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Synthesis and Control of Oxide Nanoparticle Formation Process from Amine Complex with Dialysis Process and Formation of Integrated Structure.

Research Project

Project/Area Number 22550178
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionChiba University

Principal Investigator

UEKAWA Naofumi  千葉大学, 大学院・工学研究科, 准教授 (60282448)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsセラミックス / ナノ粒子 / 溶液中合成 / 透析 / 酸化亜鉛 / 薄膜 / 配向 / 酸化チタン / 層状複水酸化物 / Al-ドープZnO / Nbドープ / 解膠 / 硫化物蛍光体
Research Abstract

Valence controlled TiO_2 nanoparticles and ZnO nanoparticles can be used as transparent electroconductive materials and UV shielding materials. They also show photocatalytic activity. In order to improve these characteristics, it is important issue to control orientation of the crystallites in sintered compacts and thin films. Stable dispersion of the oxide nanoparticles in solution is essentially important to obtain uniform thins films.
In this study, valence controlled TiO_2 nanoparticles and ZnO nanoparticles were prepared by solution process with low temperature heating process. Furthermore, the nanoparticle formation process was carried out in a cellulose tube. The dialysis processes with cellulose tube enabled to obtain the oxide nanoparticles with stable dispersion in a aqueous solution since the formation and growth process was occurred with reducing the impurity ions by dialysis process.Furthermore, the nanosheet particles of Nb^<5+> - doped titanic acid was easily obtained and the highly oriented Nb5+ - doped TiO_2 was formed by only coating process on substrate.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (35 results)

All 2013 2012 2011 2010

All Journal Article (15 results) (of which Peer Reviewed: 8 results) Presentation (20 results)

  • [Journal Article] Control of orientation and electrical conductivity of doped ZnO films using a layered doublehydroxide nanoparticle precursor and spark plasma sintering process2013

    • Author(s)
      N. Ukawa, T. Saito, T. Kojima, K. Kakegawa
    • Journal Title

      Scripta Materialia

      Volume: 69 Pages: 131-134

    • Related Report
      2012 Final Research Report
  • [Journal Article] Synthesis of ZnO sols by low-temperature heating of ethylene glycol solution and control of their photoluminescence with addition of glucose2013

    • Author(s)
      N. Uekawa, T. Fujino, T. Kojima, K. Kakegawa
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 121 Pages: 62-67

    • NAID

      130004950783

    • Related Report
      2012 Final Research Report
  • [Journal Article] Control of orientation and electrical conductivity of doped ZnO films using a layered double hydroxide nanoparticle precursor and spark plasma sintering process2013

    • Author(s)
      Uekawa, N., Saito, T., Kojima, T., Kakegawa, K
    • Journal Title

      Scripta Materialia

      Volume: 2013 Issue: 2 Pages: 1-4

    • DOI

      10.1016/j.scriptamat.2013.02.016

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of oriented zinc oxide thin films by firing Zn-Al layered double hydroxide thin films2012

    • Author(s)
      N. Uekawa, T. Saito, T. Kojima, K. Kakegawa
    • Journal Title

      Mater. Lett.

      Volume: 86 Pages: 125-128

    • Related Report
      2012 Final Research Report
  • [Journal Article] Characterization of titanium oxide nanoparticles obtained by hydrolysis reaction of ethylene glycol solution of alkoxide2012

    • Author(s)
      N. Uekawa, N. Endo, K. Ishii, T. Kojima, K. Kakegawa
    • Journal Title

      Journal of Nanotechnology, art

      Volume: no. 102361 Pages: 1-8

    • Related Report
      2012 Final Research Report
  • [Journal Article] Characterization of titanium oxide nanoparticles obtained by hydrolysis reaction of ethylene glycol solution of alkoxide2012

    • Author(s)
      Uekawa, N., Endo, N., Ishii, K., Kojima, T., Kakegawa, K.
    • Journal Title

      Journal of Nanotechnology

      Volume: art. no. 102361 Pages: 1-8

    • DOI

      10.1155/2012/102361

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of oriented zinc oxide thin films by firing ZnAl layered double hydroxide thin films2012

    • Author(s)
      Uekawa, N., Saito, T., Kojima, T., Kakegawa, K.
    • Journal Title

      Materials Letters

      Volume: 86 Pages: 125-128

    • DOI

      10.1016/j.matlet.2012.07.047

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of ZnO sols by low-temperature heating of ethylene glycol solution and control of their photoluminescence with addition of glucose2012

    • Author(s)
      Uekawa, N., Fujino, T., Kojima, T., Kakegawa, K.
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Pages: 62-67

    • NAID

      130004950783

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Titanium Oxide Nanoparticles Obtained by Hydrolysis Reaction of Ethylene Glycol Solution of Alkoxide2012

    • Author(s)
      上川直文, 遠藤直哉, 石井啓介, 小島隆, 掛川一幸
    • Journal Title

      Journal of Nanotechnology

      Volume: (掲載確定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a stable sol of Mn^<2+>- doped ZnS nanoparticles by low-temperature heating of sulfide precipitate in ethylene glycol2011

    • Author(s)
      N. Uekawa, T. Matsumoto, T. Kojima, K. Kakegawa
    • Journal Title

      J. Ceram. Soc. Jpn

      Volume: 119 Pages: 346-350

    • NAID

      130000662436

    • Related Report
      2012 Final Research Report
  • [Journal Article] Characterization of oxides obtained by heating a mixture of peroxoniobic acid and peroxotitanic acid2011

    • Author(s)
      N. Uekawa, Y. Ohsawa, T. Kojima, K. Kakegawa
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 1817-1822

    • Related Report
      2012 Final Research Report
  • [Journal Article] Synthesis of a stable sol of Mn^<2+>-doped ZnS nanoparticles by low-temperature heating of sulfide precipitate in ethylene glycol2011

    • Author(s)
      上川直文, 松本貴彬, 小島隆, 掛川一幸
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 119 Pages: 346-350

    • NAID

      130000662436

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of oxides obtained by heating a mixture of peroxoniobic acid and peroxotitanic acid2011

    • Author(s)
      上川直文, 大澤祐介, 小島隆, 掛川一幸
    • Journal Title

      Dalton Transaction

      Volume: VOL.40 Pages: 1817-1822

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of stable sol of ZnS nanoparticles by heating the mixture of ZnS precipitate and ethylene glycol2010

    • Author(s)
      N. Uekawa, T. Matsumoto, T. Kojima, K. Kakegawa
    • Journal Title

      Colloids and Surfaces A

      Volume: 361 Pages: 132-137

    • Related Report
      2012 Final Research Report
  • [Journal Article] Synthesis of stable sol of ZnS nanoparticles by heating the mixture of ZnS precipitate and ethylene glycol2010

    • Author(s)
      上川直文, 松本貴彬, 小島隆, 掛川一幸
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Eng ineering Aspects

      Volume: VOL.361 Pages: 132-137

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 糖添加エチレングリコール中でのZnOナノ粒子生成過程のUV-VIS吸光スペクトルの経時変化測定による検討2013

    • Author(s)
      上川直文,藤野辰哉,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2013-03-19
    • Related Report
      2012 Final Research Report
  • [Presentation] 糖添加エチレングリコール中でのZnOナノ粒子生成過程のUV-VIS吸光スペクトルの経時変化測定による検討2013

    • Author(s)
      上川 直文・藤野 辰哉・小島 隆・掛川 一幸
    • Organizer
      (公社)日本セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Control of orientation and ele ctrical conductivity of doped ZnO films by u sing LDH nanoparticles as precursor and SPS process2012

    • Author(s)
      N. UEKAWA, T. SAITO, T. KOJIMA, K. KAKEGAWA
    • Organizer
      The 29th Korea-Japan International Seminar on Ceramics
    • Place of Presentation
      EXCO, D aegu, Korea
    • Year and Date
      2012-11-23
    • Related Report
      2012 Final Research Report
  • [Presentation] クエン酸イオン含有ZnSナノ粒子分散ゾルへの遷移金属イオン添加による蛍光発光特性制御2012

    • Author(s)
      大内真弓,上川直文,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 掛川一幸,グリコール類を用いたZnOナノ粒子安定分散ゾルの低温合成と糖添加による蛍光発光制御2012

    • Author(s)
      藤野辰哉,上川直文,小島隆
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] ジアミンを用いた沈殿生成反応によるZn系酸化物微粒子の合成と物性制御2012

    • Author(s)
      上川直文,齋藤貴宏,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Zn^<2+>含有層状複水酸化物微粒子分散水溶液を用いた配向性酸化亜鉛薄膜の作製2012

    • Author(s)
      齋藤貴宏,上川直文,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] エチレングリコールを溶媒として用いたZnOナノ粒子の合成と糖添加による蛍光発光特性制御2012

    • Author(s)
      藤野辰哉,上川直文,小島隆,掛川一幸
    • Organizer
      無機マテリアル学会第124回学講演会
    • Place of Presentation
      船橋市文化創造館
    • Year and Date
      2012-06-07
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] ジアミンを用いた水溶液からの沈殿法によるAl-Zn系酸化物薄膜の調製と導電性の検討2012

    • Author(s)
      上川直文,齋藤貴宏,小島隆,掛川一幸
    • Organizer
      無機マテリアル学会第124回学講演会
    • Place of Presentation
      船橋市文化創造館
    • Year and Date
      2012-06-07
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] ジアミンを用いた沈殿法によるAlドープZnO粒子の調製と物性の検討2012

    • Author(s)
      上川直文,齋藤貴宏,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      2012-03-21
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] ジアミンを用いた沈殿生成反応によるZn系酸化物微粒子の合成と物性制御2012

    • Author(s)
      上川 直文・齋藤 貴宏・小島 隆・掛川 一幸
    • Organizer
      (公社)日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学(東山キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Zn2+含有層状複水酸化物微粒子分散水溶液を用いた配向性酸化亜鉛薄膜の作製2012

    • Author(s)
      齋藤 貴宏・上川 直文・小島 隆・掛川 一幸
    • Organizer
      (公社)日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学(東山キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] グリコール類を用いたZnOナノ粒子安定分散ゾルの低温合成と糖添加による蛍光発光制御2012

    • Author(s)
      藤野辰哉・上川直文・小島隆・掛川一幸
    • Organizer
      (公社)日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学(東山キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] クエン酸イオン含有ZnSナノ粒子分散ゾルへの遷移金属イオン添加による蛍光発光特性制御2012

    • Author(s)
      大内 真弓・上川 直文・小島 隆・掛川 一幸
    • Organizer
      (公社)日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学(東山キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Control of orientation and electrical conductivity of doped ZnO films by using LDH nanoparticles as precursor and SPS process2012

    • Author(s)
      Naofumi UEKAWA, Takahiro SAITO, Takashi KOJIMA, Kazuyuki KAKEGAWA
    • Organizer
      The 29th Korea-Japan International Seminar on Ceramics
    • Place of Presentation
      EXCO, Daegu, Korea
    • Related Report
      2012 Annual Research Report
  • [Presentation] 層状複水酸化物粒子を用いた配向性を有するAl^<3+>ドープZnO薄膜の作製2011

    • Author(s)
      上川直文,齋藤貴宏,小島隆,掛川一幸
    • Organizer
      無機マテリア学会第123回学術講演会
    • Place of Presentation
      佐賀県
    • Year and Date
      2011-11-18
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] アルコキシドとNH_3水の混合静置によるTiO_2ゾル生成過程の検討と得られたTiO_2ナノ粒子の色素吸着特性2011

    • Author(s)
      上川直文,遠藤直哉,石井啓介,小島隆,掛川一幸
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2011-09-08
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] チタンアルコキシドとNH_3水を用いた安定なTiO_2ナノ粒子分散ゾルの合成と選択的色素吸着特性の検討2011

    • Author(s)
      上川直文,遠藤直哉,小島隆,掛川一幸
    • Organizer
      第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター
    • Year and Date
      2011-01-11
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Synthesis and Characterization of Stable Sol of Cation Doped ZnS Nanoparticl es Obtained by Peptization of Sulfide Precipit ate2010

    • Author(s)
      T. Matsumoto, N. Uekawa, T. Kojima, K. Kakegawa
    • Organizer
      ICC3
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2010-11-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of Stable Sol of TiO_2 Nanoparticles by Heating Ti Alkoxide i n NH_3 Solution and Characterization of Their Surface Properties2010

    • Author(s)
      N. Uekawa, Y. Aoki, N. Endo, T. Kojim a, K. Kakegawa
    • Organizer
      ICC3
    • Place of Presentation
      Osaka,Japan
    • Year and Date
      2010-11-17
    • Related Report
      2012 Final Research Report

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Published: 2010-11-30   Modified: 2019-07-29  

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