| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Outline of Final Research Achievements |
By applying artificial host molecules as parts, higher-order structures such as capsule-like and fibril structures have been built. Coordinative groups were introduced on the ortho positions of triphenolic host molecules, and the product tridentates were treated with a Pd(II) precursor to give M3L2-type capsule-like complex, which showed host ability. Macrocyclic host molecules consisted of 2,6- and 3,6-pyridylene rings were observed to self-associate by pi-stacking, and AFM images showed fibril structures. Tricationic derivative incorporated melamine with self-aggregate into cotton-like structure.
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