| Project/Area Number |
22655045
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Meijo University |
|---|
Principal Investigator |
SAITO Gunzi 名城大学, 総合研究所, 教授 (40132724)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
YOSHIDA Yukihiro 名城大学, 総合研究所, 助教 (10378870)
MAESATO Mitsuhiko 京都大学, 理学研究科, 助教 (60324604)
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥3,440,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,400,000 (Direct Cost: ¥2,400,000)
|
|---|
| Keywords | 超伝導 / 導電性高分子 / 固相重合 / 圧力 / ポリチオフェン / キャリアドープ / 電解重合 / ポリピロール |
|---|
| Research Abstract |
We found a high-pressure induced solid-state polymerization of a thiophene derivative monomer. This finding offers a unique opportunity for obtaining highly conductive, closely packed and well-ordered organic polymer, which is crucial for the development of superconductivity. In pursuit of stable solid-sate polymerization, we prepared single crystals of an unprecedented chloro-substituted thiophene oligomer and thiophene oligomer-based charge-transfer complexes.
|
