| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
We developed efficient method for introduction of various functionalities toward hexa-peri-hexabenzocoronenes. Second, we discovered that oxidation of amino-substituted porphyrins provided pyrazine-fused dimers in excellent yield with high regioselectivity. The pyrazine-fused dimers were also obtained by oxidation of amino-substituted anthracenes. In this case, pyrrole-fused dimer with helical conformation was obtained. Furthermore, oxidation of dihydroxyanthracenes afforded highly distorted [2.2]metacyclophanes.
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