Rational Synthesis and Properties Evaluation of Oligoacene Derivatives
Project/Area Number |
23685030
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Research Category |
Grant-in-Aid for Young Scientists (A)
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Allocation Type | Single-year Grants |
Research Field |
Functional materials chemistry
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Research Institution | Nara Institute of Science and Technology (2012-2013) Kyoto University (2011) |
Principal Investigator |
ARATANI Naoki 奈良先端科学技術大学院大学, 物質創成科学研究科, 准教授 (60372562)
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Project Period (FY) |
2011-04-01 – 2014-03-31
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Project Status |
Completed (Fiscal Year 2013)
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Budget Amount *help |
¥29,510,000 (Direct Cost: ¥22,700,000、Indirect Cost: ¥6,810,000)
Fiscal Year 2013: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2012: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2011: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
|
Keywords | アセン / ナノ材料 / 合成化学 / 構造・機能 |
Research Abstract |
Acenes are typical aromatic hydrocarbons composed of linearly fused benzene rings and of contemporary interest from a practical standpoint as functional organic materials. One of the rational synthetic routes to the oligoacene is that the reduction of the oligoacene quinone after introduction of substituents at the ketone parts. We have already succeeded in synthesis of the largest oligoacenequinone, nonacenequinone (9 benzene rings), and in its transformation to the quinoneimine with anilines. Reduction of the imine gave the UV-vis absorption spectrum up to 1100 nm. We have also succeeded in synthesis of a directly linked pentacene dimer. We are trying to make FET devices based on it.
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Report
(4 results)
Research Products
(101 results)
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[Journal Article] Synthesis and optical reactivity of 6,13-a-diketoprecursors of 2,3,9,10-tetraalkylpentacenes in solution, film and crystals2014
Author(s)
S. Katsuta, H. Saeki, K. Tanaka, Y. Murai, D. Kuzuhara, M. Misaki, N. Aratani, S. Masuo, Y. Ueda, H. Yamada
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Journal Title
J. Mater. Chem. C
Volume: 2
Issue: 6
Pages: 986-993
DOI
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Peer Reviewed
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[Journal Article] η^5-Cyclopentadienyliron (II)-[14] Triphyrin (2.1.1) Sandwich Compounds : Synthesis,Characterization,and Stable Redox Interconversion2013
Author(s)
Z. Xue,D. Kuzuhara,S. Ikeda,Y. Sakakibara,K. Ohkubo,N. Aratani,T. Okujima,H. Uno,S. Fukuzumi,H. Yamada
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Journal Title
Angew. Chem. Int. Ed
Volume: 52
Pages: 7306-7306
NAID
Related Report
Peer Reviewed
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[Journal Article] η5-Cyclopentadienyl-Iron(II)-[14]Triphyrin(2.1.1) Sandwich Compounds: Synthesis, Characterization, and Stable Redox Interconversion2013
Author(s)
Zhaoli Xue, Daiki Kuzuhara, Shinya Ikeda, Yuka Sakakibara, Kei Ohkubo, Naoki Aratani, Tetsuo Okujima, Hidemitsu Uno, Shunichi Fukuzumi and Hiroko Yamada
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Journal Title
Angew. Chem. Int. Ed.
Volume: 52
Issue: 28
Pages: 7306-7309
DOI
NAID
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Peer Reviewed
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[Journal Article] Kinetically Blocked Stable Heptazethrene and Octazethrene : Closed-Shell or Open-Shell in the Ground State?2012
Author(s)
Y. Li,W.-K. Heng,B. S. Lee,N. Aratani,J. L. Zafra,N. Bao,R. Lee,Y. M. Sung,Z. Sun,K.-W. Huang,R. D. Webster,J. T. López Navarrete,D. Kim,A. Osuka,J. Casada,J. Ding,J. Wu
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Journal Title
J. Am. Chem. Soc
Volume: 134
Pages: 14913-14913
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Peer Reviewed
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[Journal Article] Kinetically Blocked Stable Heptazethrene and Octazethrene: Closed-Shell or Open-Shell in the Ground State?2012
Author(s)
Y. Li, W.-K. Heng, B. S. Lee, N. Aratani, J. L. Zafra, N. Bao, R. Lee, Y. M. Sung, Z. Sun, K.-W. Huang, R. D. Webster, J. T. Lopez Navarrete, D. Kim, A. Osuka, J. Casada, J. Ding, and J. Wu
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Journal Title
J. Am. Chem. Soc.
Volume: 134
Issue: 36
Pages: 14913-14922
DOI
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Peer Reviewed
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[Journal Article] Synthesis of Carbazole-Containing Porphyrinoids by a Multiple Annulation Strategy : A Core-Modified and π-Expanded Porphyrin2011
Author(s)
Maeda, C., Yoneda, T., Aratani, N., Yoon, M-C., Lim, J.M., Kim, D., Yoshioka, N., Osuka, A.
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Journal Title
Angew.Chem., Int.Ed.
Volume: 50
Issue: 25
Pages: 5691-5694
DOI
Related Report
Peer Reviewed
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[Journal Article] Porphyrin-hexaphyrin hybrid tapes2011
Author(s)
Tanaka, T., Aratani, N., Lim, J.M., Kim, K.S., Kim, D., Osuka, A.
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Journal Title
Chem.Sci.
Volume: 2
Issue: 7
Pages: 1414-1418
DOI
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Peer Reviewed
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[Journal Article] The Role of Electronic Couplings in Linear Porphyrin Arrays Probed by Single-Molecule Fluorescence Spectroscopy2011
Author(s)
Yang, J., Lee, J-E., Lee, C.Y., Aratani, N., Osuka, A., Hupp, J.T., Kim, D.
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Journal Title
Chem.Euro.J.
Volume: 17
Issue: 33
Pages: 9219-9225
DOI
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Peer Reviewed
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[Journal Article] Synthesis of a diimidazolylporphyrin pincer palladium complex2011
Author(s)
Yamamoto, J., Shimizu, T., Yamaguchi, S., Aratani, N., Shinokubo, H., Osuka, A.
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Journal Title
J.Porphyrins Phthalocyanines
Volume: 15
Issue: 07n08
Pages: 534-538
DOI
Related Report
Peer Reviewed
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