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Atomic, Surface Structure and Hydrogen Storage Function of Aluminum-based Hydrides

Research Project

Project/Area Number 23686101
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

IKEDA KAZUTAKA  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 特任准教授 (80451615)

Research Collaborator FUJISAKI Fumika  総合研究大学院大学, 高エネルギー加速器 科学研究科, 博士過程
OHSHITA Hidetoshi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 博士研究員 (00625163)
KITAJIMA Yoshinori  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 講師 (00204892)
ABE Hitoshi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 准教授 (00509937)
OTOMO Toshiya  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (90270397)
SUZUYA Kentaro  独立行政法人日本原子力研究開発機構, J-PARCセンター, 研究主幹 (50354684)
SATO Toyoto  東北大学, 金属材料研究所, 助教 (20455851)
MATSUO Motoaki  東北大学, 金属材料研究所, 講師 (20509038)
SEMBOSHI Satoshi  東北大学, 金属材料研究所, 准教授 (00364026)
LI Hai-wen  九州大学, 水素エネルギー国際研究センター, 准教授 (20505771)
ORIMO Shin-ichi  東北大学, 金属材料研究所, 教授 (40284129)
ICHIKAWA Takayuki  広島大学, 先進機能物質研究センター, 准教授 (10346463)
KOJIMA Yoshitsugu  広島大学, 先進機能物質研究センター, 教授
TATSUMI Kazuyoshi  名古屋大学, 大学院工学研究科, 准教授 (00372532)
MUTO Shunsuke  名古屋大学, 大学院工学研究科, 教授 (20209985)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords水素 / 水素化物 / 水素貯蔵 / 中性子 / アルミニウム / 局所構造 / 結晶構造 / エネルギー
Research Abstract

Atomic, Surface Structure and Hydrogen Storage Function of Aluminum-based Hydrides were studied. We investigated the ether desorption steps for AlH3 synthesis by Pair Distribution Function analysis. Differences of the electric structure for phases in the reversible hydrogen absorption and
desorption reactions of NaAlH4 were analyzed. Local structural changes that accompany amorphization during the decomposition of LiAl(NH2)4 were investigated.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (39 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 7 results) Presentation (21 results) (of which Invited: 10 results) Book (2 results) Remarks (4 results)

  • [Journal Article] Local Structural Analysis on Decomposition Process of LiAl(ND<sub>2</sub>)<sub>4</sub>2014

    • Author(s)
      K. Ikeda, T. Otomo, H. Ohshita, N. Kaneko, M. Tsubota, K. Suzuya, F. Fujisaki, T. Ono, T. Yamanaka, K. Shimoda, T. Ichikawa, Y. Kojima
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 55 Issue: 8 Pages: 1129-1133

    • DOI

      10.2320/matertrans.MG201406

    • NAID

      130004825213

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local atomic structural investigations of precursory phenomenon of the hydrogen release from LiAlD_42014

    • Author(s)
      T. Sato, K. Tomiyasu, K. Ikeda, T. Otomo, M. Feygenson, J. Neuefeind, K. Yamada, S. Orimo
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 586 Pages: 244-247

    • DOI

      10.1016/j.jallcom.2013.09.209

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local Structural Analysis on Decomposition Process of LiAl(ND2)42014

    • Author(s)
      K. Ikeda, T. Otomo, H. Ohshita, N. Kaneko, M. Tsubota, K. Suzuya, F. Fujisaki, T. Ono, T. Yamanaka, K. Shimoda, T. Ichikawa, Y. Kojima
    • Journal Title

      Materials Transactions

      Volume: 印刷中

    • NAID

      130004825213

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高強度中性子を用いた全散乱法による水素貯蔵機構の解明2013

    • Author(s)
      大友季哉, 池田一貴, 大下英敏, 鈴谷賢太郎
    • Journal Title

      まてりあ

      Volume: 52 (7)

    • NAID

      10031183682

    • Related Report
      2013 Final Research Report
  • [Journal Article] 高強度中性子を用いた全散乱法による水素貯蔵機構の解明2013

    • Author(s)
      大友季哉、池田一貴、大下英敏、鈴谷賢太郎
    • Journal Title

      日本金属学会会報「まてりあ」

      Volume: 57 Pages: 346-349

    • NAID

      10031183682

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical bonding of AIH_3 hydride by Al-L_<2,3> electron energy-loss spectra and their first principles calculations2012

    • Author(s)
      K. Tatsumi, S. Muto, K. Ikeda, S. Orimo
    • Journal Title

      Materials

      Volume: 5 Issue: 4 Pages: 566-574

    • DOI

      10.3390/ma5040566

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Specific Heat of CaPdH_<3-δ> with the Perovskite Structure2012

    • Author(s)
      Shin-ya Ayukawa, Kazutaka Ikeda, Masatsune Kato, Takashi Noji, Shin-ichi Orimo, Yoji Koike
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 81 Issue: 3 Pages: 034704-034704

    • DOI

      10.1143/jpsj.81.034704

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] J-PARCの物質・生命科学実験施設2012

    • Author(s)
      池田一貴, 奥隆之, 鈴木淳市, 武田全康, 星川晃範, 三宅康博
    • Journal Title

      工業材料

      Volume: 60 (8)

    • Related Report
      2013 Final Research Report
  • [Journal Article] 高強度中性子全散乱装置NOVAによる水素貯蔵材料の構造解析2012

    • Author(s)
      池田一貴,大友季哉, 鈴谷賢太郎, 三沢正勝, 大下英敏, 坪田雅己, 金子直勝, 瀬谷智洋, 福永俊晴, 伊藤恵司, 亀田恭男,山口敏男, 吉田亨次, 丸山健二, 社本真一, 樹神克明, 川北至信, 藤崎布美佳
    • Journal Title

      水素エネルギーシステム

      Volume: 37 (4)

    • Related Report
      2013 Final Research Report
  • [Journal Article] 高強度中性子全散乱装置NOVAによる水素貯蔵材料の構造解析2012

    • Author(s)
      池田一貴、大友季哉、鈴谷賢太郎、三沢正勝、大下英敏、坪田雅己、金子直勝、瀬谷智洋、福永俊晴、伊藤恵司、亀田恭男、山口敏男、吉田亨次、丸山健二、社本真一、樹神克明、川北至信、藤崎布美佳
    • Journal Title

      水素エネルギーシステム

      Volume: 37 Pages: 328-335

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Vibrational Properties of CaAlH_5 andα-AlH_3 with Different AlH6 Networks Studied by Inelastic Neutron Scattering2011

    • Author(s)
      T. Sato, A.J. (Timmy) Ramirez-Cuesta, K. Ikeda, S. Orimo, K. Yamada
    • Journal Title

      Inorganic Chemistry

      Volume: 20 Issue: 17 Pages: 8007-8011

    • DOI

      10.1021/ic200231f

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] アルミニウム水素化物の合成および原子配置と水素放出特性2011

    • Author(s)
      池田一貴, 大友季哉, 武藤俊介, 折茂慎一
    • Journal Title

      セラミックス

      Volume: 46

    • NAID

      10028236111

    • Related Report
      2013 Final Research Report
  • [Presentation] Structural Study of Advanced Hydrogen Storage Materials by High Intensity Neutron Total Diffractometer (NOVA)2014

    • Author(s)
      K. Ikeda, T. Otomo, Y. Kojima, S. Orimo
    • Organizer
      3rd International Conference and Exhibition on Materials Science & Engineering
    • Place of Presentation
      San Antonio, USA
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] Structural and Hydrogen Desorption Properties of Aluminum-based Hydrogen Storage Materials2014

    • Author(s)
      K. Ikeda, T. Otomo, S. Muto, S. Orimo
    • Organizer
      2014 Energy Materials Nanotechnology (EMN) East Meeting
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] Structural and Hydrogen Desorption Properties of Aluminum Hydride2014

    • Author(s)
      K. Ikeda, T. Otomo, S. Muto, S. Orimo
    • Organizer
      1st Workshop on Hydrogen and CO2 Storage
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] XAFSによるTi添加NaAlH4におけるAl化学状態観測2014

    • Author(s)
      藤崎布美佳、大友季哉、池田一貴、大下英敏、金子直勝、瀬谷智洋、鈴谷賢太郎、松尾元彰、佐藤豊人、折茂慎一、榊浩司、中村優美子
    • Organizer
      日本金属学会2014年春期(第154回)講演大会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] In-situ Diffraction Measurements of Hydrogen Storage Materials by High-Intensity Neutron Total Diffractometer, NOVA2014

    • Author(s)
      K. Ikeda, T. Otomo, K. Suzuya, H. Ohshita, N. Kaneko, T. Seya, F. Fujisaki
    • Organizer
      14th International Symposium on Metal-Hydrogen Systems: Fundamentals and Applications
    • Place of Presentation
      Manchester, United Kingdom
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structural Analysis of Aluminum-based Hydrogen Storage Materials by High Intensity Neutron Total Diffractometer (NOVA)2013

    • Author(s)
      K. Ikeda, T. Otomo, Y. Kojima, S. Orimo
    • Organizer
      2013 International Conference on Processing & Manufacturing of Advanced Materials
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis, Atomic Structure and Hydrogen Storage Properties of Aluminum Hydride2013

    • Author(s)
      K. Ikeda, T. Otomo, S. Muto, S. Orimo
    • Organizer
      3rd International Conference on Nanotek and Expo (Nanotek-2013)
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] A High Intensity Neutron Scattering Techniques for Hydrogen Materials Studies2013

    • Author(s)
      T. Otomo, K. Suzuya, H. Ohshita, K. Ikeda, N. Kaneko, T. Seya
    • Organizer
      PRICM-8 (8th Pacific Rim International Congress on Advanced Materials and Processing)
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高強度中性子全散乱装置NOVAによる高圧ガスその場実験環境2013

    • Author(s)
      池田一貴、大下英敏、金子直勝、瀬谷智洋、大友季哉、鈴谷賢太郎、藤崎布美佳
    • Organizer
      日本中性子科学会第13回年会
    • Place of Presentation
      千葉県柏市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高強度全散乱装置NOVAの現状2013

    • Author(s)
      大友季哉、池田一貴、大下英敏、金子直勝、瀬谷智洋、鈴谷賢太郎、藤崎布美佳
    • Organizer
      日本中性子科学会第13回年会
    • Place of Presentation
      千葉県柏市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高強度中性子全散乱装置NOVAによるTi添加したNaAlD4水素吸蔵放出反応のin-situ中性子回折測定2013

    • Author(s)
      藤崎布美佳、大友季哉、池田一貴、大下英敏、金子直勝、瀬谷智洋、鈴谷賢太郎、松尾元彰、佐藤豊人、折茂慎一、榊浩司、中村優美子
    • Organizer
      日本金属学会2013年春期(第152回)講演大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高強度中性子全散乱装置NOVAによるLiAl(ND2)4の構造解析2013

    • Author(s)
      池田一貴、坪田雅己、大下英敏、金子直勝、大友季哉、鈴谷賢太郎、小野泰輔、山中俊幸、下田景士、市川貴之、小島由継
    • Organizer
      日本金属学会2013年春期(第152回)講演大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] LiAlD4の40-300Kにおける局所構造変化2013

    • Author(s)
      佐藤豊人、折茂慎一、富安啓輔、池田一貴、大友季哉、山田和芳
    • Organizer
      日本金属学会2013年春期(第152回)講演大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis, Atomic Structure and Hydrogen Storage Properties of Aluminum Hydride2013

    • Author(s)
      K. Ikeda, T. Otomo, S. Muto, S. Orimo
    • Organizer
      3rd International Conference on Nanotek and Expo
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Structural Analysis of Aluminum-based Hydrogen Storage Materials by High Intensity Neutron Total Diffractometer (NOVA)2013

    • Author(s)
      K. Ikeda, T. Otomo, Y. Kojima, S. Orimo
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials, THERMEC'2013
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Vibrational Properties on Al Based Hydrides Studied by Inelastic Neutron Scattering2012

    • Author(s)
      T. Sato, A.J. (Timmy) Ramirez-Cuesta, K. Tomiyasu, K. Ikeda, S. Orimo, K. Yamada
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2012, MH2012
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高強度全散乱装置NOVAによるLiAl(ND2)4の構造解析2012

    • Author(s)
      池田一貴、坪田雅己、大下英敏、金子直勝、大友季哉、鈴谷賢太郎、小野泰輔、山中俊幸、下田景士、市川貴之、小島由継
    • Organizer
      日本中性子科学会第12回年会
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高強度中性子全散乱装置(NOVA)によるアルミニウム水素化物の構造解析と水素放出特性2011

    • Author(s)
      池田一貴,大友季哉,武藤俊介,折茂慎一
    • Organizer
      第9回水素量子アトミクス研究会
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis, properties and applications of aluminum hydride2011

    • Author(s)
      K. Ikeda, S. Muto, T. Otomo, S. Orimo
    • Organizer
      2011 International Conference on Processing & Manufacturing of Advanced Materials
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis, properties and applications of aluminum hydride2011

    • Author(s)
      K.Ikeda, S.Muto, T.Otomo, S.Orimo
    • Organizer
      Thermec'2011 International Conference on Processing & Manufacturing of Advanced Materials
    • Place of Presentation
      Quebec, Canada(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高強度中性子全散乱装置(NOVA)によるアルミニウム水素化物の構造解析と水素放出特性2011

    • Author(s)
      池田一貴, 大友季哉, 武藤俊介, 折茂慎一
    • Organizer
      第9回水素量子アトミクス研究会
    • Place of Presentation
      仙台(宮城県)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Book] ペロブスカイト水素化物の合成と水素貯蔵特性「水素利用技術集成Vol.4」2014

    • Author(s)
      池田一貴,高木成幸,大友季哉,折茂慎一
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Final Research Report
  • [Book] 「水素利用技術集成 Vol.4」第2編第2章第3節 ペロブスカイト水素化物の合成と水素貯蔵特性2014

    • Author(s)
      池田一貴、高木成幸、大友季哉、折茂慎一
    • Total Pages
      11
    • Publisher
      ㈱エヌ・ティー・エス
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.kek.jp/imss/

    • Related Report
      2013 Final Research Report
  • [Remarks] リチウムアルミニウムアミドLiAl(ND2)4

    • URL

      http://neutron-www.kek.jp/topics/121115_report/121115_report.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] NaAlD4における水素吸蔵放出反応

    • URL

      http://neutron-www.kek.jp/topics/130207_report/130207_report.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.kek.jp/imss/

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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