      The 14th International Symposium on Advanced Organic Photonics (ISAOP-14)
    • Place of Presentation
      大阪大学銀杏会館(大阪府吹田市)
    • Year and Date
      2014-11-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] フレキシブルなチエノキノイド半導体薄膜におけるラビングによる分子パッキング構造制御2014

    • Author(s)
      青山哲也, 横田裕基, 橋爪大輔, 高石和人, 内山真伸, Pascal Andre, 田中利彦, 松本真哉, Jean-Charles Ribierre
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analysis of molecular packing and carrier transport in bisazomethine dye derivatives by X-ray diffraction and quantum chemical calculations2014

    • Author(s)
      T. Aoyama, Y. Yokota, B.-S. Kim, T. Tanaka, D. Hashizume, A. Muranaka, M. Uchiyama, J. C. Ribierre, S. Matsumoto
    • Organizer
      22nd International Conference for Science and Technology of Synthetic Metals (ICSM 2014)
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-07-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] チエノキノイド薄膜トランジスタにおける両極性電荷輸送特性の膜厚依存性と分子パッキング構造2012

    • Author(s)
      青山哲也, 渡邉智, 松本睦良, 橋爪大輔, 石塚亜弥, 松本真哉, 武藤豪志, 高石和人, 村中厚哉, 内山真伸, J. C. Rjbierre
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of the optical and charge transport properties of a solution-processable quinoidal oligothiophene derivative2011

    • Author(s)
      J. C. Ribierre, O. P. M. Gaudin, K. Takaishi, P. Andrd, T. Fujihara, T. Muto, M. Uchiyama, T. Aoyama
    • Organizer
      The 7th International Conference on Advanced Materials and Devices (ICAMD2011)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-12-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Optical and charge transport properties of a solution-processable low band gap quinoidal oligothiophene derivative2011

    • Author(s)
      J. C. Ribierre, T. Aoyama
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      Gyeongju, Korea
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Reversible p-n conversion and logic gates based on a solution-processible thienoquinoid semiconductor2011

    • Author(s)
      T. Aoyama, T. Fujihara, T. Muto, K. Takaishi, A. Nakao, S. Watanabe, M. Matsumoto, S. Matsumoto, S. Inoue, A. Muranaka, D. Hashizume, M. Uchiyama, J. C. Ribierre
    • Organizer
      The 11th European Conference on Molecular Electronics (ECME2011)
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Role of the film morphology on the ambipolar charge transport properties of a quinoidal oligothiophene derivative2011

    • Author(s)
      J. C. Ribierre, T. Fujihara, S. Watanabe, M. Matsumoto, T. Muto, K. Takaishi, A. Nakao, S. Matsumoto, S. Inoue, A. Muranaka, D. Hashizume, M. Uchiyama, T. Aoyama
    • Organizer
      The 2011 Spring Meeting of the European Mater. Res. Soc. (E-MRS), the Int. Conf. on Adv. Mater. (ICAM) of the Int. Union of Mater. Res. Soc. (IUMRS)
    • Place of Presentation
      Nice, France
    • Year and Date
      2011-05-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] チエノキノイド半導体における加熱・溶媒処理によるリバーシブルp-n変換2010

    • Author(s)
      青山 哲也
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎県長崎市
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Direct laser writing of solution-processed organic CMOS logic circuits and p-n microstructures2010

    • Author(s)
      Jean-Charles RIBIERRE
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      京都府京都市
    • Year and Date
      2010-07-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Carrier transport properties and quantum chemical calculations in ambipolar organic thin film transistors

    • Author(s)
      T. Aoyama, Y. Yokota, A. Muranaka, A. Ishizuka, M. Sato, T. Tanaka, D. Hashizume, T. Muto, K. Takaishi, M. Uchiyama, S. Matsumoto, J. C. Ribierre
    • Organizer
      E-MRS 2013 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Study of exciton diffusion in a solution-processable low bandgapquinoidaloligothiophene derivative using femtosecond transient absorption measurements

    • Author(s)
      H. -Y. Shin, J. H. Woo, M. J. Kwon, M. Barthelemy, M. Vomir, T. Muto, T. Takaishi, M. Uchiyama, D. Hashizume, T. Aoyama, D. -W. Kim, S. Yoon, J. -Y. Bigot, J. W. Wu, J. C. Ribierre
    • Organizer
      E-MRS 2013 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Quantum chemical calculations and photoresponses in bisazomethine dye ambipolar thin film transistors

    • Author(s)
      T. Aoyama
    • Organizer
      The 13th International Symposium on Advanced Organic Photonics (ISAOP-13)
    • Place of Presentation
      Kingston, Canada
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機トランジスタにおけるambipolar輸送特性の量子化学計算による検討

    • Author(s)
      青山哲也, 横田裕基,村中厚哉,石塚亜弥,田中利彦,橋爪大輔,武藤豪志,高石和人,内山真伸,ジーン・チャールズリビエル,松本真哉
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都, 日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] Thermally Induced Majority Carriers Conversion Kinetics in Quinoidal Thiophene

    • Author(s)
      L. Mazur, F. Mathevet, A. -J. Attias, K. Matczyszyn, M. Samoc, J. W. Wu, K. Takaishi, T. Muto, M. Uchiyama, T. Aoyama, J. C. Ribierre
    • Organizer
      12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
    • Place of Presentation
      Auckland, NewZealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] Analysis by quantum chemical calculations on ambipolar organic thin film transistors

    • Author(s)
      T. Aoyama, Y. Yokota, A. Muranaka, A. Ishizuka, T. Tanaka, D. Hashizume, T. Muto, K. Takaishi, M. Uchiyama, S. Matsumoto, J. C. Ribierre
    • Organizer
      12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
    • Place of Presentation
      Auckland, NewZealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] Control of Molecular Alignment and Transport Properties of Bisazomethine Dye Thin-Film Transistors

    • Author(s)
      Y. Yokota, B. -S. Kim, A. Ishizuka, M. Sato, J. C. Ribierre, T. Tanaka, A. Muranaka, M. Uchiyama, S. Matsumoto, T. Aoyama
    • Organizer
      12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
    • Place of Presentation
      Auckland, NewZealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] ビスアゾメチン色素誘導体を用いたトランジスタにおける分子配向と輸送特性の相関

    • Author(s)
      横田裕基, Byung-Soon Kim,橋爪大輔,Jean-Charles Ribierre,田中利彦,村中厚哉,内山真伸,松本真哉,青山哲也
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      相模原, 日本
    • Related Report
      2013 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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