Preparation and Characterization of Novel Luminescent Transition-MetalComplexes Bearing Sulfanenitrile Ligand
| Project/Area Number |
22550045
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nihon University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 有機化学 / 有機元素化学 / 錯体化学 / 光発光 / 硫黄?窒素化学 / 硫黄-窒素化学 |
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| Research Abstract |
(1) Syntheses and Photophysical Properties of noble Mixed Ligand Pt(II) Complexes: The heteroleptic complexes, [Pt(N^N)(1)]X_2 [N^N = 1,10-phenanthroline (phen) (2),4,7-diphenyl- phenanthroline (bathophen) (3); X = PF_6 (a) and ClO_4 (b)] and [Pt(C^N)(ndsdsd)]X [C^N= 2-phenylpyridine (ppy) (4) and benzo[h]quinoline (bzq) (5); X = PF_6 (a) and ClO_4 (b)] were prepared,and the molecular structures of 2?5 were characterized. Complexes 2 and 3a are very weaklyluminescent in solution, whereas they show highly emissive in the solid state (Φ_em = 0.11?0.27).(2) Syntheses and Photophysical Properties of Pd Complexes Containing a Disulfanenitrile Ligand: Thehomoleptic complex, [Pd(1)_2]Cl_2 (6) and the heteroleptic complexes, [Pd(diimine)(1)]Cl_2 (diimine:2,2’-bipyridine (7), 1,10-phenanthroline (8), and 4,7-diphenyl-1,10-phenanthroline (9)) were prepared,and the molecular structures of 6?9 were characterized. The complexes 7?8 are not emissive at ambient temperature in the solid state, but the homoleptic complex 6 shows an unstructured emission bond (λ_max = 690 nm).
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Report
(4 results)
Research Products
(21 results)
