Selective oxidation processes to yield high-value added compounds by utilizing micro-reaction devices with immobilized photocatalyst

• Project/Area Number: 23510142
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Microdevices/Nanodevices
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: MATSUSHITA Yoshihisa 東京工業大学, 理工学研究科, 助教 (80240753)
• Co-Investigator(Kenkyū-buntansha): OOKAWARA Shinichi 東京工業大学, 大学院理工学研究科, 准教授 (39524301) ; 大川原 真一 東京工業大学, 理工学研究科, 准教授 (30282825)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
• Keywords: マイクロ化学システム / マイクロリアクター / 光触媒 / 高付加価値化合物 / 医薬品合成 / 二酸化炭素資源化

Research Abstract

Micro-channel reactors and palletized micro-channel reaction devices optimized for photocatalytic reactions have been developed. We have demonstrated that reaction efficiency and selectivity of phtocatalytic reactions to yield high-value added compounds can be improved by utilizing unique features of micro-reaction vessels combined with photocatalysts.

Research Products

• [Journal Article] Intensification of Photochemical Wastewater Decolorization Process Using Microreactors (2014)
  • Author(s): Bruno Ramos; Shinichi Ookawara; Yoshihisa Matsushita; Shiro Yoshikawa
  • Journal Title: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN Volume: 47 Pages: 136-140
  • NAID: 130003390862
• [Journal Article] The impact of Novel Process Windows on the Claisen rearrangement (2013)
  • Author(s): Hiroki Kobayashi, Brian Driessen, Dannie J.G.P.van Osch, Ali Talla, Shinichi Ookawara, Timothy Noel, Volker Hessel
  • Journal Title: Tetrahedron Volume: 69 Pages: 2885-2890
• [Presentation] Effect of Growth Temperature on Vertically-Aligned Carbon Nanotubes Prepared byRadio-Frequency Plasma-Enhanced Chemical Vapor Deposition (2014)
  • Author(s): Abdalla M. Abdalla, Haitham M. El-bery1, Mohamed N. A. Nasr, Y. Matsushita, Ahmed Eldesouky1, and Ahmed Abdelmoneim
  • Organizer: Sixth International Conference on NANO-TECHNOLOGY IN CONSTRUCTION
  • Place of Presentation: Cairo
  • Year and Date: 2014-03-23
• [Presentation] Effect of Growth Temperature on Vertically-Aligned Carbon Nanotubes Prepared by Radio-Frequency Plasma-Enhanced Chemical Vapor Deposition (2014)
  • Author(s): Abdalla M. Abdalla, Haitham M. El-bery1, Mohamed N. A. Nasr, Y. Matsushita, Ahmed Eldesouky1, and Ahmed Abdelmoneim
  • Organizer: Sixth International Conference on NANO-TECHNOLOGY IN CONSTRUCTION
  • Place of Presentation: Cairo, Egypt
• [Presentation] マイクロ空間の特性を利用した光触媒反応による高付加価値化合物合成 (2013)
  • Author(s): 松下慶寿
  • Organizer: 第4回マイクロ化学プロセス分科会講演会
  • Place of Presentation: 京都大学品川サテライト
  • Year and Date: 2013-01-24
  • Invited
• [Presentation] マイクロ空間の特性を利用した光触媒反応による高付加価値化合物合成 (2013)
  • Author(s): 松下慶寿
  • Organizer: 第4 回マイクロ化学プロセス分科会講演会
  • Place of Presentation: 京都大学品川サテライト
  • Invited
• [Presentation] Intensification of photochemical wastewater decolorization process by using microreactors (2012)
  • Author(s): B. Ramos,S. Ookawara, Y. Matsushita, S. Yoshikawa
  • Organizer: International Workshop on Process Intensification 2012
  • Place of Presentation: Seoul
  • Year and Date: 2012-11-08
• [Presentation] MICRO-FLOW REACTION SYSTEMS FOR PHOTOCATALYTIC CARBON DIOXIDE RECYCLING AND HYDROGEN GENERATION (2012)
  • Author(s): Yoshihisa Matsushita, Haitham Mohamed AhmedMohamed, Shinichi Ookawara
  • Organizer: The 16th International Conference on Miniaturized Systems for Chemistry and Life Sciences (MicroTAS 2012)
  • Place of Presentation: 沖縄コンベンションセンター
  • Year and Date: 2012-10-31
• [Presentation] Selective Oxidation and Reduction Processes in Photocatalytic Microreaction Systems (2012)
  • Author(s): Yoshihisa Matsushita, Shinichi Ookawara, Masuomi Shimoda, Ahmed Hamza Ali, Ahmed AbdEl-Moneim, and Yoshikazu Kimura
  • Organizer: 12th International Conference on Microreaction Technology
  • Place of Presentation: University of Lyon
  • Year and Date: 2012-02-21
• [Presentation] Intensification of photochemical wastewater decolorization process by using microreactors (2012)
  • Author(s): B. Ramos,S. Ookawara, Y. Matsushita, S. Yoshikawa
  • Organizer: International Workshop on Process Intensification 2012
  • Place of Presentation: Seoul, Korea
• [Presentation] Selective Oxidation and Reduction Processes in Photocatalytic Microreaction Systems (2012)
  • Author(s): Yoshihisa Matsushita, Shinichi Ookawara, Masuomi Shimoda, Ahmed Hamza Ali, Ahmed Abd El-Moneim, and Yoshikazu Kimura
  • Organizer: 12th International Conference on Microreaction Technology
  • Place of Presentation: Lyon University of Lyon
• [Presentation] Microreaction Technology for Photocatalytic Synthesis of High-Value Added Compounds Arab Forum (2011)
  • Author(s): Yoshihisa Matsushita
  • Organizer: 2011 Industrial Applications of Nanotechnology
  • Place of Presentation: Cairo Hilton Dreamland
  • Year and Date: 2011-12-28
• [Presentation] Ahmed 高付加価値化合物合成のための多相流を用いた選択的光触媒酸化・還元プロセス化学工学会 (2011)
  • Author(s): 松下慶寿, 大川原真一, HAMZA ALI
  • Organizer: 第43回秋季大会
  • Place of Presentation: 名古屋工科大学
  • Year and Date: 2011-09-16
• [Presentation] Ahmed 並列流路型マイクロ反応デバイスを用いた光触媒による選択的酸化 (2011)
  • Author(s): Yoshihisa Matsushita, Shinichi Ookawara, and HAMZA ALI
  • Organizer: 還元プロセス光化学討論会2011
  • Place of Presentation: 宮崎市民プラザ
  • Year and Date: 2011-09-05
• [Presentation] 並列流路型マイクロ反応デバイスを用いた光触媒による選択的酸化・還元プロセス (2011)
  • Author(s): Yoshihisa Matsushita, Shinichi Ookawara, and HAMZA ALI, Ahmed
  • Organizer: 光化学討論会2011
  • Place of Presentation: 宮崎 宮崎市民プラザ
• [Presentation] 高付加価値化合物合成のための多相流を用いた選択的光触媒酸化・還元プロセス (2011)
  • Author(s): 松下慶寿, 大川原真一, HAMZA ALI, Ahmed
  • Organizer: 化学工学会 第43回秋季大会
  • Place of Presentation: 名古屋 名古屋工科大学
• [Presentation] Microreaction Technology for Photocatalytic Synthesis of High-Value Added Compounds (2011)
  • Author(s): Yoshihisa Matsushita
  • Organizer: Arab Forum 2011 Industrial Applications of Nanotechnology
  • Place of Presentation: Cairo Hilton Dreamland
• [Patent(Industrial Property Rights)] マイクロ流路装置、及びマイクロ流路 (2012)
  • Inventor(s): 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Holder: 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-164644
  • Filing Date: 2012-07-25
  • Overseas
• [Patent(Industrial Property Rights)] マイクロ流路装置、及びマイクロ流路 (2012)
  • Inventor(s): 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Holder: 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-164643
  • Filing Date: 2012-07-25
  • Overseas
• [Patent(Industrial Property Rights)] マイクロリアクタ装置、及びマイクロ流路 (2012)
  • Inventor(s): 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Holder: 大川原真一、下山裕介、松下慶寿、吉川史郎、小林博樹
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-164644
  • Filing Date: 2012-07-25