Study of molecular interfaces in polymer thin-film composite membranes for the efficient gas separations
| Project/Area Number |
22K04806
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Review Section |
Basic Section 27010:Transport phenomena and unit operations-related
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| Research Institution | Kyushu University |
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Principal Investigator |
Selyanchyn Roman 九州大学, エネルギー研究教育機構, 准教授 (90729790)
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| Project Period (FY) |
2022-04-01 – 2025-03-31
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| Project Status |
Granted (Fiscal Year 2023)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2024: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2023: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2022: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | gas separation / polymer membrane / thin-film composite / carbon dioxide / molecular interface / interface selectivity / selective interface / CO2/N2 separation / polymer interface / CO2 philicity |
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| Outline of Research at the Start |
This study is devoted to the development of thin-film composite membranes with selective molecularly-thin interfaces between polymers to achieve efficient carbon dioxide separation from complex mixtures with other gases. Specifically, separation from nitrogen, oxygen and hydrogen will be studied.
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| Outline of Annual Research Achievements |
This work investigates the complexity and importance of thin-film composite (TFC) membranes that contain ultrathin layers in the structure. At the beginning stage, the focus was to examine how the surface modification of the hydrophobic polymer layer by water vapor-generated plasma influences the formation of the selective interface with the hydrophilic selective layer. We discovered that a minimum critical amount of surface modification is crucial to form the proper laminate structure. However, we also found that the surface modification by the plasma treatment alone does not increase the membrane's selectivity towards CO2 and the optimal combination with selective polymer is essential.
This research then studies the gas transport of CO2, O2, and N2, to identify the extent of the molecular interface in achieving highly selective CO2/N2 and CO2/O2 separation. With the inclusion of this selective interface in the TFC structure, the selectivity significantly increased. For instance, the selectivity for CO2/N2 and CO2/O2 separation reached approximately 35 and 13, respectively, compared to ~10 and ~5 in the membranes without the selective layer and interface. Importantly, our work also focuses on the application of these membranes in the direct air capture of CO2, a technology that plays a vital role in mitigating the effects of climate change. By capturing carbon dioxide directly from the air, we can effectively reduce the concentration of greenhouse gases in the atmosphere, thereby slowing down the rate of global warming.
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| Current Status of Research Progress |
Current Status of Research Progress
2: Research has progressed on the whole more than it was originally planned.
Reason
The research is progressing smoothly according to the initial plan investigating both surface modification impact on gas separation and thinning of the layer in the thin-film composites. In addition to the planned work we have started the scaling the membrane fabrication, aiming to be able to transfer the lab approach to realistic applications.
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| Strategy for Future Research Activity |
The conditions of the selective interface formation between the highly permeable hydrophobic polymer (PDMS) and CO2 selective hydrophilic polymer poly(block-amide-ethylene oxide) were established. The influence of the surface modification by oxygen and water plasmas was systematically studied. In the next research stage, we study the influence of the thicknesses of polymeric layers and overal membrane geometry of the thin-film composite membrane. We will continue to systematically investigate the thickness's impact on interface formation and its contribution to the CO2 selectivity and, overall gas separation performance.
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Report
(2 results)
Research Products
(14 results)
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[Journal Article] Carbon molecular sieve membranes fabricated at low carbonization temperatures with novel polymeric acid porogen for light gas separation2023
Author(s)
Hongfang Guo, Jing Wei, Yulei Ma, Zikang Qin, Xiaohua Ma, Roman Selyanchyn, Bangda Wang, Xuezhong He, Bo Tang, Lin Yang, Lu Yao, Wenju Jiang, Yuanfa Zhuang, Dengguo Yin, Xue Li, Zhongde Dai
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Journal Title
Separation and Purification Technology
Volume: 317
Pages: 1-11
DOI
Related Report
Peer Reviewed
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