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Synthesis of titanate nanotube solid acid catalysts and C-C bond formation reaction

Research Project

Project/Area Number 23686115
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionTokyo Institute of Technology

Principal Investigator

KITANO Masaaki  東京工業大学, 元素戦略研究センター, 准教授 (50470117)

Project Period (FY) 2011-11-18 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords固体酸触媒 / チタン酸ナノチューブ / 触媒・化学プロセス / 異種元素ドープ / 細孔径制御 / アルキル化 / アリル化
Research Abstract

Protonated titanate nanotubes were synthesized under various conditions and modified by doping with heteroatoms. These catalysts were applied for C-C bond formation reactions. TiO2 nanoparticles were converted into titanate nanotubes or nanorods depending on the synthesis conditions and effective Bronsted and Lewis acid sites were only formed on the
surface of the titanate nanotubes. In addition, when Nb5+ and Ta5+ ions were doped into the titanate nanotubes, the catalytic performance was enhanced by a factor of 10.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (46 results)

All 2014 2013 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (33 results)

  • [Journal Article] Highly Dispersed Ru on Electride [Ca24Al28O64]4+(e-)4 as a Catalyst for Ammonia Synthesis2014

    • Author(s)
      Y. Inoue, M. Kitano, S. W. Kim, T. Yokoyama, M. Hara, H. Hosono
    • Journal Title

      ACS Catal.

      Volume: 4 Issue: 2 Pages: 674-680

    • DOI

      10.1021/cs401044a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Acid Catalysis of TiO4 Tetrahedra on Mesoporous Silica in Water2014

    • Author(s)
      H. Shintaku, K. Nakajima, M. Kitano, N. Ichikuni, M. Hara
    • Journal Title

      ACS Catal.

      Volume: 4 Issue: 4 Pages: 1198-1204

    • DOI

      10.1021/cs401149n

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective glucose transformation by titania as a heterogeneous Lewis acid catalyst2014

    • Author(s)
      K. Nakajima, R. Noma, M. Kitano, M. Hara
    • Journal Title

      J. Mol. Cat. A

      Volume: 印刷中 Pages: 100-105

    • DOI

      10.1016/j.molcata.2013.09.012

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Treatment for Conductive 12CaO7Al2O3 Electride Powder by Rapid Thermal Annealing Processing and Its Application to Ammonia Synthesis2014

    • Author(s)
      F. Hayashi, M. Kitano, T. Yokoyama, M. Hara, H. Hosono
    • Journal Title

      ChemCatChem

      Volume: 印刷中 Issue: 5 Pages: 1317-1323

    • DOI

      10.1002/cctc.201301061

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Preparation Conditions on the Structural and Acid Catalytic Properties of Protonated Titanate Nanotubes2013

    • Author(s)
      E. Wada, M. Kitano, K. Nakajima, M. Hara
    • Journal Title

      J. Mater. Chem. A

      Volume: 1 Issue: 41 Pages: 12768-12774

    • DOI

      10.1039/c3ta13015k

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Protonated Titanate Nanotubes with Lewis and Brønsted Acidity : Relationship between Nanotube Structure and Catalytic Activity2013

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, S. Hayashi, S. Miyazaki, H. Kobayashi, M. Hara
    • Journal Title

      Chem. Mater

      Volume: 25 Issue: 3 Pages: 385-393

    • DOI

      10.1021/cm303324b

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] チタン酸ナノチューブの固体酸触媒特性2013

    • Author(s)
      北野政明,原亨和
    • Journal Title

      触媒

      Volume: 53 Pages: 340-345

    • NAID

      10029659908

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia Decomposition by Ruthenium Nanoparticles Loaded on Inorganic Electride C12A7:e-2013

    • Author(s)
      F. Hayashi, Y. Toda, Y. Kanie, M. Kitano, Y. Inoue, T. Yokoyama, M. Hara, H. Hosono
    • Journal Title

      Chem. Sci.

      Volume: 4 Issue: 8 Pages: 3124-3130

    • DOI

      10.1039/c3sc50794g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Conversion of Pyruvic Aldehyde into Lactic Acid by Lewis Acid Cataly st in Water2013

    • Author(s)
      Yusuke Koito, Kiyotaka Nakajima, Masaaki Kitano, Michikazu Hara
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 8 Pages: 873-875

    • DOI

      10.1246/cl.130319

    • NAID

      10031189280

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Titania as an Early Transition Metal Oxide with a High Density of Lewis Acid Sites workable in Water2013

    • Author(s)
      K. Nakajima, R. Noma, M. Kitano, M. Hara
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 31 Pages: 16028-16033

    • DOI

      10.1021/jp404523r

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ルテニウムを担持した12CaO7Al2O3エレクトライドによるアンモニア合成2013

    • Author(s)
      北野政明,原亨和,細野秀雄
    • Journal Title

      触媒

      Volume: 2 Pages: 239-245

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電子化物を利用したアンモニア合成用触媒材料の開発2013

    • Author(s)
      北野政明,原亨和,細野秀雄
    • Journal Title

      スマートプロセス学会誌

      Volume: 2 Pages: 293-298

    • NAID

      130004698743

    • Related Report
      2013 Annual Research Report
  • [Journal Article] チタン酸ナノチューブの固体酸触媒特性2011

    • Author(s)
      北野政明、原亨和
    • Journal Title

      触媒

      Volume: 53 Pages: 340-345

    • NAID

      10029659908

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Brønsted Acid Property of Niobium doped Titanate Nanotubes2013

    • Author(s)
      M. Kitano, K. Yamamoto, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      5th Gratama Workshop
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-31
    • Related Report
      2013 Final Research Report
  • [Presentation] Taを添加したチタン酸ナノチューブの固体酸触媒特性2013

    • Author(s)
      北野政明・森田一輝・山本一登・中島清隆・原亨和
    • Organizer
      石油学会第56回年会(第62回研究発表会)
    • Place of Presentation
      タワーホール船堀,東京
    • Year and Date
      2013-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Taドープしたチタン酸ナノチューブの固体酸触媒特性2013

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学,大阪
    • Year and Date
      2013-03-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Taを添加したチタン酸ナノチューブの固体酸触媒特性2013

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学,滋賀
    • Year and Date
      2013-03-22
    • Related Report
      2013 Final Research Report
  • [Presentation] チタン酸ナノチューブの構造歪みと酸触媒特性との相関の解明2013

    • Author(s)
      北野政明,森田一輝,山本一登,中島清隆,原亨和
    • Organizer
      第43回石油・石油化学討論会(北九州大会)
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of Structural Distortion on the Brønsted Acidity of the Titanate Nanotubes2013

    • Author(s)
      M. Kitano, K. Nakajima, H. Kobayashi, M. Hara
    • Organizer
      8th International Mesostructured Materials Symposium
    • Place of Presentation
      Awaji
    • Related Report
      2013 Final Research Report
  • [Presentation] Evaluation of Catalytic Properties of Nb-doped Titanate Nanotubes2013

    • Author(s)
      M. Kitano, K. Yamamoto, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      Evaluation of Catalytic Properties of Nb-doped Titanate Nanotubes
    • Place of Presentation
      TKP Garden City Shinagawa, Tokyo
    • Related Report
      2013 Final Research Report
  • [Presentation] Evaluation of Catalytic Properties of Nb-doped Titanate Nanotubes2013

    • Author(s)
      Masaaki Kitano, Kazuto Yamamoto, Kiyotaka Nakajima, Shigenobu Hayashi, Michikazu Hara
    • Organizer
      7th International Symposium on Acid-Base Catalysis (ABC-7)
    • Place of Presentation
      TKP Garden City Shinagawa, Tokyo
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of Structural Distortion on the Bronsted Acidity of the Titanate Nanotubes2013

    • Author(s)
      Masaaki Kitano, Kiyotaka Nakajima, Hisayoshi Kobayashi, Michikazu Hara
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS-8, IMMS2013)
    • Place of Presentation
      Awaji Yumebutai International Conference Center (AYICC), Awaji
    • Related Report
      2013 Annual Research Report
  • [Presentation] Bronsted Acid Property of Niobium doped Titanate Nanotubes2013

    • Author(s)
      Masaaki Kitano, Kazuto Yamamoto, Kiyotaka Nakajima, Shigenobu Hayashi, Michikazu Hara
    • Organizer
      5th Gratama Workshop
    • Place of Presentation
      Tokyo Institute of Technology, Tokyo
    • Related Report
      2013 Annual Research Report
  • [Presentation] チタン酸ナノチューブの構造歪みと酸触媒特性との相関の解明2013

    • Author(s)
      北野政明、森田一輝、山本一登、中島清隆、原亨和
    • Organizer
      第43回石油・石油化学討論会(北九州大会)
    • Place of Presentation
      北九州国際会議場、福岡
    • Related Report
      2013 Annual Research Report
  • [Presentation] リン酸処理したチタン酸ナノチューブの触媒特性2012

    • Author(s)
      山本一登・北野政明・中島清隆・原亨和
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学,東京
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 表面フッ素修飾したチタン酸ナノチューブの構造解析と酸触媒特性2012

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学大岡山キャンパス,東京
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Solid Acid Catalysis of Protonated Titanate Nanotubes : Effect of Structural Distortion on the Acidity of the Titanate Nanotubes2012

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      International Symposium on Zeolites and MicroPorous Crystals 2012
    • Place of Presentation
      ASTER PLAZA, Hiroshima,Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Nb doped titanate nanotubes as solid acid catalysts2012

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      5th International Congress on Catalysis 2012
    • Place of Presentation
      Munich, Germany
    • Related Report
      2013 Final Research Report
  • [Presentation] チタン酸ナノチューブの固体酸触媒特性の解明2012

    • Author(s)
      北野政明・中島清隆・宮崎聡一・小林久芳・林繁信・原亨和
    • Organizer
      第1回JACI/GSCシンポジウム
    • Place of Presentation
      ベルサール神田,東京
    • Related Report
      2013 Final Research Report
  • [Presentation] ニオブドープチタン酸ナノチューブの固体酸触媒特性2012

    • Author(s)
      北野政明・中島清隆・林繁信・原亨和
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶應義塾大学,東京
    • Related Report
      2013 Final Research Report
  • [Presentation] ニオブドープチタン酸ナノチューブの固体酸触媒特性2011

    • Author(s)
      北野政明
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶應義塾大学、東京
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Evaluation of Catalytic Properties of Protonated Titanate Nanotubes2011

    • Author(s)
      Masaaki Kitano
    • Organizer
      The Fifth International Conference on the Science and Technology for Advanced Ceramics (STAC-5) and The 2nd International Conference on Advanced Materials Development and Integration of Novel Structured Metallic and Inorganic Materials (AMDI2)
    • Place of Presentation
      Mielparque-Yokohama, Yokohama, Japan
    • Year and Date
      2011-06-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Structural and Catalytic Properties of Protonated Titanate Nanotubes2011

    • Author(s)
      Masaaki Kitano
    • Organizer
      The 13^<th> Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Seogwipo KAL Hotel, Korea
    • Year and Date
      2011-05-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] チタン酸ナノチューブの固体酸触媒特性と作用機構2011

    • Author(s)
      北野政明・中島清隆・宮崎聡一・小林久芳・林繁信・原亨和
    • Organizer
      石油化学討論会
    • Place of Presentation
      秋田キャッスルホテル,秋田
    • Related Report
      2013 Final Research Report
  • [Presentation] Nb添加チタン酸ナノチューブの固体酸触媒特性2011

    • Author(s)
      北野政明・中島清隆・野村淳子・林繁信・原亨和
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学,北海道
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Evaluation of Catalytic Properties of Protonated Titanate Nanotubes2011

    • Author(s)
      M. Kitano, K. Nakajima, J. N. Kondo, S. Hayashi, M. Hara
    • Organizer
      The Fifth International Conference on the Science and Technology for Advanced Ceramics
    • Place of Presentation
      Mielparque-Yokohama, Yokohama, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Structural and Catalytic Properties of Protonated Titanate Nanotubes2011

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, J. N. Kondo, S. Hayashi
    • Organizer
      The 13^<th> Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Seogwipo KAL Hotel, Jeju Island, Korea
    • Related Report
      2013 Final Research Report
  • [Presentation] Taを添加したチタン酸ナノチューブの固体酸触媒特性

    • Author(s)
      北野政明、森田一輝、山本一登、中島清隆、原亨和
    • Organizer
      石油学会第56回年会(第62回研究発表会)
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] チタン酸ナノチューブの固体酸触媒特性の解明

    • Author(s)
      北野政明・中島清隆・宮崎聡一・小林久芳・林繁信・原亨和
    • Organizer
      第1回 JACI/GSCシンポジウム(第12回 GSCシンポジウム)
    • Place of Presentation
      ベルサール神田,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nb doped titanate nanotubes as solid acid catalysts

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      15th International Congress on Catalysis 2012
    • Place of Presentation
      Munich, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] Solid Acid Catalysis of Protonated Titanate Nanotubes: Effect of Structural Distortion on the Acidity of the Titanate Nanotubes

    • Author(s)
      M. Kitano, E. Wada, K. Nakajima, S. Hayashi, M. Hara
    • Organizer
      International Symposium on Zeolites and MicroPorous Crystals 2012 (ZMPC2012)
    • Place of Presentation
      ASTER PLAZA, Hiroshima,Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] チタン酸ナノチューブの固体酸触媒特性と作用機構

    • Author(s)
      北野政明・中島清隆・宮崎聡一・小林久芳・林繁信・原亨和
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田キャッスルホテル、秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 表面フッ素修飾したチタン酸ナノチューブの構造解析と酸触媒特性

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      第2回CSJ化学フェスタ 2012
    • Place of Presentation
      東京工業大学大岡山キャンパス, 東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] リン酸処理したチタン酸ナノチューブの触媒特性

    • Author(s)
      山本一登・北野政明・中島清隆・原亨和
    • Organizer
      第2回CSJ化学フェスタ 2012
    • Place of Presentation
      東京工業大学大岡山キャンパス,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Taを添加したチタン酸ナノチューブの固体酸触媒特性

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学 びわこ・くさつキャンパス,滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] Taドープしたチタン酸ナノチューブの固体酸触媒特性

    • Author(s)
      森田一輝・北野政明・中島清隆・原亨和
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学千里山キャンパス,大阪
    • Related Report
      2012 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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