Fabrication of nanoporous film with periodically arranged photocatalysts in normally oriented cylindrical channels
| Project/Area Number |
24350067
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kyoto Institute of Technology |
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Principal Investigator |
ASAOKA Sadayuki 京都工芸繊維大学, 工芸科学研究科, 准教授 (50336525)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
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| Keywords | 機能性触媒 / ナノ材料 / 分子認識 / 自己組織化 / 人工光合成 |
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| Outline of Final Research Achievements |
The amphiphilic liquid crystalline diblock copolymers having a porphyrin or a rhenium complex at the junction of hydrophilic/hydrophobic segments were synthesized. In this copolymer film, the pigments were arranged along the normally oriented cylindrical phase segregation interfaces to form the periodically standing circular pigment arrays which were subject to the smectic layer structure of hydrophobic liquid crystalline domain. The blend film of these copolymers also gave normally oriented cylindrical nanostructure, in which the photo-induced electron transfer from porphyrins to rhenium complexes was observed.
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Report
(4 results)
Research Products
(29 results)
