Development of catalytic oxidative coupling reaction using redox property of halide Ions
| Project/Area Number |
23750042
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kochi University |
|---|
Principal Investigator |
NAGANO Takashi 高知大学, 教育研究部自然科学系, 助教 (80500587)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
|
|---|
| Keywords | グリーンケミストリー / 酸化反応 / 脱水素カップリング反応 / ハロゲン / ハロゲン化物イオン / CDC反応 / カップリング反応 |
|---|
| Research Abstract |
We have studied on catalytic cross-dehydrogenative coupling (CDC) reaction using redox property of halide ions. In the course of this study, we have developed (i) intramolecular carbon-oxygen-bond-forming reaction using iodide ion/oxygen gas, (ii) intramolecular carbon-carbon-bond-forming reaction using iodide ion/TBHP, and (iii) alcohol oxidation using bromide ion/hydrogen peroxide.
|
Report
(3 results)
Research Products
(13 results)
