• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Fine Synthesis of Nanobuilding Units and Construction of Multidimensional Structures through Their Self-Assembly

Research Project

Project/Area Number 23350098
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionThe University of Tokyo

Principal Investigator

OKUBO Tatsuya  東京大学, 工学(系)研究科(研究院), 教授 (40203731)

Co-Investigator(Renkei-kenkyūsha) SHIMOJIMA Atsushi  早稲田大学, 先進理工学部, 准教授 (90424803)
NARUTAKI Ayae  名古屋大学, 大学院・工学研究科, 准教授 (10508203)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2013: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywordsナノ材料 / 自己組織化 / 表面・界面物性 / 複合材料・物性 / ナノ粒子
Research Abstract

We have established a gram-scale synthesis of monodispersed silica nanospheres, the diameter of which can be controlled below 50 nm size region. These nanospheres as colloidal dispersion can serve as excellent nanobuilding units (NBUs) in the bottom-up materials synthesis. In this study, we have developed more facile synthetic method of monodispersed silica nanospheres. Furthermore, novel NBUs having a variety of composition, shape, and interior structures are synthesized. The NBUs are self-assembled into one-, two-, or three-dimensional structures by the fine tuning of interparticle interations operated in liquid phases.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (49 results)

All 2014 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 1 results) Presentation (31 results) (of which Invited: 3 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synthesis of String-Bean-Like Anisotropic Titania Nanoparticles with Basic Amino Acids2014

    • Author(s)
      Junzheng Wang, John K. Katahara, Akihito Kumamoto, Tetsuya Tohei, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      RSC Adv

      Volume: 4 Issue: 18 Pages: 9233-9234

    • DOI

      10.1039/c3ra47170e

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Amino Acid-assisted One-dimensional Assembly of Semiconducting Metal Oxide Nanoparticles in Aqueous Alcohol Media2014

    • Author(s)
      Junzheng Wang, Hiroki Yabe, Atsushi Shimojima, Takashi Sekiguchi, Ayae Sugawara-Narutaki, Tatsuya Okubo
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 6 Pages: 934-935

    • DOI

      10.1246/cl.140158

    • NAID

      130004868203

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Monodisperse Organosilica Nanoparticles with Hollow Interiors and Porous Shells Using Silica Nanospheres as Templates2013

    • Author(s)
      Natsume Koike, Takaaki Ikuno, Tatsuya Okubo, Atsushi Shimojima
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 44 Pages: 4998-5000

    • DOI

      10.1039/c3cc41904e

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Synthesis of Well-Dispersed, Core-Shell Ag@SiO2 Mesoporous Nanoparticles Using Amino Acids and Sugars2013

    • Author(s)
      Philippe Saint-Cricq, Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Journal of Materials Chemistry B

      Volume: 1 Issue: 19 Pages: 2451-2454

    • DOI

      10.1039/c3tb20210k

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Base Molecules on One-dimensional Assembly of Silica Nanospheres Mediated by a Block Copolymer2013

    • Author(s)
      Shujun Zhou, Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 5 Pages: 481-482

    • DOI

      10.1246/cl.130017

    • NAID

      10031167797

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 単分散球状シリカナノ粒子が拓くナノアーキテクチャーの世界2013

    • Author(s)
      鳴瀧彩絵, 大久保達也
    • Journal Title

      表面

      Volume: 51(6) Pages: 22-35

    • NAID

      40019981178

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Facile Synthesis of Well-Dispersed Hollow Mesoporous Silica Nanoparticles Using Iron Oxide Nanoparticles as Template2013

    • Author(s)
      Takaaki Ikuno
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 3 Pages: 316-317

    • DOI

      10.1246/cl.2013.316

    • NAID

      130004426906

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chain-like nanostructures from anisotropic self-assembly of semiconducting metaloxide nanoparticles with block copolymer2012

    • Author(s)
      J. Wang, S. Winardi, A. Sugawara-Narutaki, A. Kumamoto, T. Tohei, A. Shimojima, and *T. Okubo
    • Journal Title

      Chemistry Communication

      Volume: 48 Issue: 90 Pages: 11115-11117

    • DOI

      10.1039/c2cc36210d

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Dimensional Assembly of Silica Nanospheres : Effects of Nonionic Block Copolymers2012

    • Author(s)
      Shujun Zhou, Takeshi Sakamoto, Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Langmuir

      Volume: 28 Issue: 37 Pages: 13181-13188

    • DOI

      10.1021/la302443f

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biphasic Synthesis of Colloidal Mesoporous Silica Nanoparticles using Primary Amine Catalysts2012

    • Author(s)
      Junzheng Wang
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 385 Issue: 1 Pages: 41-47

    • DOI

      10.1016/j.jcis.2012.06.069

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Phase Synthesis of Monodisperse Silica Nanospheres with Amines or Ammonia Catalyst and Their Controlled Self-Assembly2011

    • Author(s)
      Junzheng Wang, Ayae Sugawara-Narutaki, Masashi Fukao, Toshiyuki Yokoi, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 3 Issue: 5 Pages: 1538-1544

    • DOI

      10.1021/am200104m

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis of Well-Dispersed Organo-Silica Nanoparticles with Hollow Interiors by Hard Templating2013

    • Author(s)
      Atsushi Shimojima, Takaaki Ikuno, Natsume Koike, Ayae Sugawara-Narutaki, Tatsuya Okubo
    • Organizer
      8th International Mesoporous Materials Symposium (IMMS2013)
    • Place of Presentation
      兵庫
    • Year and Date
      2013-05-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Well-Dispersed Organo-Silica Nanoparticles with Hollow Interiors by Hard Templating2013

    • Author(s)
      Atsushi Shimojima, Takaaki Ikuno, Natsume Koike, Ayae Sugawara-Narutaki, Tatsuya Okubo
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS2013)
    • Place of Presentation
      淡路夢舞台国際会議場, 兵庫
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Monodisperse Organosilica Nanoparticles with Hollow Interior and Porous Shell Using Silica Nanospheres as Templates2013

    • Author(s)
      Natsume Koike, Takaaki Ikuno, Tatsuya Okubo, Atsushi Shimojima
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS2013)
    • Place of Presentation
      淡路夢舞台国際会議場, 兵庫
    • Related Report
      2013 Annual Research Report
  • [Presentation] One-pot Synthesis of Monodisperse, Hollow Silsesquioxane Nanoparticles Using Silica Nanospheres as Template2013

    • Author(s)
      Atsushi Shimojima, Natsume Koike, Takaaki Ikuno, Tatsuya Okubo
    • Organizer
      The XVII International Sol-Gel Conference (Sol-Gel 2013)
    • Place of Presentation
      MELIA CASTILLA HOTEL, Madrid. Spain
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分散性有機修飾メソポーラスシリカナノ粒子の創製2013

    • Author(s)
      下嶋敦, 生野敬明, 石井大貴, 小池夏萌, 大久保達也
    • Organizer
      第29回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀, 東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] アミノ基を有するブロックコポリマーを用いた中空シリカナノ粒子の合成2013

    • Author(s)
      坪池祥生, 鳴瀧彩絵, 大久保達也, 下嶋敦, 織田ゆか里, 青島貞人
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学津島キャンパス, 岡山
    • Related Report
      2013 Annual Research Report
  • [Presentation] アミノ 基を有する両親媒性ブロックコポリマーを用いた中空シリカナノ粒子の合成2013

    • Author(s)
      坪池祥生, 鳴瀧彩絵, 大久保達也, 下嶋敦, 織田ゆか里, 青島貞人
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀, 東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 単分散中空有機シリカナノ粒子の合成2013

    • Author(s)
      大久保達也
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学, 大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] 結晶性酸化スズナノ粒子の合成と集合体形成2013

    • Author(s)
      大久保達也
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学, 大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] Block Copolymer-Mediated Anisotropic Self-Assembly of Semiconducting Metal Oxide Nanoparticles2012

    • Author(s)
      Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Organizer
      2012 AIChE Annual Meeting, Pittsburgh
    • Place of Presentation
      USA
    • Year and Date
      2012-10-31
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of Silica Nanospheres with Anisotropic Geometry via Adsorption on Charged Surface2012

    • Author(s)
      Dieu Huong Pham, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] One Dimensional Self-Assembly of Semiconducting Metal Oxide Nanopartides with Block Copolymer in Aqueous System2012

    • Author(s)
      Junzheng Wang, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Anisotoropic Assembly of Isotropic Nanoparticles by Macrooperation2012

    • Author(s)
      Tatuya Okubo
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-15
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Anisotoropic Assembly of Isotropic Nanoparticles by Macrooperation2012

    • Author(s)
      Tatuya Okubo
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      東京(招待講演)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Basic Amino Acid-Mediated 1D Self-Assembly of Tin Oxide Nanoparticles2012

    • Author(s)
      大久保達也
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学, 仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] Block Copolymer-Mediated Anisotropic Self-Assembly of Semiconducting Metal Oxide Nanoparticles2012

    • Author(s)
      Tatsuya Okubo
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      Pittsburgh, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Two-Phase Synthesis of Mesoporous Silica Nanoparticles with Primary Amine Catalysts2012

    • Author(s)
      Tatsuya Okubo
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      Pittsburgh, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Larger-Scale Production of Janus Silica-on-Silica Nanoparticles via Adsorption on Charged Surface2012

    • Author(s)
      Tatsuya Okubo
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      Pittsburgh, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation and Assembly of Anisotropically Polymer-Grafted Silica Nanospheres via Adsorption on Charged Surface2012

    • Author(s)
      Tatsuya Okubo
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      Pittsburgh, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation of Janus-Type Polystyrene-Grafted Silica Nanospheres and Their Assembly2012

    • Author(s)
      Tatsuya Okubo
    • Organizer
      10th Japan-Korea Symposium on Materials and Interfaces
    • Place of Presentation
      コープイン京都, 京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] Chain-Like Assembly of Silica Nanospheres by the Effect of Polymers2011

    • Author(s)
      岡田瑞季, 周淑君, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Anisotropically Surface-Modified Silica Nanospheres2011

    • Author(s)
      Dieu Huong Pham, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Biphasic Synthesis of Colloidal Mesoporous Silica Nanospheres with Primary Amine Catalysts2011

    • Author(s)
      王軍政, 鳴瀧彩絵, Christine Marie Montesa, 下嶋敦, 幾原雄一, 大久保達也
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 球状シリカナノ粒子の合成と自己集合2011

    • Author(s)
      下嶋敦
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-10-26
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 球状シリカナノ粒子の合成と自己集合2011

    • Author(s)
      下嶋敦
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪(招待講演)
    • Year and Date
      2011-10-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Uniform Silica Nanospheres in Liquid-Liquid Biphasic Systems Using Amines or Ammonia Catalyst and Their Controlled Self-Assembly2011

    • Author(s)
      Junzheng Wang, Ayae Sugawara-Narutaki, Masashi Fukao, Toshiyuki Yokoi, Atsushi Shimojima, Tatsuya Okubo
    • Organizer
      2011 AIChE Annual Meeting
    • Place of Presentation
      Minneapolis, USA
    • Year and Date
      2011-10-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Preparation of Anisotropic Silica Nanoparticles via One-Dimensional Assembly of Presynthesized Spherical Seeds2011

    • Author(s)
      Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Organizer
      2011 AIChE Annual Meeting
    • Place of Presentation
      Minneapolis, USA
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子の効果による球状シリカナノ粒子の一次元自己集合2011

    • Author(s)
      岡田瑞季, 周淑君, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Role of Pluronic Block Copolymers in Mediating Anisotropic Assembly of Silica Nanospheres2011

    • Author(s)
      周淑君, 鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 球状シリカナノ粒子の液相における一次元自己集合とその応用2011

    • Author(s)
      鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      日本セラミックス協会第24秋季シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-09
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 球状シリカナノ粒子の液相における一次元自己集合とその応用2011

    • Author(s)
      鳴瀧彩絵, 下嶋敦, 大久保達也
    • Organizer
      日本セラミックス協会第24秋季シンポジウム
    • Place of Presentation
      札幌(招待講演)
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.zeolite.t.u-tokyo.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 大久保・脇原研究室

    • URL

      http://www.zeolite.t.u-tokyo.ac.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 大久保・脇原研究室

    • URL

      http://www.zeolite.t.u-tokyo.ac.jp/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.zeolite.t.u-tokyo.ac.jp/

    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属酸化物構造体の製造方法2012

    • Inventor(s)
      大久保達也, 鳴瀧彩絵, 周叔君
    • Industrial Property Rights Holder
      大久保達也, 鳴瀧彩絵, 周叔君
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2014-097557
    • Filing Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 中空の有機シリカ構造体の製造方法2012

    • Inventor(s)
      大久保達也, 下嶋敦, 小池夏萌
    • Industrial Property Rights Holder
      大久保達也, 下嶋敦, 小池夏萌
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-277289
    • Filing Date
      2012-12-19
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属酸化物構造体の製造方法2012

    • Inventor(s)
      大久保達也, 鳴瀧彩絵, 周叔君
    • Industrial Property Rights Holder
      大久保達也, 鳴瀧彩絵, 周叔君
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-251503
    • Filing Date
      2012-11-15
    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi