| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Research Abstract |
Synthesis of sulfuration reagents acting as a sulfur-atom donor and their sulfuration ability were studied. As a result, we reveald that methoxycarbonylsulfenyl chloride is a suitable sulfur-atom donor for one-pot synthesis of thiiranes from alkenes, and hydrogen bonding of hydroxy groups in isolated silanols to reactants participates in solid-state thiiranation of alkenes with 3H-1,2-benzodithiole-3-one 1,1-dioxide and silica gel.
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