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AC-Driven Electrochemiluminescent Device with Helical Biopolymer toward Circular Polarized Light Emission

Research Project

Project/Area Number 24350090
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionChiba University

Principal Investigator

KOBAYASHI Norihisa  千葉大学, 融合科学研究科(研究院), 教授 (50195799)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Kazuki  千葉大学, 大学院融合科学研究科, 助教 (00554320)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywords有機電子材料 / 生体高分子 / 電気化学発光 / 円偏光発光
Outline of Final Research Achievements

Circular polarized light (CPL) is expected to be a nex-generation light source which enables novel important applications. Electrochemiluminescence (ECL) is a light emitting phenomenon induced by electrochemical reaction. On the other hand, DNA complexes can show various function by interacting with other materials.
In this research program, in order to realize CPL device with large g-value, we integrated DNA complex with helical structure into AC driven ECL with quick emission response and high ECL intensity. Namely, we prepared novel DNA/Ru(bpy)32+ film-modified electrode and fablicated AC-operated ECL cell. The ECL properties of the cell was analyzed. As a result, the ECL was obtained from quite high frequency of 10 kHz, enabling quick response time of < 100 μs.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (26 results)

All 2015 2014 2013 2012 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 2 results) Presentation (9 results) (of which Invited: 4 results) Book (3 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Stretching and Immobilization of Photo-Electro Functional Nanowires Consisted of DNA and Functional Molecules2015

    • Author(s)
      Norinisa Kobayashi, Kazuki Nakamura, Makoto Nishizawa, Rena Son, Shintaro Inoue and Yuki Nishiyama
    • Journal Title

      Nonlinear Optics, Quantum Optics

      Volume: 47

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High-Contrast Electroswitching of Emission and Coloration Based on Single-Molecular Fluoran Derivatives2015

    • Author(s)
      Kenji kanazawa, Kazuki Nakamura and Norihisa Kobayashi
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 118 Issue: 31 Pages: 6026-6033

    • DOI

      10.1021/jp5060588

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Analysis of Charge Transport Property in Polymer Film Containing Triphenylamine Derivative Film using Impedance Spectroscopy2014

    • Author(s)
      Keita Ishii, Kazuki Nakamura and Norihisa Kobayashi,
    • Journal Title

      NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)

      Volume: 53 Issue: 4 Pages: 259-264

    • DOI

      10.11370/isj.53.259

    • NAID

      130004678689

    • ISSN
      1344-4425, 1880-4675
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of amide bond in gate dielectric polymers on memory performance of organic field-effect transistors2014

    • Author(s)
      Heisuke Sakai, Hea-Jeong Cheong, Takehito Kodzasa, Hideo Tokuhisa, Kazuhiko Tokoro, Manabu Yoshida, Taihei Ikoga, Kazuki Nakamura, Norihisa Kobayashi and Sei Uemura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S3 Pages: 05HB13-05HB13

    • DOI

      10.7567/jjap.53.05hb13

    • NAID

      210000143979

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-dependent characteristics of non-volatile transistor memory based on a polypeptide2014

    • Author(s)
      Lijuan Liang, Tomoo Fukushima, Kazuki Nakamura, Sei Uemura, Toshihide Kamata, Norihisa Kobayashi
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 2 Issue: 5 Pages: 879-883

    • DOI

      10.1039/c3tc31777c

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure of DNA-Octadecyltrimethylammonium Chloride Biopolymer Complex and the Application to Non-Volatile BiOTFT Memory2014

    • Author(s)
      Lijuan Liang, Kazuki Nakamura, Sei Uemura, Toshihide Kamata, and Norihisa Kobayashi
    • Journal Title

      Science of Advanced Materials

      Volume: -

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Materials for Novel Light Emitting Device and Dual Mode Display2013

    • Author(s)
      Taiki Nobeshima, Kazuki Nakamura, Norihisa Kobayashi
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 26 Issue: 3 Pages: 397-402

    • DOI

      10.2494/photopolymer.26.397

    • NAID

      130004721129

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction Mechanism and Improved Performance of Solution-Based Electrochemiluminescence Cell Driven by Alternating Current2013

    • Author(s)
      Taiki Nobeshima, Kazuki Nakamura, Norihisa Kobayashi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 5S1 Pages: 05DC18-05DC18

    • DOI

      10.7567/jjap.52.05dc18

    • NAID

      210000142244

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alternating- Current-Driven, Color-Tunable Electrochemiluminescent Cells2013

    • Author(s)
      Taiki Nobeshima. Masaru Nakakomi, Kazuki Nakamura, Norihisa Kobayashi
    • Journal Title

      Advanced Optical Materials

      Volume: 1 Issue: 2 Pages: 144-149

    • DOI

      10.1002/adom.201200056

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Emission Characteristics of AC-operated Electrochemiluminescent (ECL) Cell with Electroconductive Polymer2012

    • Author(s)
      M. Takase, S. Sugimoto, K. Nakamura and N. Kobayashi
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 25 Issue: 3 Pages: 261-265

    • DOI

      10.2494/photopolymer.25.261

    • NAID

      130004833449

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Electrochemical Optical-Modulation Device with Reversible Optical Property Transformation between Transparent, Mirror and Black2012

    • Author(s)
      S. Araki, K. Nakamura, K. Kobayashi, A. Tsuboi and N. Kobayashi
    • Journal Title

      Adv. Mater.

      Volume: 24 Issue: 23

    • DOI

      10.1002/adma.201200060

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Improvement of photopysical properties of emissive molecules in DNA matrix2014

    • Author(s)
      Norihisa Kobayashi, Wataru Watanabe and Kazuki Nakamura
    • Organizer
      SPIE Security&Diffince
    • Place of Presentation
      Amsterdam, Neitherland
    • Year and Date
      2014-09-22 – 2014-09-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Reflective and emissive dual mode display with electrochromism and electro- chemiluminescence2014

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      International caparica conference on chromogenics and emissive materials
    • Place of Presentation
      Caparica, Portugal
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] BioTFT memory with DNA gate dielectric and its thermal property2014

    • Author(s)
      Norihisa Kobayashi, Kazuki Nakamura, Sei Uemura and Toshihide Kamata
    • Organizer
      SPIE optics+Photonics
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2014-08-17 – 2014-08-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Alternating-Current-Driven Electrochemiluminescence for Solution-Based Multicolor Light-Emitting Device2013

    • Author(s)
      T. Nobeshima, M. Nakakomi, K. Nakamura, N. Kobayashi
    • Organizer
      International Display Workshop 2013
    • Place of Presentation
      Sapporo, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Photoemission Properties in Eu(III) Complex Doped DNA-CTMA Film2013

    • Author(s)
      N. Kobayashi, A. Sagara and K. Nakamura
    • Organizer
      SPIE Optics + Photonics 2013
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Fabrication and Characterization of OTFT Memory Based on DNA Gate Dielectric2013

    • Author(s)
      L.-J. Liang, K. Nakamura, S. Uemura, T. Kamata and N. Kobayashi
    • Organizer
      SPIE Optics + Photonics 2013
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Organic TFT Memory with Biopolymers as Gate Dielectric (BioTFT Memory) Toward Printed Electronics2012

    • Author(s)
      N. Kobayashi
    • Organizer
      1^<st>Int. Conf. Emerging Adv. Nanomater (Invited)
    • Place of Presentation
      Brisbane (Australia)
    • Year and Date
      2012-10-24
    • Related Report
      2012 Annual Research Report
  • [Presentation] Enhancement of Red Emission from Eu(III) Complex-Doped DNA-CTMA film2012

    • Author(s)
      K. Nakamura, A. Sagara and N. Kobayashi
    • Organizer
      SPIE Optics + Photonics 2012
    • Place of Presentation
      San Diego Convention Center (USA)
    • Year and Date
      2012-08-12
    • Related Report
      2012 Annual Research Report
  • [Presentation] Photo and Electronic Properties of DNA-Surfactant Complex2012

    • Author(s)
      N. Kobayashi, M. Fukabori and K. Nakamura
    • Organizer
      SPIE Optics + Photonics 2012 (Invited)
    • Place of Presentation
      San Diego Convention Center (USA)
    • Year and Date
      2012-08-12
    • Related Report
      2012 Annual Research Report
  • [Book] “Application of DNA to Materials Science 2” in DNA Engineering : Properties and Applications2015

    • Author(s)
      Norihisa Kobayashi and Kazuki Nakamura
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] “Electrochemical Luminescence” in Encyclopedia of Applied Electrochemistry2014

    • Author(s)
      Norihisa Kobayashi
    • Total Pages
      2169
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] “DNA electronics and photonics” in Electronic Processes in Organic Electronics: Bridging Nanostructure, Electronic States and Device Properties2014

    • Author(s)
      Norihisa Kobayashi and Kazuki Nakamura
    • Total Pages
      432
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Remarks] http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 発光材料及びこれを用いた表示装置2014

    • Inventor(s)
      小林範久,中村一希
    • Industrial Property Rights Holder
      小林範久,中村一希
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-178604
    • Filing Date
      2014-09-02
    • Related Report
      2014 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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