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In-situ observation of hydrogen behavior in surface oxides of Zr-based alloys for fuel claddings

Research Project

Project/Area Number 23360427
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionKyoto University

Principal Investigator

TAKAGI Ikuji  京都大学, 工学(系)研究科(研究院), 教授 (20206717)

Co-Investigator(Kenkyū-buntansha) AKIYOSHI Masafumi  京都大学, 大学院・工学研究科, 助教 (70378793)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2011: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Keywords被覆管 / ジルコニウム合金 / 照射効果 / 水素吸収 / 酸化膜 / 拡散 / 加速器分析 / 燃料被覆管 / 水素化 / 照射損傷 / 軽水炉 / 照射 / 加速器 / 水素 / 拡散係数 / ジルコニウム / 核反応法
Research Abstract

Zr-based alloys are widely used for fuel claddings of light water reactors. These alloys might fail to confine fuel elements and fission products when absorbing a large amount of hydrogen. In the present work, deuterium depth profiles in oxides formed on the surface of the alloys were observed with a good depth resolution. The results showed that (1) the hydrogen absorption rate of the alloys was controlled by the hydrogen diffusion coefficient in the oxide, (2) the inner region of the oxide near the oxide/metal interface inhibited the hydrogen absorption owing to a very low diffusion coefficient, and (3) the inner region with the low diffusivity became larger with irradiation dose, probably due to formation of irradiation defects such as dislocation loops.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (27 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (15 results) Remarks (4 results)

  • [Journal Article] Deuterium diffusion in oxide layers of Zr-2.5Nb alloy2013

    • Author(s)
      K. Une, K. Sakamoto, I. Takagi, K. Sawada, H. Watanabe, M. Aomi
    • Journal Title

      J. Nucl. Mater

      Volume: 439 Issue: 1-3 Pages: 84-92

    • DOI

      10.1016/j.jnucmat.2013.04.003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of proton irradiation on deuterium diffusion in zirconium oxide layer2012

    • Author(s)
      K. Une, I. Takagi, K. Sawada, H.Watanabe, K. Sakamoto, M. Aomi
    • Journal Title

      J. Nucl. Mater

      Volume: 420 Issue: 1-3 Pages: 445-445

    • DOI

      10.1016/j.jnucmat.2011.10.021

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deuterium diffusion in LiOH-water-corroded oxide layer of zirconium alloys2012

    • Author(s)
      K. Une, I. Takagi, K. Sawada, S. Miyamura, M. Aomi
    • Journal Title

      Progress in Nuclear Energy

      Volume: 57 Pages: 93-93

    • DOI

      10.1016/j.pnucene.2011.11.009

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Irradiation effects on thermal diffusivity and positron annihilation lifetime in ceramics induced by neutron and 30 MeV electron2012

    • Author(s)
      M. Akiyoshi, H. Tsuchida, I. Takagi, T. Yoshiie, X. Qiu, K. Sato, T. Yano
    • Journal Title

      J. Nucl. Sci. Technol

      Volume: 49 Issue: 6 Pages: 595-601

    • DOI

      10.1080/00223131.2012.686809

    • NAID

      10030438848

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of proton irradiation on deuterium diffusion in zirconium oxide layer2012

    • Author(s)
      K. Une, I. Takagi, K. Sawada, H. Watanabe, K. Sakamoto, M. Aomi
    • Journal Title

      Journal of Nuclear Materials

      Volume: 420 Pages: 445-451

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen absorption mechanism of zirconium alloys based on characterization of oxide layer2011

    • Author(s)
      K. Une, K. Sakamoto, M. Aomi, J. Matsunaga, Y. Etoh, I. Takagi, S. Miyamura, T. Kobayashi, K. Ito
    • Journal Title

      J. ASTM Int

      Volume: 8

    • URL

      http://www.astm.org/search/fullsite-search.html?toplevel=products-and-services&sublevel=standards-and-publications&type=journals&dltype=alldl&journal=jai&query=JAI102950

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deuterium diffusion in steam-corroded oxide layer of zirconium alloys2011

    • Author(s)
      I. Takagi, K. Une, S. Miyamura, T. Kobayashi
    • Journal Title

      J. Nucl. Mater

      Volume: 419 Issue: 1-3 Pages: 339-339

    • DOI

      10.1016/j.jnucmat.2011.06.001

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen absorption machanism of zirconium alloys based on characterization of oxide laver2011

    • Author(s)
      K.Une, K.Sakamoto, M.Aomi, J.Matsunaga, Y.Etoh, I.Takagi
    • Journal Title

      Journal of ASTM International (ID JAI102950)

      Volume: 8 Pages: 1-21

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Role of alloying elements in hydrogen pickup mechanism of Zr-based alloys2013

    • Author(s)
      K. Sakamoto, K. Une, M. Aomi, K. Hashizume, I. Takagi
    • Organizer
      2nd Asian Zirconium Workshop
    • Place of Presentation
      Baoji, Shaanxi, China
    • Related Report
      2013 Final Research Report
  • [Presentation] Property change of oxide layer of Zr-based alloys with oxide growth2013

    • Author(s)
      K. Sakamoto, K. Une, Y. Kashiba, H. Watanabe, I. Takagi, M. Aomi
    • Organizer
      TopFuel 2013
    • Place of Presentation
      Charlotte, North Carolina
    • Related Report
      2013 Final Research Report
  • [Presentation] 遷移前後のZr 合金酸化膜における重水素拡散2013

    • Author(s)
      樫葉洋平, 渡辺久之, 高木郁二, 坂本寛, 宇根勝己
    • Organizer
      日本原子力学会春の年会C36
    • Place of Presentation
      東大阪市
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr 合金酸化膜中の重水素の移動に及ぼすイオン照射の影響II2013

    • Author(s)
      渡辺久之, 樫葉洋平一, 高木郁二, 坂本寛, 宇根勝己, 青見雅樹
    • Organizer
      日本原子力学会秋の大会L08
    • Place of Presentation
      八戸市
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr 合金酸化膜中の重水素拡散に及ぼすイオン照射の影響(II)2013

    • Author(s)
      渡辺久之,樫葉洋平,高木郁二,坂本寛,宇根勝己,青見雅樹
    • Organizer
      日本原子力学会
    • Place of Presentation
      八戸工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Zr合金酸化膜中の重水素の拡散に及ぼすイオン照射の影響(II)2013

    • Author(s)
      渡辺久之、樫葉洋平、高木郁二、坂本寛、宇根勝己、青見雅紀
    • Organizer
      日本原子力学会春の年会 (ポスター発表)
    • Place of Presentation
      近畿大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Controlling factors in hydrogen absorption of zirconium alloys2012

    • Author(s)
      K. Une, K. Sakamoto, J. Matsunaga, Y. Etoh, M. Aomi, I. Takagi, K. Sawada, H. Watanabe
    • Organizer
      TopFuel 2012
    • Place of Presentation
      Manchester, UK
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] ジルコニウム合金の水素吸収機構の検討2012

    • Author(s)
      宇根勝己, 坂本 寛, 松永純治, 栄藤良則, 青見雅樹, 高木郁二, 澤田憲一, 渡辺久之
    • Organizer
      日本原子力学会春の年会C36
    • Place of Presentation
      福井市
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr 合金酸化膜中の重水素の移動に及ぼすイオン照射の影響2012

    • Author(s)
      渡辺久之, 澤田憲一, 高木郁二, 坂本 寛, 宇根勝己, 青見雅樹
    • Organizer
      日本原子力学会秋の大会J24
    • Place of Presentation
      東広島市
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr合金酸化膜中の重水素の拡散に及ぼすイオン照射の影響2012

    • Author(s)
      渡辺久之、澤田憲一、高木郁二、坂本寛、宇根勝己、青見雅紀
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Deuterium diffusion in oxide layers of Zr-2.5Nb alloy2012

    • Author(s)
      K. Une, K. Sakamoto, I. Takagi, K Sawada, H. Watanabe, M. Aomi
    • Organizer
      NuMat 2012
    • Place of Presentation
      大阪市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Deuterium diffusion in Zr oxide irradiated with self ions2012

    • Author(s)
      I. Takagi, H. Watanabe, K. Sawada, K. Une, K. Sakamoto
    • Organizer
      Swift Heavy Ions in Matter (Shim) 2012
    • Place of Presentation
      京都市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Zr-25Nb合金酸化膜中の重水素の拡散挙動2011

    • Author(s)
      澤田憲一, 渡辺久之, 高木郁二, 宇根勝己, 坂本寛
    • Organizer
      日本原子力学会2011年秋の大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Zr-2.5Nb 合金酸化膜中の重水素の拡散挙動2011

    • Author(s)
      澤田憲一, 渡辺久之, 高木郁二, 宇根勝己, 坂本寛
    • Organizer
      日本原子力学会秋の大会E32
    • Place of Presentation
      北九州市
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr 合金酸化膜中の重水素の拡散に及ぼすプロトン照射の影響2011

    • Author(s)
      宇根勝己, 澤田憲一, 渡辺久之, 高木郁二, 青見雅樹
    • Organizer
      日本原子力学会秋の大会E33
    • Place of Presentation
      北九州市
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.nucleng.kyoto-u.ac.jp/Groups/Gr2/index.htm

    • Related Report
      2013 Final Research Report
  • [Remarks] 京都大学大学院工学研究科 原子核工学専攻 核材料工学分野ホームページ

    • URL

      http://www.nucleng.kyoto-u.ac.jp/Groups/Gr2/index.htm

    • Related Report
      2013 Annual Research Report
  • [Remarks] 軽水炉燃料被覆管の水素化

    • URL

      http://www.nucleng.kyoto-u.ac.jp/Groups/Gr2/tc00_hydride.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 被覆管酸化膜中の水素拡散

    • URL

      http://www.nucleng.kyoto-u.ac.jp/Groups/Gr2/tc03_diffusion.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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