| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
(peroxo)Fe(III)2 complexes having various core structures were prepared and their oxidation reactivity towards external substrates were investigated. (peroxo)Fe(III)2 complex with a triphenylacetate bridge is capable of the oxidation of aliphatic C-H bonds having BDEs from 74-92 kcal/mol. A mononuclear peracetatoiron(III) complex with a tripodal ligand was also prepared. This comples is the first example of a structurally and spectroscopically well-defined non-heme type peracetatoiron(III) complex and has modest oxidation ability toward triphenyl phosphine, some olefins, and the tertiary C-H bond of adamantane.
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