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Elucidation of pulsed laser-induced morphological changes of gold nanoparticles using transient absorption and single particle spectroscopies

Research Project

Project/Area Number 23310065
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionThe University of Tokushima

Principal Investigator

HASHIMOTO Shuichi  徳島大学, ソシオテクノサイエンス研究部, 教授 (70208445)

Co-Investigator(Renkei-kenkyūsha) FURUBE Akihiro  独立行政法人産業技術総合研究所, 計測フロンティア研究部門, 主任研究員 (30357933)
UWADA Takayuki  奈良先端科学技術大学院大学, 物質創成科学研究科, 非常勤研究員 (30455448)
Research Collaborator WERNER Daniel  徳島大学, 大学院ソシオテクノサイエンス研究部, 徳島大学特別研究員(日本学術振興会特別研究員
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2012: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2011: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywordsナノ材料 / 金ナノ粒子 / レーザー / 光熱効果 / プラズモン / 熱伝導 / 形態変化 / サイズ減少 / 熱移動 / バブル / ナノ超臨界 / 単一粒子分光 / 散乱スペクトル / レーザー誘起形態変化 / 時間分解分光
Research Abstract

We focused our attention to the fundamental aspects of the laser-gold nanoparticle (Au NP) interaction that leads to the particle heating as well as energy deposition to the surrounding media. The former gives rise to the particle melting, deformation, and ablation, which has discussion on the mechanism. The latter generates medium temperature gradients and bubbles resulting from local heating through the heat transfer from the particle to the surroundings. The laser-Au NP interaction can be applied to the material fabrication such as fine tuning of particle size and size distribution by applying high pressures and nanohole fabrication on glass substrates. We also refer to the importance of temperature measurements in dimension smaller than the diffraction limit. We show that this can be achieved by CW laser-Au NP interaction by using the single particle spectroscopy.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (23 results)

All 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (13 results) (of which Invited: 7 results) Remarks (1 results)

  • [Journal Article] Observation of Nanoscale Cooling Effects by Substrates and the Surrounding Media for Single Gold Nanoparticles under CW-laser Illumination2013

    • Author(s)
      K. Setoura, Y. Okada, D. Werner, S. Hashimoto
    • Journal Title

      ACS Nano

      Volume: Vol.7 Issue: 9 Pages: 7874-7885

    • DOI

      10.1021/nn402863s

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controlling the pulsed-laser-induced size reduction of Au and Agnanoparticles via changes in the external pressure, laser intensity, and excitation wavelength.2013

    • Author(s)
      Werner Daniel, Shuichi Hashimoto
    • Journal Title

      Langmuir

      Volume: 29 Issue: 4 Pages: 1295-1302

    • DOI

      10.1021/la3046143

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical Scattering Spectral Thermometry and Refractometry of a Single Gold Nanoparticle under CW laser excitation2012

    • Author(s)
      Kenji Setoura, Werner Daniel, Shuichi Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Issue: 29 Pages: 15458-15466

    • DOI

      10.1021/jp304271d

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the Interaction of Pulsed Lasers with Plasmonic Gold Nanoparticles toward Light Manipulation2012

    • Author(s)
      S. Hashimoto, D. Werner, T. Uwada
    • Journal Title

      Heat Management, and Nanofabrication

      Volume: Vol.13 Issue: 1 Pages: 28-54

    • DOI

      10.1016/j.jphotochemrev.2012.01.001

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Methodological Improvement in Pulsed Laser-Induced Size Reduction of Aqueous Colloidal Gold Nanoparticles by Applying High Pressure2012

    • Author(s)
      D.Werner, T.Ueki, S.Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Issue: 9 Pages: 5482-5491

    • DOI

      10.1021/jp300690z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the Interaction of Pulsed Lasers with Plasmonic Gold Nanoparticles2012

    • Author(s)
      S.Hashimoto, D.Werner, T.Uwada
    • Journal Title

      J.Photochem.Phtobiol.C : Review

      Volume: 13 Pages: 28-54

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Femtosecond Laser-Induced Size Reduction of Aqueous Gold Nanoparticles : In situ and Pump-Probe Spectroscopy Investigations Revealing Coulomb Explosion2011

    • Author(s)
      D. Werner, A. Furube, T. Okamoto, S. Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: Vol.115 Issue: 17 Pages: 8503-8512

    • DOI

      10.1021/jp112262u

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved working model for interpreting the excitation wavelength-and fluence-dependent response in nanosecond pulsed laser-induced size reduction of aqueous gold nanoparticles2011

    • Author(s)
      D. Werner, S. Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: Vol.115 Issue: 12 Pages: 5063-5072

    • DOI

      10.1021/jp109255g

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic aspect of surface modification on glass substrates assisted by single shot pulsed laser-induced fragmentation of gold nanoparticles2011

    • Author(s)
      S. Hashimoto, T. Uwada, M. Hagiri, R. Shiraishi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: Vol.115 Issue: 12 Pages: 4986-4993

    • DOI

      10.1021/jp106830x

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] Ensemble and single particle measurements of photothermal response of gold nanoparticles2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      The 9th Korea-Japan Symposium on Frontier of Photoscience-2013
    • Place of Presentation
      Seoul National University (Seoul, Korea)
    • Year and Date
      2013-11-25
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 単一金ナノ粒子を用いた光熱効果の研究(特別企画講演)2013

    • Author(s)
      橋本修一
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県)
    • Year and Date
      2013-03-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Plasmonic Nanobubble Dynamics on Excitation of Aqueous Colloidal Gold Nanoparticles Observed by Picosecond Transient Spectroscopy2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      Symposium on Plasmon-based Chemistry and Physics
    • Place of Presentation
      Leuven Catholic University (Leuven, Belgium)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Interaction of lasers with gold nanopaticles : remarkable effects on the particles and the surrounding media2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      International Symposium : Molecular Plasmonics 2013
    • Place of Presentation
      Institute of Photonic Technology, Jena, Germany
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Ensemble and single particle measurements of photothermal response of gold nanoparticles2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      The 9th Korea-Japan Symposium on Frontier of Photoscience 2013
    • Place of Presentation
      Seoul National University (Korea)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Plasmonic Nanobubble Dynamics on Excitation of Aqueous Colloidal Gold Nanoparticles Observed by Picosecond Transient Spectroscopy2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      Symposium on Plasmon-based Chemistry and Physics
    • Place of Presentation
      Leuven (Belgium)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Interaction of lasers with gold nanopaticles: remarkable effects on the particles and the surrounding media.2013

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      International Symposium: Molecular Plasmonics 2013
    • Place of Presentation
      Iena (Germany)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 金ナノ粒子とパルスレーザーの相互作用を利用したナノ加工(特別企画講演)2012

    • Author(s)
      橋本修一
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      立命館大学びわこ・草津キャンパス(滋賀県)
    • Year and Date
      2012-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Interactions of Lasers with Gold Nanoparticles Leading to the Phase Transformations of the Particles and the Surrounding Media2012

    • Author(s)
      Shuichi Hashimoto, Daniel Werner, Kenji Setoura
    • Organizer
      Japan-India Bilateral Seminar on Supramolecular Nanomaterials for Energy Innovation
    • Place of Presentation
      Alpha Anabuki Hall (Takamatsu, Japan)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 高圧レーザーアブレーション法による金ナノ粒子のサイズおよびサイズ分布の精密コントロール2012

    • Author(s)
      橋本 修一
    • Organizer
      2012年 光化学討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単一金ナノ粒子の表面融解現象及びレーザー誘起形態変化の解明2012

    • Author(s)
      橋本 修一
    • Organizer
      2012年 光化学討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Optical Scattering Spectral Thermometry and Refractometry of a Single Gold Nanoparticle under CW Laser Excitation2012

    • Author(s)
      橋本 修一
    • Organizer
      第7回アジア光化学会議
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Femtosecond laser photolysis study of gold nanoparticles in solution : observation of Coulomb explosion2011

    • Author(s)
      S.Hashimoto, D.Werner, A.Furube
    • Organizer
      XXV Internatinal Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      2011-08-12
    • Related Report
      2011 Annual Research Report
  • [Remarks] 橋本研究室ウェブサイト

    • URL

      http://www.opt.tokushima-u.ac.jp/lab/a-4/index.html

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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