Synthesis of unsaturated main group elements compounds and their application for activation of small molecules
Project/Area Number |
24350031
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Kinki University |
Principal Investigator |
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Co-Investigator(Kenkyū-buntansha) |
HASHIZUME Daisuke 独立行政法人理化学研究所, その他部局等, ユニットリーダー (00293126)
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Project Period (FY) |
2012-04-01 – 2015-03-31
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Project Status |
Completed (Fiscal Year 2014)
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Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2014: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
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Keywords | 典型元素 / 不飽和結合 / ホウ素 / 水素化ホウ素化合物 / ジボラン / X線結晶構造解析 / ジホスフェン / リン / 水素化アルミニウム化合物 / 小分子活性化 |
Outline of Final Research Achievements |
Novel unsaturated compounds of boron, silicon, phosphorus, etc. have been synthesized by the introduction of the fused-ring bulky "Rind" groups, which we have recently developed. Their molecular structures and chemical bonding have been elucidated by the experimental and theoretical studies. We have also examined the reactivity of the resulting unsaturated main group elements compounds. Especially, we have focused on the synthesis of new hydroboron compounds, and their structures clearly confirmed by X-ray crystallography. The reactions of the dihydrodiborane(4) with small molecules such as dihydrogen and carbon monoxide have been investigated.
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Report
(4 results)
Research Products
(38 results)
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[Journal Article] Intramolecular [2+2+2] cycloaddition of bis(propargylphenyl)carbodiimides: synthesis of L-shaped π-extended compounds with pyrrolo[1,2-a][1,8]naphthyridine corner units2013
Author(s)
T. Otani, T. Saito, R. Sakamoto, H. Osada, A. Hirahara, N. Furukawa, N. Kutsumura, T. Matsuo, K. Tamao
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Journal Title
Chem. Commun.
Volume: 49
Issue: 55
Pages: 6206-6208
DOI
Related Report
Peer Reviewed
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