Design and Development of Complex with Light-harvesting Molecule, Artificial Co-enzyme and Formate Dehydrogenase for Carbon Dioxide Fuelization
| Project/Area Number |
23560947
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Biofunction/Bioprocess
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| Research Institution | Osaka City University (2013-2014)
Oita University (2011-2012) |
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Principal Investigator |
AMAO YUTAKA 大阪市立大学, 複合先端研究機構, 教授 (80300961)
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| Project Period (FY) |
2011-04-28 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 人工光合成 / 二酸化炭素還元 / 人工補酵素 / ソーラー燃料生成 / 酵素反応速度論 / ギ酸脱水素酵素 / 光捕集分子 / 酵素反応 / 光誘起電子移動 / 低炭素燃料 |
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| Outline of Final Research Achievements |
In this study, design and development of complex with light-harvesting molecule, artificial co-enzyme and formate dehydrogenase for carbon dioxide fuelization were studied. The results are as follows.
(1) The suitable artificial co-enzyme for formate dehydrogenase was designed and synthesized. Relationship between the catalytic activity of formate dehydrogenase and chemical structure of artificial co-enzyme was clarified.
(2) The complex with light-harvesting molecule and artificial co-enzyme was was designed and synthesized. Photochemical and physical properties of the complex were clarified using fluorescence spectroscopy.
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Report
(5 results)
Research Products
(54 results)
