• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Function of ion transport in 1-D channels of porous coordination polymer

Research Project

Project/Area Number 23750155
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionKyoto University

Principal Investigator

HORIKE Satoshi  京都大学, 工学研究科・合成・生物化学専攻, 助教 (70552652)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsイオン伝導 / 錯体化学 / 固体 NMR / 配位高分子 / イオン伝導体 / 錯体 / 固体NMR
Research Abstract

Coordination polymer having 1 nm of 1-D channels are suitable to accommodate the proton carrier molecules and we observed the anhydrous proton conductivity above 100 degC. The accommodated azoles are able to rotate in solid state, and the dynamic behavior provides the anhydrous proton conduction. The conductivity were monitored by solid state NMR and impedance spectroscopy, and the optimized structure shows over 10-3S/cm of conductivity.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (55 results)

All 2013 2012 2011

All Journal Article (35 results) (of which Peer Reviewed: 35 results) Presentation (9 results) (of which Invited: 2 results) Book (11 results)

  • [Journal Article] Post-synthesis modification of a porous coordination polymer by LiCl to enhance H+ transpor2013

    • Author(s)
      Satoshi Horike, Yusuke Kamitsubo, Munehiro Inukai, Tomohiro Fukushima, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 135 Pages: 4612-4615

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pore design of two-dimensional coordination polymers toward selective adsorption2013

    • Author(s)
      Yuh Hijikata, Satoshi Horike, Masayuki Sugimoto, Munehiro Inukai, Tomohiro Fukushima, Susumu Kitagawa
    • Journal Title

      Inorg. Chem

      Volume: 52 Pages: 3634-3642

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Susumu KitagawaSoft 2-D layer porous coordination polymers with 1,2-di(4-pyridyl)ethaneAust2013

    • Author(s)
      Keisuke Kishida, Satoshi Horike, Kanokwan Kongpatpanich
    • Journal Title

      J. Chem

      Volume: 66 Pages: 464-469

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fe2+ Layered Porous Coordination Polymers and Soft Encapsulation of Guest via Redox Activity2013

    • Author(s)
      Satoshi Horike, Masayuki Sugimoto, Kanokwan Kongpatpanich, Yuh Hijikata, Munehiro Inukai, Daiki Umeyama, Shinji Kitao, Makoto Seto, Susumu Kitagawa
    • Journal Title

      J. Mater. Chem.

      Volume: 1 Pages: 3675-3679

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Post-synthesis modification of a porous coordination polymer by LiCl to enhance H+ transport2013

    • Author(s)
      Satoshi Horike, Yusuke Kamitsubo, Munehiro Inukai, Tomohiro Fukushima, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      Jollrnal of the American Chemical Society

      Volume: 135 Issue: 12 Pages: 4612-4615

    • DOI

      10.1021/ja3122872

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pore Design of Two-dimensional Coordination Polymers toward Selective Adsorption2013

    • Author(s)
      Y. Hijikata, T. Fukushima, S. Kitagawa, 他
    • Journal Title

      Inorg. Chem.

      Volume: 135 Issue: 7 Pages: 3634-3642

    • DOI

      10.1021/ic302006x

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft 2-D layer porous coordination polymers with 1,2-di(4-pyridyl)ethane2013

    • Author(s)
      Keisuke Kishida
    • Journal Title

      Aust. J. Chem.

      Volume: 66 Issue: 4 Pages: 464-469

    • DOI

      10.1071/ch12467

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe2+ Layered Porous Coordination Polymers and Soft Encapsulation of Guest via Redox Activity2013

    • Author(s)
      Satoshi Horike
    • Journal Title

      J. Mater. Chem. A

      Volume: 1 Issue: 11 Pages: 3675-3679

    • DOI

      10.1039/c3ta01414b

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional Cu(II) Porous Coordination Polymer with Inorganic Fluorinated PF6- Anions2012

    • Author(s)
      Shin-ichiro Noro, Yuh Hijikata, Munehiro Inukai, Tomohiro Fukushima, Satoshi Horike, Masakazu Higuchi, Susumu Kitagawa, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Inorg. Chem

      Volume: 52 Pages: 280-285

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of post-grafted groups of a porous coordination polymer and its proton conduction behavior2012

    • Author(s)
      Munehiro Inukai, Satoshi Horike, Daiki Umeyama, Yuh Hijikata, Susumu Kitagawa
    • Journal Title

      Dalton Trans

      Volume: 41 Pages: 13261-13263

    • NAID

      120005323885

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process2012

    • Author(s)
      Tomohiro Fukushima, Satoshi Horike, Hirokazu Kobayashi, Masahiko Tsujimoto, Seiji Isoda, Maw Lin Foo, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 13341-13347

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Inherent Proton Conduction in 2-D Coordination Framework2012

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 12780-12785

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties2012

    • Author(s)
      Elsa Quartapelle Procopio, Tomohiro Fukushima, E. Barea, Jorge A. R. Navarro, Satoshi Horike, Susumu Kitagawa
    • Journal Title

      Chem. Eur

      Volume: 18 Pages: 13117-13125

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ligand-based Solid Solution Approach to Stabilisation of Sulphonic Acid Groups in Porous Coordination Polymer Zr6O4(OH)4(BDC)6 (UiO-66)2012

    • Author(s)
      Maw Lin Foo, Satoshi Horike, Tomohiro Fukushima, Yuh Hijikata, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Dalton Trans

      Volume: 41 Pages: 13791-13794

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dense Coordination Network Capable of Selective CO2 Capture from C1 and C2 Hydrocarbons2012

    • Author(s)
      Satoshi Horike, Keisuke Kishida, Yoshihiro Watanabe, Yasutaka Inubushi, Daiki Umeyama, Masayuki Sugimoto, Tomohiro Fukushima, Munehiro Inukai, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 9852-9855

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design of Flexible Lewis Acidic Sites in Porous Coordination Polymers by using the Viologen Moiety2012

    • Author(s)
      Masakazu Higuchi, Kohei Nakamura, Satoshi Horike, Yuh Hijikata, Nobuhiro Yanai, Tomohiro Fukushima, Jungeun Kim, Kenichi Kato, Masaki Takata, Daisuke Watanabe, Shinji Oshima, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int.

      Volume: 51 Pages: 8369-8372

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coordination-Network-Based Ionic Plastic Crystal for Anhydrous Proton Conductivity2012

    • Author(s)
      Satoshi Horike, Daiki Umeyama, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 7612-7615

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Alkaline Earth I3O0 Porous Coordination Polymer: [Ba2TMA(NO3)(DMF)] (H3TMA = trimesic acid)2012

    • Author(s)
      Maw Lin Foo, Satoshi Horike, Yasutaka Inubushi, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int

      Volume: 51 Pages: 6107-6111

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Adsorption Properties of Azulene-Containing Porous Interdigitated Framework2012

    • Author(s)
      Keisuke Kishida, Satoshi Horike, Keiji Nakagawa, Susumu Kitagawa
    • Journal Title

      Chem. Lett

      Volume: 41 Pages: 425-426

    • NAID

      10030544964

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Solid Solution Approach to 2D Coordination Polymers for CH4/CO2 and CH4/C2H6 Gas Separation: Equilibrium and Kinetic Studies2012

    • Author(s)
      Satoshi Horike, Yasutaka Inubushi, Takashi Hori, Tomohiro Fukushima, Susumu Kitagawa
    • Journal Title

      Chem. Sci

      Volume: 3 Pages: 116-120

    • NAID

      120004945142

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional CU(II) Porous Coordination Polymer with Inorganic Fluoriuated PF6- Anions2012

    • Author(s)
      S. Noro, T. Fukushima, S. Kitagawa, T. Nakamura, 他
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 1 Pages: 280-285

    • DOI

      10.1021/ic301823j

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of post-grafted groups of a porous coordination polymer and its proton conduction behavior2012

    • Author(s)
      Munehiro Inukai, Satoshi Horike, Daiki Umeyama, Yuh Hijikata, Susumu Kitagawa
    • Journal Title

      Dalton Transcription

      Volume: 41 Issue: 43 Pages: 13261-13263

    • DOI

      10.1039/c2dt31836a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process2012

    • Author(s)
      T. Fukushima, S. Horike, S. Kitagawa, 他
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 32 Pages: 13341-13347

    • DOI

      10.1021/ja303588m

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inherent Proton Conduction in a 2D Coordination Framework2012

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134 Issue: 30 Pages: 12780-12785

    • DOI

      10.1021/ja304693r

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties2012

    • Author(s)
      Elsa Quartapelle Procopio
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Issue: 41 Pages: 13117-13125

    • DOI

      10.1002/chem.201201820

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ligand-based Solid Solution Approach to Stabilisation of Sulphonic Acid Groups in Porous Coordination Polymer Zr604(OH)4 (BDC) 6 (UiO-66)2012

    • Author(s)
      M. L. Foo, T. Fukushima, S. Kitagawa, 他
    • Journal Title

      Dalton Trans.

      Volume: 41 Issue: 45 Pages: 13791-13794

    • DOI

      10.1039/c2dt31195j

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dense Coordination Network Capable of Selective CO2 Capture from C1 and C2 Hydrocarbons2012

    • Author(s)
      S. Horike, I. Fukushima, S. Kitagawa, 他
    • Journal Title

      J. Am. Chei. Soc.

      Volume: 134 Issue: 24 Pages: 9852-9855

    • DOI

      10.1021/ja302043u

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of Flexible Lewis Acidic Sites in Porous Coordination Polymers by using the Violgen Moiety2012

    • Author(s)
      M. Higuchi, T. Fukushima, S. Kitasawa, 他
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 33 Pages: 8369-8372

    • DOI

      10.1002/anie.201203834

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination-Network-Based Ionic Plastic Crystal for Anhydrous Proton Conductivity2012

    • Author(s)
      Satoshi Horike, Daiki Umeyama, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134 Issue: 18 Pages: 7612-7615

    • DOI

      10.1021/ja301875x

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Alkaline Earth I3O0 Porous Coordination Polymer: [Ba2TMA(NO3)(DMF)] (H3TMA = trimesic acid)2012

    • Author(s)
      Maw Lin Foo
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 25 Pages: 6107-6111

    • DOI

      10.1002/anie.201202285

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Adsorption Properties of Azulene-Containing Porous Interdigitated Framework2012

    • Author(s)
      Keisuke Kishida
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 4 Pages: 425-426

    • DOI

      10.1246/cl.2012.425

    • NAID

      130004426544

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Solid Solution Approach to 2D Coordination Polymers for CH4/CO2 and CH4/C2H6 Gas Separation : Equilibrium and Kinetic Studies2012

    • Author(s)
      S.Horike, T.Fukushima, S.Kitagawa, 他
    • Journal Title

      Chemical Science

      Volume: 3 Issue: 1 Pages: 116-120

    • DOI

      10.1039/c1sc00591j

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] An Alkaline Earth I3O0 Porous Coordination Polymer: [Ba2TMA(NO3)(DMF)] (H3TMA = trimesic acid)2012

    • Author(s)
      Maw Lin Foo, Satoshi Horike, Yasutaka Inubushi, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Confinement of Mobile Histamine in Coordination Nanochannels for Fast Proton Transfer2011

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Yuh Hijikata, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 50 Issue: 49 Pages: 11706-11709

    • DOI

      10.1002/anie.201102997

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of a 1-D Porous Barium Carboxylate Coordination Polymer, [Ba(HBTB)] (H3BTB = Benzene-1,3,5-trisbenzoic Acid)2011

    • Author(s)
      Maw Lin Foo, Satoshi Horike, Susumu Kitagawa
    • Journal Title

      Inorg. Chem.

      Volume: 50 Issue: 23 Pages: 11853-11855

    • DOI

      10.1021/ic201814g

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 金属錯体機能の根源を探る~分子構造とその変化様式の探求最前線2013

    • Organizer
      分子研研究会
    • Place of Presentation
      分子科学研究所
    • Year and Date
      2013-03-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Ion transfer in the restricted channels of coordination polymer2013

    • Organizer
      iCeMS Trilateral Australia-USA-Japan Symposium on Porous Materials
    • Place of Presentation
      京都大学
    • Year and Date
      2013-03-08
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Dynamic coordination framework materials for new energy resources2013

    • Organizer
      International meeting "Nanomaterial Futures" of Bristol Centre for Functional Nanomaterials
    • Place of Presentation
      ブリストル大学
    • Year and Date
      2013-02-19
    • Related Report
      2012 Final Research Report
  • [Presentation] 配位高分子構造のダイナミックスが誘起するイオン伝導機能2013

    • Author(s)
      堀毛悟史
    • Organizer
      分子研研究会
    • Place of Presentation
      分子科学研究所
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Dynamic coordination framework materials for new energy resources2013

    • Author(s)
      Satoshi Horike
    • Organizer
      Nanomaterial Futures
    • Place of Presentation
      University of Bristol
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 多孔性錯体の動的結晶化学を用いた環境・エネルギー固体材料の開発2012

    • Organizer
      第92回日本化学会年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 多孔性錯体の動的結晶化学を用いた環境・エネルギー固体材料の開発2012

    • Author(s)
      堀毛悟史
    • Organizer
      第92回 日本化学会年会(招待講演)
    • Place of Presentation
      慶應大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Porous coordination polymer as crystalline ion transporter2011

    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Porous Coordination Polymer as Crystalline Ion Transporter2011

    • Author(s)
      堀毛悟史
    • Organizer
      第61回 錯体化学討論会(招待講演)
    • Place of Presentation
      岡山東京理科大学
    • Related Report
      2011 Research-status Report
  • [Book] 空間の「柔らかさ」を利用した CO2 分離2012

    • Author(s)
      堀毛悟史、犬伏康貴
    • Related Report
      2012 Final Research Report
  • [Book] イオン伝導性配位高分子堀毛悟史2012

    • Author(s)
      堀毛悟史
    • Publisher
      日本化学会
    • Related Report
      2012 Final Research Report
  • [Book] 配位高分子を用いたリチウム二次電池-無機・有機に続く第三の材料となるか2012

    • Author(s)
      堀毛悟史
    • Publisher
      化学同人
    • Related Report
      2012 Final Research Report
  • [Book] 材料科学の基礎2012

    • Author(s)
      堀毛悟史、坂本裕俊、杉本雅行、福島知宏、岸田圭輔、梅山大樹、北川進
    • Publisher
      シグマ アルドリッチ ジャパン株式会社
    • Related Report
      2012 Final Research Report
  • [Book] 多孔性配位高分子(PCP)/金属有機構造体(MOF)の基礎2012

    • Author(s)
      堀毛悟史
    • Total Pages
      16
    • Publisher
      シグマ-アルドリッチ
    • Related Report
      2012 Annual Research Report
  • [Book] 配位高分子を用いたリチウム二次電池 -無機・有機に続く第三の材料となるか-2012

    • Author(s)
      堀毛悟史
    • Total Pages
      1
    • Publisher
      化学同人
    • Related Report
      2012 Annual Research Report
  • [Book] イオン伝導性配位高分子(飛翔する若手研究者)2012

    • Author(s)
      堀毛悟史
    • Total Pages
      2
    • Publisher
      日本化学会
    • Related Report
      2012 Annual Research Report
  • [Book] 空間の「柔らかさ」を利用したCO2分離2012

    • Author(s)
      堀毛悟史
    • Total Pages
      4
    • Publisher
      東京化学同人
    • Related Report
      2012 Annual Research Report
  • [Book] 現代化学 2012年4月号2012

    • Author(s)
      堀毛悟史、犬伏康貴
    • Total Pages
      2
    • Publisher
      東京化学同人
    • Related Report
      2011 Research-status Report
  • [Book] Metal-Organic Frameworks : Applications from Catalysis to Gas StoragePart 1 - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future2011

    • Author(s)
      Satoshi Horike, Susumu Kitagawa
    • Publisher
      Wiley-VCH
    • Related Report
      2012 Final Research Report
  • [Book] Metal-Organic Frameworks : Applications from Catalysis to Gas Storage2011

    • Author(s)
      Satoshi Horike, Susumu Kitagawa
    • Total Pages
      19
    • Publisher
      Wiley-VCH (Germany)
    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi