Control of synergistically working multi-functions designed in conductive molecular magnets
Project/Area Number |
24245012
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Tohoku University |
Principal Investigator |
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Co-Investigator(Renkei-kenkyūsha) |
KOSAKA Wataru 東北大学, 金属材料研究所, 助教 (70620201)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
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Budget Amount *help |
¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000)
Fiscal Year 2014: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2013: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2012: ¥32,760,000 (Direct Cost: ¥25,200,000、Indirect Cost: ¥7,560,000)
|
Keywords | 電子ドナー・アクセプター / 金属―有機物骨格体 / 導電性分子磁石 / 電荷移動 / 協奏的多重機能 / 金属ー有機物骨格体 |
Outline of Final Research Achievements |
The aim of the research project is to establish multi-functional molecular materials using electron-donor/-acceptor-based conductive molecular magnets or highly redox-active molecular framework compounds, in which not only ‘physical responses’ such as magnetic ordering, electron transporting, and dielectric responses resulted from their frameworks, but also ‘chemical reactions’ involving chemical adsorption/desorption of gaseous molecules in nano-sized pores are synergistically functioned. We discovered tunable selective NO adsorption behavior in a series of electron-donor-type chain compounds based on paddlewheel-type diruthenium(II, II) complexes, and succeeded to capture modifications involving gas adsorptions as gate-opening gas adsorption transitions and chemical interactions caused by host-guest interactions as electric signals by applying ac electric fields in situ gas handling.
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Report
(4 results)
Research Products
(53 results)
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[Journal Article] Cyano-Bridged Mn^III-M^III Single-Chain Magnets with M^III=Co^III, Fe^III, Mn^III , and Cr^III2012
Author(s)
H. Miyasaka, T. Madanbashi, A. Saitou, R. Ishikawa, M. Yamashita, S. Bahr, W. Werrsdorfer, R. Crelac
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Journal Title
Chem. Eur. J.
Volume: 18
Issue: 13
Pages: 3942-3954
DOI
Related Report
Peer Reviewed
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