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Gel electrophoresis for separating of nano-scaled polyoxometalate clusters

Research Project

Project/Area Number 22850013
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionYamaguchi University

Principal Investigator

TSUNASHIMA Ryo  山口大学, 大学院・理工学研究科, 助教 (70466431)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,029,000 (Direct Cost: ¥2,330,000、Indirect Cost: ¥699,000)
Fiscal Year 2011: ¥1,404,000 (Direct Cost: ¥1,080,000、Indirect Cost: ¥324,000)
Fiscal Year 2010: ¥1,625,000 (Direct Cost: ¥1,250,000、Indirect Cost: ¥375,000)
Keywordsポリ酸 / ポリオキソメタレート
Research Abstract

Polyoxometalate clustersencompass a vast library of molecular metal-oxo anions with a large range of mass, size, and charge and are generally formed under one-pot conditions, where many species may exist in solution at any given time. Herein it was shown that conventional gel electrophoresis can be used to separate metal oxide based nanomaterials from mixtures, and as a result identify cluster types as a function of their surface charge density. This means that when considering the structural diversity of metal oxide nanomaterials, the variation of charge, size, shape or other structural properties causes a difference in mobility that can be used to both characterise and separate the nanoscale oxides in solution.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (7 results)

All 2012 2011 2010

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results)

  • [Journal Article] Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis2012

    • Author(s)
      R. Tsunashima, C. Richmond and L. Cronin
    • Journal Title

      Chem. Sci.

      Volume: 3 Pages: 343-348

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis2012

    • Author(s)
      綱島亮, 他
    • Journal Title

      Chemical Science

      Volume: 3 Pages: 343-348

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] ポリオキソメタレート化合物のゲル電気泳動によるクロマトグラフィー分析2012

    • Author(s)
      綱島亮, 他
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      慶応大学横浜
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ポリオキソメタレート化合物のゲル電気泳動によるクロマトグラフィー分析2012

    • Author(s)
      綱島亮, 他
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      慶応大学(横浜)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ポリオキソメタレートの電気泳動移動度と構造の相関2011

    • Author(s)
      綱島亮, 他
    • Organizer
      錯体化学討論会
    • Place of Presentation
      岡山理科大学岡山
    • Year and Date
      2011-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] ポリオキソメタレートの電気泳動移動度と構造の相関2011

    • Author(s)
      綱島亮, 他
    • Organizer
      錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Year and Date
      2011-09-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Unveiling the Polyoxoniobates Architecture : High-nuclearity Isopolyoxoniobates with Pentagonal Building Blocks2010

    • Author(s)
      綱島亮
    • Organizer
      Pacific Chem 2010
    • Place of Presentation
      ホノルル アメリカ
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-27   Modified: 2016-04-21  

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