Tunable catalysis by using high-density mixed monolayer

• Project/Area Number: 23760735
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Catalyst/Resource chemical process
• Research Institution: Hokkaido University
• Principal Investigator: HARA Kenji 北海道大学, 触媒化学研究センター, 准教授 (10333593)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
• Keywords: 単分子層 / 金表面 / 触媒反応場 / 選択性 / 協奏機能 / 触媒調製化学 / 金属錯体 / イソシアニド / 鉄 / ニッケル / 水素化 / 触媒 / ロジウム / 銅 / 金 / 表面

Research Abstract

This research was proposed to establish a novel versatile preparation method to provideunique and demanded catalytic environment by utilizing two-dimensional high-densitymolecular assembly on surface. Densely-packed mixed monolayer of catalytically activeunit and performance-determining unit was set to be key components to realize thetargeted purpose. The present research accomplished achievement in preparing severalcatalyst systems which afford usually difficult selectivity, or high catalyst turnover numberand recyclability.

Research Products

• [Journal Article] Low-Temperature Oxidation of Ethylene over Platinum Nanoparticles Supported on Mesoporous Silica (2013)
  • Author(s): Chuanxia Jiang, Kenji Hara, Atsushi Fukuoka
  • Journal Title: Angewandte Chemie International Edition Volume: 52巻(in press) Issue: 23 Pages: 6084-6087
  • DOI: 10.1002/anie.201300469
  • Peer Reviewed
• [Journal Article] High-Yielding One-Pot Synthesis of Glucose from Cellulose Using Simple Activated Carbons and Trace Hydrochloric Acid (2013)
  • Author(s): H. Kobayashi, M. Yabushita, T.Komanoya, K. Hara, I. Fujita, A. Fukuoka
  • Journal Title: ACS Catalysis Volume: 3 Issue: 4 Pages: 581-587
  • DOI: 10.1021/cs300845f
  • Peer Reviewed
• [Journal Article] Selective and Efficient Silylation of Mesoporous Silica : A Quantitative Assessment of Synthetic Strategies by Solid-State NMR (2012)
  • Author(s): Hara, K.; Akahane, S.; Wiench, J.W.; Burgin, B.R.; Ishito, N.; Lin, V.S.-Y., Fukuoka, A.; Pruski, M
  • Journal Title: J.Phys.Chem.C Volume: 116 Issue: 12 Pages: 7083-7090
  • DOI: 10.1021/jp300580f
  • Peer Reviewed
• [Journal Article] Intrinsic Catalytic Role of Mesoporous Silica in Preferential Oxidation of Carbon Monoxide in Excess Hydrogen (2012)
  • Author(s): Huang, S.; Hara, K.; Fukuoka, A.
  • Journal Title: Chem.Eur.J. Volume: 18 Issue: 15 Pages: 4738-4747
  • DOI: 10.1002/chem.201102256
  • Peer Reviewed
• [Journal Article] 1-Butanol Synthesis from Ethanol over Strontium Phosphate Hydroxyapatite Catalysts with Various Sr/P Ratios (2012)
  • Author(s): S. Ogo, A. Onda, Y. Iwasa, K. Hara, A. Fukuoka,K. Yanagisawa
  • Journal Title: Journal of Catalysis Volume: 296巻 Pages: 24-30
  • DOI: 10.1016/j.jcat.2012.08.019
  • Peer Reviewed
• [Journal Article] Phase Change of Nickel Phosphide Catalysts in the Conversion of Cellulose into Sorbitol (2012)
  • Author(s): P. Yang, H. Kobayashi, K. Hara and A. Fukuoka
  • Journal Title: ChemSusChem Volume: 5 Pages: 920-926
  • Peer Reviewed
• [Journal Article] Remarkable Effect of Ordered Mesoporous Carbon Support in Tantalum Oxide-catalyzed Selective Epoxidation of Cyclooctene (2011)
  • Author(s): Lin, M.-L.; Hara, K.; Okubo, Y.; Yanagi, M.; Nambu, H.; Fukuoka, A.
  • Journal Title: Catal.Comm. Volume: 12 Issue: 13 Pages: 1228-1230
  • DOI: 10.1016/j.catcom.2011.04.023
  • NAID: 120003242991
  • Peer Reviewed
• [Presentation] Densely Packed Monolayer of Metal-Diisocyanide on Gold Surface; (2013)
  • Author(s): 原賢二、Sachin Jagtap、梶義規、田旺帝、福岡淳
  • Organizer: Preparation and Application in Catalysis, Collaborative Conference on Materials Research (CCMR)
  • Place of Presentation: Ramada Plaza Jeju Hotel(大韓民国)
  • Year and Date: 2013-06-26
• [Presentation] 規整表面上での金属錯体の高密度固定化による新規触媒の開発 (2013)
  • Author(s): 原賢二
  • Organizer: 触媒学会千葉地区講演会高付加価値生成物合成に向けた新規触媒の開発
  • Place of Presentation: 千葉大学西千葉キャンパス(千葉市)
  • Year and Date: 2013-06-14
• [Presentation] 高密度ジイソシアニド-金属錯体単分子層の特異な触媒機能とXAFS構造解析 (2013)
  • Author(s): 原賢二、SachinJagtap、難波光太郎、梶義規、田旺帝、朝倉清高、福岡淳
  • Organizer: 第30回PFシンポジウム
  • Place of Presentation: つくば国際会議場(つくば市)
  • Year and Date: 2013-03-15
• [Presentation] 規整表面上における高密度金属錯体単分子層の形成と触媒反応への応用 (2013)
  • Author(s): 原賢二、SachinJagtap、難波光太郎、梶義規、福岡淳
  • Organizer: 平成24年度日本表面科学会東北・北海道支部学術講演会
  • Place of Presentation: 日本大学工学部(郡山市)
  • Year and Date: 2013-03-11
• [Presentation] 規整表面上における高密度金属錯体単分子層の形成と触媒反応への応用 (2013)
  • Author(s): 原 賢二、Sachin Jagtap、難波 光太郎、梶 義規、福岡 淳
  • Organizer: 平成24年度日本表面科学会東北・北海道支部学術講演会
  • Place of Presentation: 日本大学工学部（郡山市）
  • Invited
• [Presentation] Densely Packed Monolayer of Metal-Diisocyanide on Gold Surface; Preparation and Application in Catalysis (2013)
  • Author(s): K. Hara, S .Jagtap Y. Kaji, W.J. Chun, A. Fukuoka
  • Organizer: Collaborative Conference on Materials Research (CCMR) 2013
  • Place of Presentation: Ramada Plaza Jeju Hotel（大韓民国）
  • Invited
• [Presentation] Densely Packed Monolayer of Rh- and Cu-Diisocynide on Gold Surface as Platforms for Highly Active and Selective Catalysis (2012)
  • Author(s): K. Hara, K. Namba, S. Jagtap, Y. Kaji, W.J.Chun, A. Fukuoka
  • Organizer: Cambodian Malaysian Chemical Conference (CMCC) 2012
  • Place of Presentation: Angkor Century Resort & Spa(Cambodia)
  • Year and Date: 2012-10-21
• [Presentation] 金表面上におけるジイソシアニド銅錯体単分子層の作製と触媒反応への応用 (2012)
  • Author(s): 難波光太郎,原賢二,福岡淳
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 九州大学伊都キャンパス(福岡市)
  • Year and Date: 2012-09-24
• [Presentation] 金表面上におけるジイソシアニド銅錯体単分子層の作製と触媒反応への応用 (2012)
  • Author(s): 原賢二,難波光太郎,福岡淳
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学吹田キャンパス(吹田市),
  • Year and Date: 2012-09-14
• [Presentation] Densely packed monolayer of metal complex on gold surface as platform for selective catalysis (2012)
  • Author(s): 原賢二, Sachin Jagtap, 梶義規, 福岡淳
  • Organizer: International Symposium on Zeolite and Microporous Crystals(ZMPC) 2012
  • Place of Presentation: アステールプラザ(広島市)
  • Year and Date: 2012-07-29
• [Presentation] Monolayer of diisocyanide on Au surface as a platform for Rh catalysis of 1,4-hydrogenation of 〓,〓-unsaturated carbonyl compounds (2012)
  • Author(s): 原賢二, Sachin Jagtap, 梶義規, 福岡淳
  • Organizer: 15th International Congress on Catalysis 2012
  • Place of Presentation: International Congress Center Munich(ドイツ)
  • Year and Date: 2012-07-04
• [Presentation] 表面上での金属ジイソシアニド錯体単分子層の形成と有機分子変換反応への応用 (2012)
  • Author(s): 原賢二
  • Organizer: 電気化学会北海道支部第18回若手研究者交流会
  • Place of Presentation: おたる自然の家おこばち山荘(小樽市)(招待講演)
  • Year and Date: 2012-06-24
• [Presentation] Monolayer of diisocyanide on Au surface as a platform for Rh catalysis of 1,4-hydrogenation of 〓,〓-unsaturated carbonyl compounds (2012)
  • Author(s): 原賢二, Sachin Jagtap, 梶義規, 福岡淳
  • Organizer: International Association of Colloid and Interface Scientists,Conference (IACIS) 2012
  • Place of Presentation: 仙台国際センター(仙台市)
  • Year and Date: 2012-05-17
• [Presentation] ジイソシアニド金属錯体単分子層の形成と触媒への応用 (2012)
  • Author(s): 難波光太郎、原賢二、福岡淳
  • Organizer: 化学系学協会北海道支部2012年冬季研究発表会
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2012-01-31
• [Presentation] Preparation and Catalysis of Monolayer of Rh-diisocyanide on Gold Surface, CRC International Symposium on Green (2012)
  • Author(s): 原賢二, Sachin Jagtap, 梶義規, 福岡淳
  • Organizer: Sustainable Catalysis: from Theoretical and Fundamental Aspects to Catalyst Design
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2012-01-26
• [Presentation] 規整表面上での触媒反応場の構築と応用 (2012)
  • Author(s): 原賢二
  • Organizer: 触媒学会横浜地区講演会
  • Place of Presentation: 東京工業大学(横浜市)
  • Year and Date: 2012-01-24
• [Presentation] 表面上での金属ジイソシアニド錯体単分子層の形成と有機分子変換反応への応用 (2012)
  • Author(s): 原 賢二
  • Organizer: 電気化学会北海道支部第18回若手研究者交流会
  • Place of Presentation: おたる自然の家おこばち山荘（小樽市）
  • Invited
• [Presentation] Monolayer of diisocyanide on Au surface as a platform for Rh catalysis of 1,4-hydrogenation of α,ß-unsaturated carbonyl compounds (2012)
  • Author(s): K. Hara, S. Jagtap, Y. Kaji, A. Fukuoka
  • Organizer: International Association of Colloid and Interface Scientists, Conference (IACIS) 2012
  • Place of Presentation: 仙台国際センター（仙台市）
• [Presentation] Monolayer of diisocyanide on Au surface as a platform for Rh catalysis of 1,4-hydrogenation of α,ß-unsaturated carbonyl compounds (2012)
  • Author(s): K. Hara, S. Jagtap, Y. Kaji, A. Fukuoka
  • Organizer: 15th International Congress on Catalysis 2012
  • Place of Presentation: International Congress Center Munich（ドイツ）
• [Presentation] Densely packed monolayer of metal complex on gold surface as platform for selective catalysis (2012)
  • Author(s): Kenji Hara, Sachin Jagtap, Yoshinori Kaji, Atsushi Fukuoka
  • Organizer: International Symposium on Zeolite and Microporous Crystals (ZMPC) 2012
  • Place of Presentation: アステールプラザ（広島市）
• [Presentation] Monolayer of Diisocyanide on Gold Surface as a Platform for Rh-Catalyzed Selective Hydrogenation (2012)
  • Author(s): Kenji Hara, Sachin Jagtap, Yoshinori Kaji, Atsushi Fukuoka
  • Organizer: The 6th International Conference on Gold Science, Technology and its Applications (Gold 2012)
  • Place of Presentation: 京王プラザホテル東京（東京都新宿区）
• [Presentation] 金表面上におけるジイソシアニド銅錯体単分子層の作製と触媒反応への応用 (2012)
  • Author(s): 難波 光太郎, 原 賢二, 福岡 淳
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学吹田キャンパス（吹田市）
• [Presentation] 金表面上におけるジイソシアニド銅錯体単分子層の作製と触媒反応への応用 (2012)
  • Author(s): 難波 光太郎, 原 賢二, 福岡 淳
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 九州大学伊都キャンパス（福岡市）
• [Presentation] Densely Packed Monolayer of Rh- and Cu-Diisocynide on Gold Surface as Platforms for Highly Active and Selective Catalysis (2012)
  • Author(s): K. Hara, K. Namba, S. Jagtap, Y. Kaji, W.J. Chun, A. Fukuoka
  • Organizer: Cambodian Malaysian Chemical Conference (CMCC) 2012
  • Place of Presentation: Angkor Century Resort & Spa（Cambodia）
  • Invited
• [Presentation] 規整表面上での触媒反応場の構築と応用 (2012)
  • Author(s): 原 賢二
  • Organizer: 触媒学会横浜地区講演会(招待講演)
  • Place of Presentation: 東京工業大学（横浜市）
• [Presentation] ジイソシアニド金属錯体単分子層の形成と触媒への応用 (2012)
  • Author(s): 難波 光太郎、原 賢二、福岡 淳
  • Organizer: 化学系学協会北海道支部2012年冬季研究発表会
  • Place of Presentation: 北海道大学（札幌市）
• [Presentation] Preparation and Catalysis of Monolayer of Rh-diisocyanide on Gold Surface (2012)
  • Author(s): Kenji Hara, Sachin Jagtap, Yoshinori Kaji, Atsushi Fukuoka
  • Organizer: CRC International Symposium on Green & Sustainable Catalysis: from Theoretical and Fundamental Aspects to Catalyst Design
  • Place of Presentation: 北海道大学（札幌市）
• [Presentation] 規整表面上での触媒反応場の構築と応用,長崎大学第2期中期目標・中期計画重点研究課題 (2011)
  • Author(s): 原賢二
  • Organizer: 平成23年度第1回講演会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2011-12-08
• [Presentation] Densely Packed Monolayer of Rh-Diisocyanide on Gold Surface as Recyclable Catalyst for Hydrogenation of Enones (2011)
  • Author(s): 原賢二
  • Organizer: International Symposium and the Third Iwasawa Conference on Catalysis and Surface Science for Efficient Utilization of Carbon Resources and Related Topics
  • Place of Presentation: アモイ大学(中国)
  • Year and Date: 2011-12-04
• [Presentation] Densely Packed Monolayer of Metal Complex on Gold Surface: Application in Selective Catalysis (2011)
  • Author(s): 原賢二
  • Organizer: 9th Asian Conference on Chemical Sensors
  • Place of Presentation: Chientan Youth Activity Center (台湾)
  • Year and Date: 2011-11-15
• [Presentation] 金表面上におけるロジウムージイソシアニド錯体単分子層の形成と触媒機能 (2011)
  • Author(s): 原賢二,SachinJagtap,梶義規,福岡淳
  • Organizer: 統合物質創製化学推進事業第2回統合物質シンポジウム「化学合成力と機能創出」
  • Place of Presentation: 名古屋大学(名古屋市)
  • Year and Date: 2011-11-06
• [Presentation] Preparation and Catalysis of Densely Packed Monolayer of Rhodium-Diisocyanide Monolayer on Gold Suface (2011)
  • Author(s): 原賢二
  • Organizer: The 14th Asian Chemical Congress 2011
  • Place of Presentation: クイーンシリキットコンベンションセンター(タイ)
  • Year and Date: 2011-09-08
• [Presentation] 金表面上に高密度に集積化した単分子層を利用する触媒反応 (2011)
  • Author(s): 原賢二
  • Organizer: ワークショップナノ粒子触媒の構造制御と表面化学
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2011-06-28
• [Presentation] Densely Packed Monolayer of Metal Complex on Gold Surface: Application in Selective Catalysis (2011)
  • Author(s): Hara, K
  • Organizer: 9th Asian Conference on Chemical Sensors(招待講演)
  • Place of Presentation: Chientan Youth Activity Center (Taiwan)
• [Presentation] Densely Packed Monolayer of Rh-Diisocyanide on Gold Surface as Recyclable Catalyst for Hydrogenation of Enones (2011)
  • Author(s): Hara, K
  • Organizer: International Symposium and the Third Iwasawa Conference on Catalysis and Surface Science for Efficient Utilization of Carbon Resources and Related Topics(招待講演)
  • Place of Presentation: Xiamen University (China)
• [Presentation] 規整表面上での触媒反応場の構築と応用 (2011)
  • Author(s): 原 賢二
  • Organizer: 長崎大学第２期中期目標・中期計画重点研究課題 「次世代エネルギー物質科学の基盤構築」平成２３年度第1回講演会(招待講演)
  • Place of Presentation: 長崎大学（長崎市）
• [Presentation] Preparation and Catalysis of Densely Packed Monolayer of Rhodium-Diisocyanide Monolayer on Gold Suface (2011)
  • Author(s): Hara, K
  • Organizer: The 14th Asian Chemical Congress 2011(招待講演)
  • Place of Presentation: クイーンシリキットコンベンションセンター (Thailand)
• [Presentation] 金表面上におけるロジウムージイソシアニド錯体単分子層の形成と触媒機能 (2011)
  • Author(s): 原 賢二 , Sachin Jagtap, 梶 義規, 福岡 淳
  • Organizer: 統合物質創製化学推進事業 第２回統合物質シンポジウム 「化学合成力と機能創出」
  • Place of Presentation: 名古屋大学（名古屋市）
• [Presentation] 金表面上に高密度に集積化した単分子層を利用する触媒反応 (2011)
  • Author(s): 原 賢二
  • Organizer: ワークショップ「ナノ粒子触媒の構造制御と表面化学」
  • Place of Presentation: 北海道大学（札幌市）
• [Presentation] 高密度ジイソシアニド-金属錯体単分子層の特異な触媒機能とＸＡＦＳ構造解析
  • Author(s): 原 賢二、Sachin Jagtap、難波 光太郎、梶 義規、田 旺帝、朝倉 清高、福岡
  • Organizer: 第30回PFシンポジウム
  • Place of Presentation: つくば国際会議場 （つくば市）
• [Book] 金属錯体単分子層の高密度化・構築と新規触媒反応場としての応用 (2013)
  • Author(s): 原賢二
  • Publisher: 技術情報協会
• [Remarks]
  • URL: http://www.cat.hokudai.ac.jp/fukuoka/