| Budget Amount *help |
¥20,280,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥4,680,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
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| Outline of Final Research Achievements |
At the beginning of the project, we focused on the alkyl chain, which has a self-assembling ability and hydrophobicity, and tried to develop highly selective and efficient catalyst. During the research, we found a use of organocatalyst, which has a molecular flame with two functional group, is effective for the preparation of heterocyclic compound with high asymmetric induction. Moreover, we also found a novel cycloaddition reaction using metal-porphiryn catalyst, which has high hydrophobicity. And also, we developed novel method for the preparation of cyclic compounds using nickel catalyst and organozinc reagent.
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