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Fabrication of innovative energy materials by room-temperature ionic liquid-accelerated electron beam irradiation method

Research Project

Project/Area Number 24350071
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionOsaka University

Principal Investigator

TSUDA Tetsuya  大阪大学, 工学(系)研究科(研究院), 准教授 (90527235)

Co-Investigator(Renkei-kenkyūsha) KUWABATA Susumu  大阪大学, 工学研究科, 教授 (40186565)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords量子ビーム / ナノ粒子 / イオン液体 / 燃料電池 / リチウムイオン電池 / 電極触媒 / 負極活物質 / 酸素還元 / ナノ材料 / エネルギー全般 / 電気化学 / 加速器電子線 / 次世代電池
Outline of Final Research Achievements

In this research, nanoparticles of silicon, platinum alloy, and so on were produced through the nanoparticle synthesis process, which is called room-temperature ionic liquid-accelerated electron beam irradiation (RTIL-AEBI) method, by the combination of RTIL and AEBI. In order to clarify the nucleation and growth processes for the nanoparticles during the RTIL-AEBI method, similar reaction condition was replicated in a transmission electron microscope (TEM) system, and the whole processes were directly observed on a nanoscale. The resulting nanoparticles could be used for energy materials.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (50 results)

All 2015 2014 2013 2012 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results,  Acknowledgement Compliant: 6 results,  Open Access: 3 results) Presentation (27 results) (of which Invited: 5 results) Book (4 results) Remarks (3 results)

  • [Journal Article] In situ SEM observation of the Si negative electrode reaction in an ionic-liquid-based lithium-ion secondary battery2015

    • Author(s)
      Tetsuya Tsuda, Tsukasa Kanetsuku, Teruki Sano, Yoshifumi Oshima, Koichi Ui, Masaki Yamagata, Masashi Ishikawa, and Susumu Kuwabata
    • Journal Title

      Microscopy

      Volume: 64 Issue: 3 Pages: 159-168

    • DOI

      10.1093/jmicro/dfv003

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Novel Ionic Liquids with Aromatic Trifluoroborate Anions2014

    • Author(s)
      Kazuki Iwasaki, Kazuki Yoshii, Seiji Tsuzuki, Tetsuya Tsuda, and Susumu Kuwabata
    • Journal Title

      ECS Transaction

      Volume: 64(4) Issue: 4 Pages: 83-93

    • DOI

      10.1149/06404.0083ecst

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrodeposition of Al-W-Mn Alloy from Lewis Acidic AlCl3-1-Ethyl-3-methylimidazolium Chloride Ionic Liquid2014

    • Author(s)
      Tetsuya Tsuda, Yuichi Ikeda, Susumu Kuwabata, Gery R. Stafford, and Charles L. Hussey
    • Journal Title

      ECS Transaction

      Volume: 64(4) Issue: 4 Pages: 563-574

    • DOI

      10.1149/06404.0563ecst

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Energy Storage Device with a Lewis Acidic AlBr3-1-Ethyl-3-methylimidazolioum Bromide Room-Temperature Ionic Liquid2014

    • Author(s)
      Tetsuya Tsuda, Itsuki Kokubo, Masakatsu Kawabata, Masaki Yamagata, Masashi Ishikawa, Shohei Kusumoto, Akihito Imanishi, and Susumu Kuwabata
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 161(6) Issue: 6 Pages: A908-A914

    • DOI

      10.1149/2.029406jes

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrodeposition of Al-W Alloys in the Lewis Acidic Aluminum Chloride-1-Ethyl-3-Methylimidazolium Chloride Ionic Liquid2014

    • Author(s)
      Tetsuya Tsuda, Yuichi Ikeda, Takashi Arimura, Masaki Hirogaki, Akihito Imanishi, Susumu Kuwabata, Gery R. Stafford, and Charles L. Hussey
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 161(9) Issue: 9 Pages: D405-D412

    • DOI

      10.1149/2.016409jes

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] SEM Observation of Hydrous Superabsorbent Polymer Pretreated with Room-Temperature Ionic Liquids2014

    • Author(s)
      Tetsuya Tsuda1*, Eiko Mochizuki1, Shoko Kishida1, Kazuki Iwasaki1, Katsuhiko Tsunashima2, Susumu Kuwabata
    • Journal Title

      PLOS ONE

      Volume: 9(3) Issue: 3 Pages: e91193-e91193

    • DOI

      10.1371/journal.pone.0091193

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Physicochemical properties of 1-alkyl-3-methylimidazolium chloride-urea melts2013

    • Author(s)
      Tetsuya Tsuda, Koshiro Kondo, Masahiro Baba, Shotaro Suwa, Yuichi Ikeda, Taiki Sakamoto, Satoshi Seino, Hiroyuki Yoshida, Masanori Ozaki, Akihito Imanishi, Susumu Kuwabata
    • Journal Title

      Electrochimica Acta

      Volume: 100 Pages: 285-292

    • DOI

      10.1016/j.electacta.2012.05.156

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physicochemical Properties of Tri-n-butylalkylphosphonium Cation-Based Room-Temperature Ionic Liquids2013

    • Author(s)
      吉井一記
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 117 Issue: 48 Pages: 15051-15059

    • DOI

      10.1021/jp406791a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition of aluminum-hafnium alloy from the Lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride molten salt2013

    • Author(s)
      Tetsuya Tsuda, Susumu Kuwabata, Gery R. Stafford, Charles L. Hussey
    • Journal Title

      Journal of Solid State Electrochemistry

      Volume: 17 Issue: 2 Pages: 409-417

    • DOI

      10.1007/s10008-012-1933-y

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ SEM study of a lithium deposition and dissolution mechanism in a bulk-type solid-state cell with a Li2S-P2S5 solid electrolyte2013

    • Author(s)
      Motohiro Nagao, Akitoshi Hayashi, Masahiro Tatsumisago, Tsukasa Kanetsuku, Tetsuya Tsuda, Susumu Kuwabata
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 15 Issue: 42 Pages: 18600-18606

    • DOI

      10.1039/c3cp51059j

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Various metal nanoparticles produced by accelerated electron beam irradiation of room-temperature ionic liquid2012

    • Author(s)
      Tetsuya Tsuda, Taiki Sakamoto, Yoshitomo Nishimura, Satoshi Seino, Akihito Imanishi, Susumu Kuwabata
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 13 Pages: 1925-1927

    • DOI

      10.1039/c2cc16183d

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Electrochemical Reaction and Biological Specimen by Novel Analytical Technique Combined with Room-Temperature Ionic Liquid and Scanning Electron Microscope2012

    • Author(s)
      Tsuda, Tetsuya; Mochizuki, Eiko: Kuwabata Susumu, et al.
    • Journal Title

      Electrochemistry

      Volume: 80 Issue: 5 Pages: 308-311

    • DOI

      10.5796/electrochemistry.80.308

    • NAID

      40019237086

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum nanoparticle immobilization onto carbon nanotubes using Pt-sputtered room-temperature ionic liquid2012

    • Author(s)
      吉井一記
    • Journal Title

      RSC Advances

      Volume: 2 Issue: 22 Pages: 8262-8264

    • DOI

      10.1039/c2ra21243a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-ion Diffusion in Ionic Liquid Studied by Electrochemical Scanning Electron Microscopy with X-ray Fluorescence Spectrometry2012

    • Author(s)
      Uematsu, Taro; Tsuda, Tetsuya; Kuwabata Susumu, et al.
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 116 Issue: 39 Pages: 20902-20907

    • DOI

      10.1021/jp306241p

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of gold nanoparticles using reactive species produced in room-temperature ionic liquids by accelerated electron beam irradiation2012

    • Author(s)
      Tetsuya Tsuda, Taiki Sakamoto, Yoshitomo Nishimura, Satoshi Seino, Akihito Imanishi, Kazuhiko Matsumoto, Rika Hagiwara, Taro Uematsu and Susumu Kuwabata
    • Journal Title

      RSC Adv.

      Volume: 2 Issue: 31 Pages: 11801-11807

    • DOI

      10.1039/c2ra21353b

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold Nanoparticle Assisted Self-Assembly and Enhancement of Charge Carrier Mobilities of a Conjugated Polymer2012

    • Author(s)
      Vijayakuaar, Chakkooth; Tsuda, Tetsuya; Kuwabata, Susunu; Seki, Shu, et al.
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 116 Issue: 33 Pages: 17343-17350

    • DOI

      10.1021/jp3039253

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] イオン液体中における電気化学反応の可視化2015

    • Author(s)
      津田哲哉
    • Organizer
      第1回放射光連携研究ワークショップ
    • Place of Presentation
      ステーションコンファレンス東京(東京都千代田区)
    • Year and Date
      2015-03-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 金属イオンを含むイオン液体への電子線パターン照射による金属微小構造体 の作製2015

    • Author(s)
      入江晴康、南本大穂、上松太郎、津田哲哉、今西哲士、関 修平、桑畑 進
    • Organizer
      電気化学会第82 回大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体への加速器電子線照射によるPtNi 合金酸素還元触媒の合成2014

    • Author(s)
      坂本剛志、清野智史、津田哲哉、桑畑 進
    • Organizer
      第5 回イオン液体討論会
    • Place of Presentation
      横浜シンポジア(横浜市)
    • Year and Date
      2014-10-28 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体中での放射線化学反応制御による微細三次元構造体の作製2014

    • Author(s)
      南本大穂、入江晴康、上松太郎、津田哲哉、今西哲士、関 修平、桑畑 進
    • Organizer
      第5 回イオン液体討論会
    • Place of Presentation
      横浜シンポジア(横浜市)
    • Year and Date
      2014-10-28 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体を用いて作製した高耐久性燃料電池触媒2014

    • Author(s)
      山路佳佑、吉井一記、津田哲哉、鳥本 司、桑畑 進
    • Organizer
      第5 回イオン液体討論会
    • Place of Presentation
      横浜シンポジア(横浜市)
    • Year and Date
      2014-10-28 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 芳香族トリフルオロボラート系イオン液体への置換導入による影響2014

    • Author(s)
      岩﨑和紀、吉井一記、都築誠二、津田哲哉、桑畑 進
    • Organizer
      第4 回CSJ 化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of Novel Ionic Liquids with Aromatic Trifluoroborate Anions2014

    • Author(s)
      Kazuki Iwasaki, Kazuki Yoshii, Seiji Tsuzuki, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      226th Meeting of the Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-05 – 2014-10-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrodeposition of Al-W-Mn Alloy from Lewis Acidic AlCl3-[C2mim]Cl Ionic Liquid2014

    • Author(s)
      Tetsuya Tsuda, Yuichi Ikeda, Akihito Imanishi, Susumu Kuwabata, Gery R. Stafford, and Charles L. Hussey
    • Organizer
      226th Meeting of the Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 芳香族トリフルオロボラート系イオン液体の構造と物性の相関2014

    • Author(s)
      岩﨑和紀、吉井一記、都築誠二、津田哲哉、桑畑 進
    • Organizer
      2014 年電気化学秋季大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 量子ビームとイオン液体を組み合わせたナノ・マイクロ材料プロセッシング2014

    • Author(s)
      津田哲哉
    • Organizer
      資源素材学会 資源・素材2014
    • Place of Presentation
      熊本大学(熊本市)
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] イオン液体-スパッタリング法による金属ナノ粒子の調製に影響する因子の検討2013

    • Author(s)
      吉井一記, 山路佳佑, 津田哲哉, 綱島克彦、鳥本司、桑畑進
    • Organizer
      2013年 電気化学会第80回大会
    • Place of Presentation
      仙台市
    • Year and Date
      2013-03-30
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体へのスパッタリングにより合成した金属ナノ粒子を用いた炭素複合材料の調製とその利用2013

    • Author(s)
      吉井一記, 山路佳佑, 津田哲哉, 鳥本司、桑畑進
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津市
    • Year and Date
      2013-03-24
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体中への量子ビーム照射による三次元マイクロ・ナノ構造体の作製2013

    • Author(s)
      南本大穂, 津田哲哉, 今西哲士, 関修平, 桑畑進
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津市
    • Year and Date
      2013-03-24
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体を用いた電気化学アクチュエータデバイス2012

    • Author(s)
      津田哲哉
    • Organizer
      2012高分子・ハイブリッド材料研究センター若手フォーラム
    • Place of Presentation
      仙台市(招待講演)
    • Year and Date
      2012-12-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体-スパッタリング法を用いた金属ナノ粒子の調製-イオン液体の種類が粒径に及ぼす影響-2012

    • Author(s)
      津田哲哉, 吉井一記, 山路佳佑, 綱島克彦, 今西哲士, 鳥本司, 桑畑進
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      那覇市
    • Year and Date
      2012-12-08
    • Related Report
      2012 Annual Research Report
  • [Presentation] 溶融塩とイオン液体が切り拓く未来2012

    • Author(s)
      津田哲哉
    • Organizer
      新学術領域 融合マテリアル 第5回若手スクール
    • Place of Presentation
      鳥取市(招待講演)
    • Year and Date
      2012-11-27
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体を用いた電気化学デバイスの電極反応 -電子顕微鏡によるin situ観察-2012

    • Author(s)
      津田哲哉, 桑畑進
    • Organizer
      日本顕微鏡学会 第56回シンポジウム
    • Place of Presentation
      札幌市(招待講演)
    • Year and Date
      2012-11-20
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン液体-スパッタリング法を用いて作製した白金ナノ粒子-炭素複合材料の電極触媒2012

    • Author(s)
      吉井一記, 山路佳佑, 津田哲哉, 鳥本司、桑畑進
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡市
    • Year and Date
      2012-11-16
    • Related Report
      2012 Annual Research Report
  • [Presentation] Simple Fabrication of Pt Nanopartlcle-Carbon Nanotube Composite with Ionic Liciuid-Sputtering Method2012

    • Author(s)
      Yoshii Kazuki: Tsuaa; Tetsuya; Kuwabata Susumu, et al.
    • Organizer
      222nd The Electrochemical Society Meeting
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2012-10-12
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of 3D Polymer Structures from Room-Temperature Ionic Liquid by Quantum Beam Techniaues2012

    • Author(s)
      Minamimoto, Hlro; Tsuda, Tetsuya; Kuwabata, Susunu, et al.
    • Organizer
      222nd The Electrochemical Society Meeting
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2012-10-12
    • Related Report
      2012 Annual Research Report
  • [Presentation] Physicochemical Properties of Ionic Liquids Consisting of 1-Butyl-3-vinylimidazolium Cation and Halide Anions

    • Author(s)
      Tetsuya Tsuda, Ryosuke Taniki, Masahiro Baba, Haruki Narikawa, Yuki Iwasaki, Kazuhiko Matsumoto, Rika Hagiwara, Susumu Kuwabata
    • Organizer
      33rd International Conference on Solution Chemistry
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Annual Research Report
  • [Presentation] イオン液体-加速器電子線照射法による白金合金系酸素還元触媒の合成

    • Author(s)
      坂本剛志、津田哲哉、清野智史、桑畑 進
    • Organizer
      第45回溶融塩化学討論会
    • Place of Presentation
      横浜
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ptナノ粒子単分散イオン液体により作製した高耐久性酸素還元触媒

    • Author(s)
      山路佳佑、吉井一記、津田哲哉、鳥本 司、桑畑 進
    • Organizer
      第45回溶融塩化学討論会
    • Place of Presentation
      横浜
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子材料の電子顕微鏡観察に適したイオン液体

    • Author(s)
      津田哲哉、望月衛子、岸田祥子、桑畑 進
    • Organizer
      第54回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ELECTROCHEMICAL ACTUATOR WITH IONIC LIQUID-GRAPHENE-POLYMER COMPOSITE FLEXIBLE ELECRTRODES

    • Author(s)
      Tetsuya Tsuda, Yuki Iwasaki, Masaki Yamagata, Hirotomo Nishihara, Masashi Ishikawa, Susumu Kuwabata
    • Organizer
      The 7th Asian Conference on Electrochemical Power Sources
    • Place of Presentation
      Osaka
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Ptナノ粒子単分散イオン液体を用いて作製した酸素還元触媒の耐久性評価

    • Author(s)
      山路佳佑、吉井一記、津田哲哉、鳥本 司、桑畑 進
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electroplating of Al-W-Mn Ternary Alloy System in Aluminum Chloride-1-Ethyl-3-methylimidazolium Chloride Molten Salt

    • Author(s)
      Tetsuya Tsuda, Yuichi Ikeda, and Susumu Kuwabata
    • Organizer
      Kyoto International Forum for Environment and Energy (KIFEE) International Symposium on Environment, Energy and Materials
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Molten Salts Chemistry & Technology2014

    • Author(s)
      Tetsuya Tsuda, Eiko Mochizuki, Shoko Kishida, Noriko Nemoto, Yasuhito Ishigaki, and Susumu Kuwabata
    • Total Pages
      632
    • Publisher
      John Wiley & Sons
    • Related Report
      2014 Annual Research Report
  • [Book] Molten Salts Chemistry & Technology (M. Gaune-Escard and G. Haarberg, Eds.)2014

    • Author(s)
      Tetsuya Tsuda, Eiko Mochizuki, Shoko Kishida, Noriko Nemoto, Yasuhito Ishigaki, and Susumu Kuwabata
    • Total Pages
      632
    • Publisher
      John Wiley & Sons
    • Related Report
      2013 Annual Research Report
  • [Book] 電気化学便覧 第6版2013

    • Author(s)
      津田哲哉
    • Publisher
      丸善
    • Related Report
      2012 Annual Research Report
  • [Book] Ionic Liquids-New Aspects for the Future2013

    • Author(s)
      Kuwabata, Susumu: Tor imoto. Tsukasa: Tsuda Tetsuya, et al.
    • Publisher
      InTech
    • Related Report
      2012 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究室webページ

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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