New Reactions, Compounds and Materials Based on Boron Ate Complexes

• Project/Area Number: 22750038
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: ISHIDA Naoki 京都大学, 大学院・工学研究科, 助教 (70512755)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: ホウ素 / アート錯体 / パラジウム / ボラート / インデン / アリル化 / XANTPHOS / アルケニルボラン / アルケニルボロン酸

Research Abstract

Organoboron compounds serve as useful reagents to synthesize pharmaceuticals and optoelectronic materials. We developed herein a new synthetic method for them. The present method enabled to synthesize complex molecules which are difficult to prepare by conventional methods. The pyridine. borane complexes obtained by this method exhibited intense fluorescence and high electron affinity. The new materials were successfully applied to hybrid organic-inorganic LED, a promising flexible lightning system.

Research Products

• [Journal Article] Synthesis of Pyridine-N-oxide. Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates (2011)
  • Author(s): Naoki Ishida, Wataru Ikemoto, Mizuna Narumi, Masahiro Murakami
  • Journal Title: Org. Lett Volume: 13 Pages: 3008-3011
  • Peer Reviewed
• [Journal Article] Synthesis of Pyridine-N-oxide-Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates (2011)
  • Author(s): Naoki Ishida, Wataru Ikemoto, Mizuna Narumi, Masahiro Murakami
  • Journal Title: Organic Letters Volume: 13 Issue: 12 Pages: 3008-3011
  • DOI: 10.1021/ol2008439
  • Peer Reviewed
• [Journal Article] Iterative Approach to Oligo(arylenevinylene) s Containing Tetrasubstituted Vinylene Unit (2010)
  • Author(s): Naoki Ishida, Yasuhiro Shimamoto, Masahiro Murakam
  • Journal Title: Org. Lett Volume: 12 Pages: 3179-3181
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Allylation Reaction of Alkynylborates (2010)
  • Author(s): Naoki Ishida, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, Masahiro Murakami
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 83 Pages: 1380-1385
  • NAID: 10027652835
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Allylation Reaction of Alkynylborates (2010)
  • Author(s): Naoki Ishida, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, Masahiro Murakami
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 83 Pages: 1380-1385
  • NAID: 10027652835
  • Peer Reviewed
• [Journal Article] Iterative Approach to Oligo(arylenevinylene)s Containing Tetrasubstituted Vinylene Units (2010)
  • Author(s): Naoki Ishida, Yasuhiro Shimamoto, Masahiro Murakami
  • Journal Title: Organic Letters Volume: 12 Pages: 3179-3181
  • Peer Reviewed
• [Presentation] パラジウム触媒を用いたアルキニルボラートと2-ブロモピリジン-N-オキシドの反応によるピリジン-N-オキシド-ボラン錯体の合成 (2011)
  • Author(s): 石田直樹、池元亘、鳴海瑞菜、村上正浩
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学(名古屋市)
  • Year and Date: 2011-09-09
• [Presentation] パラジウム触媒を用いたアルキニルボラートと2-ブロモピリジン-N-オキシドの反応によるピリジン-N-オキシド-ボラン錯体の合成 (2011)
  • Author(s): 石田直樹、池元旦、鳴海瑞菜、村上正浩
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋市名古屋大学
  • Year and Date: 2011-09-09
• [Presentation] Palladium-catalyzed reaction of Alkynyl(aryl) borates with aryl halides (2010)
  • Author(s): Naoki Ishida
  • Organizer: Pacifichem 2010(2010環太平洋国際化学会議)
  • Place of Presentation: ハワイ(ホノルル)
  • Year and Date: 2010-12-19
• [Presentation] Palladium-catalyzed reaction of Alkynyl(aryl)borates with aryl halides. (2010)
  • Author(s): Naoki Ishida
  • Organizer: Pacifichem 2010(2010環太平洋国際化学会議)
  • Place of Presentation: Honolulu, Hawaiiu USA
  • Year and Date: 2010-12-19