| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Research Abstract |
In this project, the precision synthesis of side-chain reactive conjugated polymers carrying functional groups and the formation of three-dimensional network structure using polymer reactions were investigated.
The control of molecular weight and head-to-tail structure were achieved in the synthesis of polythiophene derivatives with pyridine and pyrimidine, and the increase of planarity and the elongation of effective conjugation length were confirmed. By using the basicity of nitrogen heterocycles, the conjugated polymer nano-aggregate was obtained. The conjugated polymer nano gel was also obtained by the one-pot two-stage protocol.
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