• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Immobilization and decontamination of radioactive substances in soil using nano-sized smart material

Research Project

Project/Area Number 24310059
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionPrefectural University of Hiroshima

Principal Investigator

MITOMA Yoshiharu  県立広島大学, 生命環境学部, 准教授 (20301674)

Co-Investigator(Kenkyū-buntansha) KAWAJI Takatoshi  和歌山工業高等専門学校, 物質工学科, 准教授 (30290779)
OKUDA Tetsuji  広島大学, 環境安全センター, 助教 (60343290)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2014: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2012: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywordsセシウム / 除染 / ナノカルシウム / 不溶化 / 放射性物質
Outline of Final Research Achievements

In Japan, the major concern on radioactive cesium deposition and soil contamination due to the emission from the Fukushima Dai-ichi nuclear power plant showed up after a massive quake on March 11, 2011. Soil contamination with radioactive cesium has a long-term radiological impact due to its long physical half-life (30 years for 137Cs) and its high biological availability. Therefore, much attention has been paid to decontaminate Cs-polluted soil with washing and/or extraction by adopting solvents. However, such wet methods have some disadvantages, i.e. forming of secondary effluents and additional cost for their treatment. We have recently shown that the nano-size metallic calcium/calcium oxide/iron dispersing (Fe-nCa) mixture is most effective for heavy metals immobilization and volume reduction method under dry condition. Simple stirring of the contaminated soil with Fe-nCa achieved about above 90% of radioactive Cs recovery and the volume reduction level also reached around 50-60%.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(26 results)

All 2015 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results) Presentation (10 results) (of which Invited: 1 results) Remarks (2 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Dynamic immobilization of simulated radionuclide 133Cs in soil by thermal treatment/vitrification with nanometallic Ca/CaO composites2015

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji 0kuda, Cristian Simion
    • Journal Title

      Journal of Environmental Radioactivity

      Volume: 139 Pages: 118-124

    • DOI

      10.1016/j.jenvrad.2014.10.006

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preferential removal and immobilization of stable and radioactive cesium in contaminated fly ash with nanometallic Ca/CaO methanol suspension2014

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji 0kuda, Shogo Sakita, Cristian Simion
    • Journal Title

      Journal of Hazardous Materials

      Volume: 279 Pages: 52-59

    • DOI

      10.1016/j.jhazmat.2014.06.044

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous decontamination of cross-polluted soils with heavy metals and PCBs using a nano-metallic Ca/CaO dispersion mixture2014

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji Okuda, Shogo Sakita, Cristian Simion
    • Journal Title

      Environmental Science and Pollution Research International

      Volume: 21 Pages: 9270-9277

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ナノカルシウム鉄にようる放射性セシウム汚染土壌の乾式除染技術2014

    • Author(s)
      三苫好治, 奥田哲士.
    • Journal Title

      ケミカルエンジニアリング

      Volume: 59巻 Pages: 22-28

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Cesium immobilization in soil by ball-milling treatment with nanometallic Ca/CaO additive2013

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji Okuda, Shogo Sakita, Mitsunori Kakeda
    • Journal Title

      Journal of Hazardous, Toxic and Radioactive Waste

      Volume: 17巻 Pages: 2-8

    • DOI

      10.1061/(asce)hz.2153-5515.0000151

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total immobilization of soil heavy metals with nano-Fe/Ca/CaO dispersion mixtures2013

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji Okuda, Shogo Sakita, Mitsunori Kakeda
    • Journal Title

      Environmental Chemistry Letters

      Volume: 11巻 Pages: 119-125

    • DOI

      10.1007/s10311-012-0384-0

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Decontamination of radioactive cesium in soil using nano-size metallic calcium dispersing2013

    • Author(s)
      Yoshiharu Mitoma, Takezo Fukuoka, Hideaki Matsue, Hidemasa Kobayashi, Hiroaki Shiraishi, Mikio Kajitani
    • Journal Title

      デコミッショニング技報

      Volume: 特別号 Pages: 24-29

    • NAID

      40019705163

    • Related Report
      2013 Annual Research Report
  • [Journal Article] High immobilization of soil cesium using ball milling with nano-metallic Ca/Ca0/NaH2P04 implications for the remediation of radioactive soils2012

    • Author(s)
      Yoshiharu Mitoma
    • Journal Title

      Environmental Chemistry Letters

      Volume: 10 Pages: 201-207

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ナノカルシウムによる土壌中放射性セシウムの乾式迅速分離及び不溶化2012

    • Author(s)
      三苫好治
    • Journal Title

      産業と環境

      Volume: 41 Pages: 63-66

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Enhanced heavy metal immobilization in soil by grinding with addition of nanometallic Ca/CaO dispersion mixture2012

    • Author(s)
      Yoshiharu Mitoma
    • Journal Title

      Chemosphere

      Volume: 89 Pages: 717-723

    • DOI

      10.1016/j.chemosphere.2012.06.030

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属カルシウムナノ粒子によるセシウム汚染土壌の分別および溶出抑制2014

    • Author(s)
      奥田 哲士, レディ エムエス, 崎田 省吾, 三苫 好治
    • Organizer
      第25回廃棄物資源循環学会
    • Place of Presentation
      広島工業大学五日市キャンパス
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ磁性鉄分散法による放射性汚染土壌の無排水式減容化技術2014

    • Author(s)
      三苫 好治
    • Organizer
      イノベーションジャパン2014
    • Place of Presentation
      東京ビックサイト東1ホール
    • Year and Date
      2014-09-11 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ金属紛体による放射性汚染土壌の減容化技術2014

    • Author(s)
      三苫 好治; 奥田 哲士
    • Organizer
      第3回環境放射能除染研究発表会
    • Place of Presentation
      福島市民文化センター
    • Year and Date
      2014-07-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノカルシウムを利用する放射性セシウムの磁力選別及び不溶化による除染技術2012

    • Author(s)
      三苫好治
    • Organizer
      第25回「原子力施設デコミッショニング技術講座」
    • Place of Presentation
      石垣記念ホール 東京(招待講演)
    • Year and Date
      2012-10-30
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノカルシウムによる複合汚染土壌浄化への挑戦 : PCBから放射性セシウムまで2012

    • Author(s)
      三苫好治
    • Organizer
      平成24年度広島地区化学講演会
    • Place of Presentation
      広島大学学士会館レセプションホール 広島(招待講演)
    • Year and Date
      2012-10-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] Solidification and Immobilization of Heavy metals in SoU using with nano-metallic Ca/CaO Dispersion Mixture2012

    • Author(s)
      Yoshiharu Mitoma
    • Organizer
      International Conference on Heavy Metals in the Environment (ICHMET-2012)
    • Place of Presentation
      Angelicum Congress Center, Italy
    • Year and Date
      2012-09-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] Novel Approach for the Remediation of Radioactive Cesium Contaminated SoU with nano-Fe/Ca/CaO Dispersion Mixture in Dry Condition2012

    • Author(s)
      Tetsuji Okuda
    • Organizer
      International Conference on Heavy Metals in the Environment (ICHMET-2012)
    • Place of Presentation
      Angelicum Congress Center, Italy
    • Year and Date
      2012-09-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] Solidification, Immobilization and Separation of Heavy Metals in SoU with Nano-Fe/Ca/CaO Dispersion Mixtures2012

    • Author(s)
      Yoshiharu Mitoma
    • Organizer
      6th International Conference on Environmental Science and Technology (ICEST 2012)
    • Place of Presentation
      Houston, USA
    • Year and Date
      2012-06-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノカルシウムによる放射性セシウム含有汚染土壌の乾式除染技術2012

    • Author(s)
      三苫好治
    • Organizer
      平成24年度第1回環境放射能除染研究発表会
    • Place of Presentation
      パルセいいざか 福島県
    • Year and Date
      2012-05-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] Hybrid-remediation with nano-size metallic calcium and iron dispersion for detoxification of multi-pollutants containing radioactive cesium, heavy metals and POPs in contaminated soil

    • Author(s)
      Srinivasa Reddy Mallampatia, Yoshiharu Mitoma, Tetsuji Okuda, Shogo Sakita, Mitsunori Kakeda.
    • Organizer
      Nanotek-2013
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks]

    • URL

      http://www.hiroshima-pu.ac.jp/~mitomay/index.htm

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://ww7.enjoy.ne.jp/~mitomay/

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 放射性物質汚染物の処理方法及び処理装置2013

    • Inventor(s)
      三苫 好治,小林 秀匡,松江 英彰,福岡 猛三
    • Industrial Property Rights Holder
      県立広島大学,株式会社御池鐵工所
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-15
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 放射性物質汚染土壌の処理方法及び放射性物質不溶化剤2013

    • Inventor(s)
      三苫 好治,崎田 省吾,奥田 哲士
    • Industrial Property Rights Holder
      県立広島大学,広島大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-06-06
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 放射性物質汚染物の処理方法及び処理装置2012

    • Inventor(s)
      三苫好治 小林秀匡 福岡猛三
    • Industrial Property Rights Holder
      公立大学法人県立広島大学 株式会社御池鐵工所
    • Industrial Property Number
      2012-115085
    • Filing Date
      2012-05-18
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 放射性物質含有粉粒体の処理方法2012

    • Inventor(s)
      三苫好治 畸田省吾 小林秀匡
    • Industrial Property Rights Holder
      公立大学法人県立広島大学 株式会社御池鐵工所
    • Industrial Property Number
      2012-271155
    • Filing Date
      2012-12-12
    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-23   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi