Highly Efficient Degradation of Cellulose Using Designed Porous Catalysts

• Project/Area Number: 22655049
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Single-year Grants
• Research Field: Environmental chemistry
• Research Institution: Kyoto University
• Principal Investigator: UEMURA Takashi 京都大学, 工学研究科, 准教授 (50346079)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥3,240,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2010: ¥2,200,000 (Direct Cost: ¥2,200,000)
• Keywords: 多孔性金属錯体 / バイオマス / セルロース / 加水分解 / 酸触媒 / 触媒反応場 / オリゴフッ化ビニリデン / ビニル化 / 細孔サイズ

Research Abstract

Polymer reactions have been controlled in porous metal complexes with activation sites in the pores. I performed functionalization of terminal moiety in oligo(vinylidene fluoride) and hydrolysis of cellulose, which depends on the pore size, shape, and functionality of the nanopores.

Research Products

• [Journal Article] End-Functionalization of a Vinylidene Fluoride Oligomer in Coordination Nanochannels (2011)
  • Author(s): Nobuhiro Yanai, Takashi Uemura, Noriyuki Uchida, Silvia Bracco, Angiolina Comotti, Piero Sozzani, Tetsuhiro Kodani, Meiten Koh, Takashi Kanemura, Susumu Kitagawa
  • Journal Title: J. Mater Chem Volume: 21 Pages: 8021-8025
  • Peer Reviewed
• [Journal Article] End-Functionalization of a Vinylidene Fluoride Oligomer in Coordination Nanochannels (2011)
  • Author(s): N.Yanai, T.Uemura, N.Uchida, S.Bracco, A.Comotti, P.Sozzani, T.Kodani, M.Koh, T.Kanemura, S.Kitagawa
  • Journal Title: J.Mater.Chem. Volume: 45
  • Peer Reviewed
• [Presentation] 金属錯体ナノ空間で高分子を合成・操作する (2012)
  • Author(s): 植村卓史
  • Organizer: 関東高分子若手研究会2010ミニシンポジウム
  • Place of Presentation: 北海道支笏湖
  • Year and Date: 2012-09-17
• [Presentation] 低環境負荷材料の開拓に向けた錯体ナノ空間への高分子拘束 (2012)
  • Author(s): 植村卓史
  • Organizer: 奈良先端大未来開拓コロキウム「環境課題に挑戦するサステナブル分子科学」
  • Place of Presentation: 奈良先端大
  • Year and Date: 2012-03-13
• [Presentation] 低環境負荷材料の開拓に向けた錯体ナノ空間への高分子拘束 (2012)
  • Author(s): 植村卓史
  • Organizer: 奈良先端大未来開拓コロキウム「環境課題に挑戦するサステナブル分子科学」
  • Place of Presentation: 奈良先端大(招待講演)
  • Year and Date: 2012-03-13
• [Presentation] 金属錯体ナノ空間で高分子を合成・操作する (2010)
  • Author(s): 植村卓史
  • Organizer: 関東高分子若手研究会2010ミニシンポジウム
  • Place of Presentation: 北海道支笏湖(招待講演)
  • Year and Date: 2010-09-17