Synthesis of titanate nanotube solid acid catalysts and C-C bond formation reaction
| Project/Area Number |
23686115
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
KITANO Masaaki 東京工業大学, 元素戦略研究センター, 准教授 (50470117)
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| Project Period (FY) |
2011-11-18 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
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| Keywords | 固体酸触媒 / チタン酸ナノチューブ / 触媒・化学プロセス / 異種元素ドープ / 細孔径制御 / アルキル化 / アリル化 |
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| Research Abstract |
Protonated titanate nanotubes were synthesized under various conditions and modified by doping with heteroatoms. These catalysts were applied for C-C bond formation reactions. TiO2 nanoparticles were converted into titanate nanotubes or nanorods depending on the synthesis conditions and effective Bronsted and Lewis acid sites were only formed on the
surface of the titanate nanotubes. In addition, when Nb5+ and Ta5+ ions were doped into the titanate nanotubes, the catalytic performance was enhanced by a factor of 10.
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Report
(4 results)
Research Products
(46 results)
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[Presentation] Evaluation of Catalytic Properties of Protonated Titanate Nanotubes2011
Author(s)
Masaaki Kitano
Organizer
The Fifth International Conference on the Science and Technology for Advanced Ceramics (STAC-5) and The 2nd International Conference on Advanced Materials Development and Integration of Novel Structured Metallic and Inorganic Materials (AMDI2)
Place of Presentation
Mielparque-Yokohama, Yokohama, Japan
Year and Date
2011-06-23
Related Report
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