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Supra-Macromolecular Engineering with Orthogonal Molecular Design: Functional Materials with Self-Assembled Macromolecules

Research Project

Project/Area Number 23685024
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

MAKOTO Ouchi  京都大学, 工学(系)研究科(研究院), 准教授 (90394874)

Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥28,990,000 (Direct Cost: ¥22,300,000、Indirect Cost: ¥6,690,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2011: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords高分子合成 / 自己組織化 / ブロック共重合体 / リビング重合 / 開始剤 / モノマー / 超分子 / 相分離 / 超分子化学 / ナノ材料 / 高分子構造・物性 / 精密重合 / ラジカル重合 / カチオン重合 / 切断 / 水素結合 / ブロックコポリマー
Outline of Final Research Achievements

My purpose in this research is directed toward development of the concept of “supra macromolecular engineering” where structural and function factors are embedded into initiators and monomers to manipulate self-assembling functions of resultant block copolymers. I actually synthesized the following block copolymers to study the self-assembled structures and functions: cleavable block copolymers, supra block copolymers from well-defined polymers carrying complementary multiple hydrogen-bonding sites, ring-based block copolymers, block copolymers involving alternating sequence segment, block copolymers of unique connections.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (61 results)

All 2015 2014 2013 2012 2011 Other

All Journal Article (14 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 1 results) Presentation (41 results) (of which Invited: 14 results) Book (1 results) Remarks (5 results)

  • [Journal Article] Chain extension of center-functionalized polystyrene via radical–radical coupling: Periodic introduction of complementary hydrogen bonding interaction site on polymer chain2015

    • Author(s)
      Sang-Ho Lee, Makoto Ouchi, Mitsuo Sawamoto
    • Journal Title

      European Polymer Journal

      Volume: 62 Pages: 400-408

    • DOI

      10.1016/j.eurpolymj.2014.08.027

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ring-Expansion Living Cationic Polymerization of Vinyl Ethers: Optimized Ring Propagation2015

    • Author(s)
      H. Kammiyada, M. Ouchi, M. Sawamoto
    • Journal Title

      Macromolecular Symposia

      Volume: 350 Issue: 1 Pages: 105-116

    • DOI

      10.1002/masy.201400044

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functionalization at the Central Position of Vinyl Polymer Chains: Highly Associable Multipoint Hydrogen Bonds for Complementary Self-Assemblies2014

    • Author(s)
      Lee, S.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 35 Issue: 4 Pages: 431-436

    • DOI

      10.1002/marc.201300833

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ring-Expansion Living Cationic Polymerization via Reversible Activation of a Hemiacetal Ester Bond2013

    • Author(s)
      Kammiyada, H.; Konishi, A.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      ACS Macro Letters

      Volume: 2 Issue: 6 Pages: 531-534

    • DOI

      10.1021/mz400191t

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sequence-Controlled Polymer2013

    • Author(s)
      Lutz, J. F.; Ouchi, M.; Liu, D. R.; Sawamoto, M.
    • Journal Title

      Science

      Volume: 341 Issue: 6146 Pages: 628-636

    • DOI

      10.1126/science.1238149

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chain Center-Functionalized Amphiphilic Block Polymers: Complementary Hydrogen Bond Self-Assembly in Aqueous Solution2013

    • Author(s)
      Lee, S.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      Journal of Polymer Science Part A: Polymer Chemistry

      Volume: 51 Issue: 21 Pages: 4498-4504

    • DOI

      10.1002/pola.26880

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 精密ラジカル重合の展開:反応制御と機能性分子鎖の精密構築2013

    • Author(s)
      大内誠, 寺島崇矢, 澤本光男
    • Journal Title

      高分子

      Volume: 62 Pages: 252-255

    • NAID

      10031166699

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular X-Shaped Homopolymers and Block Polymers by Midsegment Complementary Hydrogen Bonds: Design of Bifunctional Initiators with Interactive Sites for Metal-Catalyzed Living Radical Polymerization2012

    • Author(s)
      Lee, S.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 9 Pages: 3702-3710

    • DOI

      10.1021/ma300479s

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Consecutive living polymerization from cationic to radical: a straightforward yet versatile methodology for the precision synthesis of "cleavable'' block copolymers with a hemiacetal ester junction2012

    • Author(s)
      Ouchi, M.; Konishi, A.; Takenaka, M.; Sawamoto, M.
    • Journal Title

      Polymer Chemistry

      Volume: 3 Issue: 8 Pages: 2193-2199

    • DOI

      10.1039/c2py20211e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 生体高分子に迫る―モノマー配列プログラミング重合2012

    • Author(s)
      大内誠,澤本光男
    • Journal Title

      月刊化学

      Volume: 67 Pages: 70-71

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Living Radical Polymerization with Active Catalysts-Promotion of Catalytic Cycle via Dynamic Transformation of the Metal Complex2011

    • Author(s)
      大内 誠,澤本 光男
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 68 Issue: 5 Pages: 289-306

    • DOI

      10.1295/koron.68.289

    • NAID

      130004489322

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sequence-Regulated Radical Polymerization with a Metal-Templated Monomer : Repetitive ABA Sequence by Double Cyclopolymerization2011

    • Author(s)
      Hibi, Y.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      Angewandte Chemie-International Edition

      Volume: 50 Issue: 32 Pages: 7434-7437

    • DOI

      10.1002/anie.201103007

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Designer Template Initiator for Sequence Regulated Polymerization : Systems Design for Substrate-Selective Metal-Catalyzed Radical Addition and Living Radical Polymerization2011

    • Author(s)
      Ida, S.; Ouchi, M.; Sawamoto, M.
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 32 Issue: 2 Pages: 209-214

    • DOI

      10.1002/marc.201000503

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single-chain technology using discrete synthetic macromolecules2011

    • Author(s)
      Ouchi, M.; Badi, N.; Lutz, JF; Sawamoto, M.
    • Journal Title

      Nature Chemistry

      Volume: 3 Issue: 12 Pages: 917-924

    • DOI

      10.1038/nchem.1175

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 結合を操って構築する創造性分子鎖: 位置・配列・形態の制御による機能創出2015

    • Author(s)
      大内 誠
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Type of Well-Defined Macromolecular Architectures: Ring-Based and Sequence-Controlled Polymers2015

    • Author(s)
      Makoto Ouchi
    • Organizer
      ESPCI講演会
    • Place of Presentation
      ESPCI(フランス,パリ)
    • Year and Date
      2015-03-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 機能性ナノ構造に向けた高分子鎖における位置・配列・形態の制御2014

    • Author(s)
      大内誠
    • Organizer
      第63回高分子学会討論会
    • Place of Presentation
      長崎大学,長崎県長崎市文教町
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 微細パターンニングに向けたPMMA-PSブロックコポリマー:セグメントシークエンスとセグメントジャンクションの緻密設計2014

    • Author(s)
      小野寛大,大内誠,澤本光男
    • Organizer
      第63回高分子学会討論会
    • Place of Presentation
      長崎大学,長崎県長崎市文教町
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 自己組織化高分子を用いたラジカル集積場の構築2014

    • Author(s)
      辻真也,大内誠,澤本光男
    • Organizer
      第63回高分子学会討論会
    • Place of Presentation
      長崎大学,長崎県長崎市文教町
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 特異結合を組み込んだ精密重合:機能性基の位置・配列制御と鎖形態の制御2014

    • Author(s)
      大内 誠
    • Organizer
      高分子四国講演会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2014-09-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 自己組織化・ミクロ相分離可能な短鎖ブロックコポリマー2014

    • Author(s)
      小野寛大,藤村幸次郎,大内誠,澤本光男
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 炭素ラジカルを組み込んだ自己組織化ポリマー2014

    • Author(s)
      辻真也,大内誠,澤本光男
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Catalytic Precision Radical Polymerization : Development of Highly Active Catalyst and Sequence-Controlled System2011

    • Author(s)
      Makoto Ouchi
    • Organizer
      KIPS-ESPCI Workshop on Polymer Science 2011
    • Place of Presentation
      京都大学(京都)(招待講演)
    • Year and Date
      2011-11-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Corporative Self-Assembly of Supramolecular Block Copolymers Carrying Mid-Chain Complementary Hydrogen-Bonding Sites2011

    • Author(s)
      李商豪, 大内誠, 澤本光男
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山)
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 二種類のリビング重合による切断性ブロックコポリマーの簡易精密合成と秩序構造体の形成2011

    • Author(s)
      小西彬人, 大内誠, 澤本光男
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山)
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Template-Directed Radical Polymerizations toward Sequence Regulation2011

    • Author(s)
      Makoto Ouchi
    • Organizer
      5th Pacific Symposium on Radical Chemistry PSRC-5
    • Place of Presentation
      ホテルシーモア(和歌山県白浜)(招待講演)
    • Year and Date
      2011-09-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sequence Regulation in Radical Polymerization with Designer Template Molecules2011

    • Author(s)
      Makoto Ouchi
    • Organizer
      242nd American Chemical Society National Meeting
    • Place of Presentation
      コロラド州デンバー(アメリカ)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属触媒精密ラジカル重合:触媒高活性化とモノマー配列制御に向けた分子デザイン2011

    • Author(s)
      大内誠
    • Organizer
      高分子学会第57回高分子研究会(神戸)
    • Place of Presentation
      兵庫県民会館(神戸)(招待講演)
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] アセタールおよびα-ハロエステル型開始剤によるリビング重合:切断性ブロックコポリマーの精密合成2011

    • Author(s)
      小西彬人, 大内誠, 澤本光男
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Design of Complementary Hydrogen-Bonded Bifunctional Initiators for Living Radical Polymerization-Corporative Self-Assembly of Block Copolymers with Hydrogen Bond Interaction2011

    • Author(s)
      李商豪, 大内誠, 澤本光男
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sequence-Controlled Vinyl Polymers via Radical-Mediated Reactions/Polymerizations

    • Author(s)
      Makoto Ouchi
    • Organizer
      European Polymer Federation (EPF 2013)
    • Place of Presentation
      Congress Palace (イタリア,ピサ)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Sequence-Controlled Vinyl Polymers by Chain Growth Control of Radical Species

    • Author(s)
      Makoto Ouchi
    • Organizer
      246th ACS National Meeting
    • Place of Presentation
      Hyatt Regency Indianapolis(アメリカ インディアナ州)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] New Developments on Precision Chain-Growth Polymerizations: Control of Position, Sequence, and Topology

    • Author(s)
      Makoto Ouchi
    • Organizer
      Seminar, Henkel Corporation
    • Place of Presentation
      Rocky Hill Henkel(アメリカ コネチカット州)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Advanced Precision Polymerizations: Control of Position, Sequence, and Topology for Vinyl Polymers

    • Author(s)
      Makoto Ouchi
    • Organizer
      The 1st ETH-Kyoto Symposium
    • Place of Presentation
      スイス連邦工科大学(ETH) (スイス チューリッヒ)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Next-Generation Precision Polymerizations: Precise Control of Position, Sequence, and Topology for Polymer Chains

    • Author(s)
      Makoto Ouchi
    • Organizer
      KIPS-ESPCI 2013 Meeting
    • Place of Presentation
      ESPCI (フランス パリ)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Advanced Precision Polymerizations via Design of Bond Singularity: Control of Sequence and Topology

    • Author(s)
      Makoto Ouchi
    • Organizer
      IUPAC International Symposium on Ionic Polymerization 2013
    • Place of Presentation
      淡路夢舞台国際会議場(兵庫県淡路市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 相補的相互作用部位を精密に導入した高分子の合成とその自己組織化挙動

    • Author(s)
      李 商豪,大内 誠,澤本 光男
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      国立京都国際会館(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 環拡大リビングカチオン重合とリビングラジカル重合の融合:環状鎖と直鎖から成るブロック共重合鎖の構築

    • Author(s)
      上宮田 源,大内 誠,澤本 光男
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      国立京都国際会館(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 炭素ラジカル集積に向けた自己組織化ポリマーの精密合成

    • Author(s)
      辻 真也,大内 誠,澤本 光男
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      金沢大学(金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アセトアルデヒド-ビニルアルコール互変異性制御を目指した水酸基認識ポリマーの精密合成

    • Author(s)
      田 淞元,大内 誠,澤本 光男
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      金沢大学(金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 環拡大リビングカチオン重合: 高分子鎖のかたちを操る開始剤設計

    • Author(s)
      上宮田 源,大内 誠,澤本 光男
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      金沢大学(金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 結合を操って究める精密重合:合成高分子の新境地に向けて

    • Author(s)
      大内 誠
    • Organizer
      第三回 次世代の物質科学・ナノサイエンスを探る
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 直交性二足歩行型テンプレートによる連鎖配列制御

    • Author(s)
      日比 裕理,大内 誠,澤本 光男
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 相補的水素結合による超分子ブロックポリマー

    • Author(s)
      李 商豪,大内 誠,澤本 光男
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 重合場構築によるモノマー選択性精密ラジカル重合

    • Author(s)
      小西 彬人,大内 誠,澤本 光男
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Designer Templates for Sequence Regulation in Radical Polymerizations

    • Author(s)
      Makoto Ouchi
    • Organizer
      The 11th International Symposium on Organic Free Radical (ISOFR-11)
    • Place of Presentation
      ベルン(スイス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 結合特異点の設計による高分子鎖精密構築

    • Author(s)
      大内 誠
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 配列制御を志向するペプチド鋳型ラジカル重合:アミノ酸開始剤/モノマーの分子設計

    • Author(s)
      中西 智哉,大内 誠,澤本 光男
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二足歩行型テンプレートによる連鎖配列制御:付加・切断・再生を繰り返す連続ラジカル反応

    • Author(s)
      日比 裕理,大内 誠,澤本 光男
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 「おたまじゃくし型」環状アセタール高分子の精密合成に向けた分子デザイン

    • Author(s)
      上宮田 源,大内 誠,澤本 光男
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 生体高分子に迫る高度精密重合:シークエンス制御に向けた分子設計

    • Author(s)
      大内 誠
    • Organizer
      平成24年度北陸地区高分子若手研究会
    • Place of Presentation
      すかっとランド九頭竜(福井県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Sequence - Next Structural Factor in Synthetic Polymers for Advanced Functions

    • Author(s)
      Makoto Ouchi
    • Organizer
      Kyoto DSA Workshop
    • Place of Presentation
      京都大学桂キャンパス(京都府)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Sequence-Programmed Radical Polymerizations with Designer Templates

    • Author(s)
      Makoto Ouchi and Mitsuo Sawamoto
    • Organizer
      The 9th International Polymer Conference (IPC 2012)
    • Place of Presentation
      神戸国際会議場(兵庫県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Sequence Regulated Radical Polymerization with Template Molecules

    • Author(s)
      Yusuke Hibi, Makoto Ouchi, and Mitsuo Sawamoto
    • Organizer
      The 9th International Polymer Conference (IPC 2012)
    • Place of Presentation
      神戸国際会議場(兵庫県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Precision Synthesis of Sequence-Controlled Polymer Chains

    • Author(s)
      Makoto Ouchi
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] Science of Synthesis, Water in Organic Synthesis2011

    • Author(s)
      Makoto Ouchi, Mitsuo Sawamoto
    • Total Pages
      20
    • Publisher
      Thieme
    • Related Report
      2011 Annual Research Report
  • [Remarks] 研究者の所属研究室

    • URL

      http://living.polym.kyoto-u.ac.jp/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究者の所属研究室

    • URL

      http://living.polym.kyoto-u.ac.jp/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://living.polym.kyoto-u.ac.jp/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 大内誠紹介ページ

    • URL

      http://living.polym.kyoto-u.ac.jp/ouchi.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://living.polym.kyoto-u.ac.jp/index.html

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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