| Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
Tungsten and Molybdenum complexes with novel ligands containing group 14 elements (i.e., the combination of carbon-silicon or carbon-germanium atoms) were synthesized. Their molecular structures were determined by X-ray crystal analyses, revealing interesting bonding nature. The dynamic behaviors in solution such as interconversion with isomers and intramolecular ligand-site exchange processes were clarified. Their reactions with various reagents were investigated to elucidate new reactivities.
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