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Synthesis of advanced cathode with high activity for fuel cell by controlling the catalyst/support interface

Research Project

Project/Area Number 24350093
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionUniversity of Yamanashi

Principal Investigator

KAKINUMA Katsuyoshi  山梨大学, 総合研究部, 教授 (60312089)

Co-Investigator(Kenkyū-buntansha) UCHIDA Makoto  山梨大学, 総合研究部, 教授 (10526734)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywords固体高分子形燃料電池 / カソード / 酸化物ナノ粒子 / 微細構造 / Pt・Pt合金 / 固/固・固/気界面 / 耐久性 / 電極触媒 / 触媒活性 / ナノ材料 / 担体 / 酸化物 / 白金 / ナノ粒子 / アノード / 酸化スズ / 酸化チタン / 窒化チタン / ナノ材料合成 / 燃料電池 / 固固界面 / 固気界面
Outline of Final Research Achievements

Polymer electrolyte fuel cells (PEFCs) are applied to the fuel cell vehicles, and residential power generation. Platinum-based catalysts supported on carbon are typical cathode catalysts for PEFCs, but the degradation of the carbon support in the high potential region is a problem to be solved to apply for the fuel cell vehicles. We invented the new tin oxide nanoparticle supports with "fused-aggregated network structure" as candidate supports for high durable cathode catalysts by the flame combustion method. We also controlled the Pt/support (solid /solid) interface and Pt/gas (solid/gas) interface by sintering procedure, and evaluated the electronic conductivity, electrochemical properties and durability of Pt or Pt alloy catalyst. We found that the Pt alloy catalysts supported on the oxide nanoparticle support showed the 2.5 times higher oxygen reduction reaction activity and several hundred times durability compared with commercial Pt catalyst supported on the carbon catalyst.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (82 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (21 results) (of which Peer Reviewed: 17 results,  Acknowledgement Compliant: 8 results) Presentation (47 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Remarks (7 results) Patent(Industrial Property Rights) (7 results) (of which Overseas: 3 results)

  • [Journal Article] Influence of Pt Loading and Cell Potential on the HF Ohmic Resistance of an Nb-Doped SnO2-Supported Pt Cathode for PEFCs2016

    • Author(s)
      Y.Chino, K.Kakinuma, D.ATrik, M.Watanabe, M.Uchida
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 163

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Novel strategy to mitigate cathode catalyst degradation during air/air startup cycling via the atmospheric resistive switching mechanism of a hydrogen anode with a platinum catalyst supported on tantalum-doped titanium dioxide2015

    • Author(s)
      H.Shintani, Y.Kojima, K.Kakinuma, M.Watanabe, M.Uchida
    • Journal Title

      Journal of Power Sources

      Volume: 294 Pages: 292-298

    • DOI

      10.1016/j.jpowsour.2015.06.072

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Performance of practical-sized membrane-electrode assemblies using titanium nitride-supported platinum catalysts mixed with acetylene black as the cathode catalyst layer2015

    • Author(s)
      H.Shintani, K.Kakinuma, H.Uchida, M.Watanabe, M.Uchida
    • Journal Title

      Journal of Power Sources

      Volume: 280 Pages: 593-599

    • DOI

      10.1016/j.jpowsour.2015.01.132

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of added graphitized CB on both performance and durability of Pt/Nb-SnO2 cathode for PEFCs2015

    • Author(s)
      Y.Chino, K.Taniguchi, Y.Senoo, K.Kakinuma,M.Hara, M.Watanabe, M.Uchida
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 162 Issue: 7 Pages: F736-F743

    • DOI

      10.1149/2.0651507jes

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cathodic performance and high potential durability of Ta-SnO2 - δ-supported Pt catalysts for PEFC cathodes2015

    • Author(s)
      Senoo, Yuichi; Taniguchi, Koji; Kakinuma, Katsuyoshi; Uchida, Makoto; Uchida, Hiroyuki; Deki, Shigehito; Watanabe, Masahiro
    • Journal Title

      Electrochemistry Communications

      Volume: 51 Pages: 37-40

    • DOI

      10.1016/j.elecom.2014.12.005

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of short-side-chain perfluorosulfonic acid ionomers as binders on the performance of low Pt loading fuel cell cathodes2015

    • Author(s)
      Young-Chul; Kakinuma, Katsuyoshi; Uchida, Hiroyuki; Watanabe, Masahiro; Uchida, Makoto
    • Journal Title

      Journal of Power Sources

      Volume: 275 Pages: 384-391

    • DOI

      10.1016/j.jpowsour.2014.10.149

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Oxidation of Hydrolyzed Poly Oxymethylene-dimethyl Ether by PtRu Catalysts on Nb-Doped SnO2-δSupports for Direct Oxidation Fuel Cells2014

    • Author(s)
      Kakinuma, Katsuyoshi; Kim, In-Tae; Senoo, Yuichi; Yano, Hiroshi; Watanabe, Masahiro; Uchida, Makoto
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 6 Issue: 24 Pages: 22138-22145

    • DOI

      10.1021/am505553b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Improvements in electrical and electrochemical properties of Nb-doped SnO2-δ supports for fuel cell cathodes due to aggregation and Pt loading2014

    • Author(s)
      Senoo, Yuichi; Kakinuma, Katsuyoshi; Uchida, Makoto; Uchida, Hiroyuki; Deki, Shigehito; Watanabe, Masahiro
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 61 Pages: 32180-32188

    • DOI

      10.1039/c4ra03988b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of the effect of a hydrophilic layer in the gas diffusion layer of a polymer electrolyte membrane fuel cell on the cell performance and cold start behaviour2014

    • Author(s)
      Satoki Hirakata, Masanori Hara, Katsuyosi Kakinuma, Makoto Uchida, Donald A. Tryk, Hiroyuki Uchida, Masahiro Watanabe
    • Journal Title

      Electrochimica Acta

      Volume: 120 Pages: 240-247

    • DOI

      10.1016/j.electacta.2013.12.050

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature- and Humidity-Controlled SAXS Analysis of Proton-Conductive Ionomer Membranes for Fuel Cells2014

    • Author(s)
      T. Mochizuki, K. Kakinuma, M. Uchida, S. Deki, M. Watanabe, K. Miyatake
    • Journal Title

      ChemSusChem

      Volume: 7 Issue: 3 Pages: 729-733

    • DOI

      10.1002/cssc.201301322

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Pt Catalysts on Nb-Doped and Sb-Doped SnO2–δ Support Materials with aggregated Structure by Rotating Disk Electrode and Fuel Cell Measurements2013

    • Author(s)
      Katsuyoshi Kakinuma, Yuji Chino, Yuichi Senoo, Makoto Uchida, Takeo Kamino, Hiroyuki Uchida, Shigehito Deki and Masahiro Watanabe
    • Journal Title

      Electrochimica Acta

      Volume: 110 Pages: 316-324

    • DOI

      10.1016/j.electacta.2013.06.127

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the state of distribution of supported Pt nanoparticles on effective Pt utilization in polymer electrolyte fuel cells2013

    • Author(s)
      Uchida, Makoto; Park, Young-Chul; Kakinuma, Katsuyoshi; Yano, Hiroshi; Tryk, Donald A.; Kamino, Takeo; Uchida, Hiroyuki; Watanabe, Masahiro
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 15 Issue: 27 Pages: 11236-11247

    • DOI

      10.1039/c3cp51801a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation between surface chemical composition with catalytic activity and selectivity of organic-solvent synthesized Pt-Ti nanoparticles2013

    • Author(s)
      Jiwei Ma, Aurelien Habrioux,Toshihiro Miyao, Katsuyoshi Kakinuma, Junji Inukai, Masahiro Watanabe and Nicolas Alonso-Vante
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 1 Issue: 31 Pages: 8798-8804

    • DOI

      10.1039/c3ta11499f

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deleterious effects of interim cyclic voltammetry on Pt/carbon black catalyst degradation during start-up/shutdown cycling evaluation2013

    • Author(s)
      Young-Chul Park, Katsuyoshi Kakinuma, Makoto Uchida, Hiroyuki Uchida, Masahiro Watanabe
    • Journal Title

      Electrochimica Acta

      Volume: 15 Pages: 84-92

    • DOI

      10.1016/j.electacta.2013.12.120

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体高分子形燃料電池の触媒層のPt削減と耐久性向上のための開発の歴史と将来設計2013

    • Author(s)
      内田誠、柿沼克良、渡辺政廣
    • Journal Title

      粉砕

      Volume: 56 Pages: 3-11

    • NAID

      130007495450

    • Related Report
      2013 Annual Research Report
  • [Journal Article] 固体高分子形燃料電池用カソード触媒の研究開発2013

    • Author(s)
      内田裕之、野原愼士、矢野啓、脇坂暢、柿沼克良、内田誠、出来成人、渡辺政廣
    • Journal Title

      燃料電池

      Volume: 12 Pages: 50-57

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Investigation of the Corrosion of Carbon Supports in Polymer Electrolyte Fuel Cells Using Simulated Start-up/Shutdown Cycling2013

    • Author(s)
      Y.-C. Park, K. Kakinuma, M. Uchida, D. A. Tryk, T. Kamino, H. Uchida, M. Watanabe
    • Journal Title

      Electrochim. Acta

      Volume: 91 Pages: 195-207

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体高分子形燃料電池及びその電極触媒用担体材料2013

    • Author(s)
      内田誠、柿沼克良、渡辺政廣
    • Journal Title

      粉砕

      Volume: 56 Pages: 3-11

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Preparation of Titanium Nitride-supported Platinum Catalysts with Well Controlled Morphology and Their Properties Relevant to Polymer Electrolyte Fuel Cells2012

    • Author(s)
      K. Kakinuma, Y. Wakasugi, M. Uchida, T. Kamino, H. Uchida, S. Deki, M. Watanabe
    • Journal Title

      Electrochim. Acta

      Volume: 77 Pages: 279-284

    • DOI

      10.1016/j.electacta.2012.06.001

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature Dependence of Oxygen Reduction Reaction Activity at Stabilized PtSkin-PtCo Alloy/Graphitized Carbon Black Catalysts Prepared by a Modified Nanocapsule Method2012

    • Author(s)
      K. Okaya, H. Yano, K. Kakinuma, M. Watanabe, H. Uchida
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 4 Issue: 12 Pages: 6982-6991

    • DOI

      10.1021/am302224n

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体高分子形燃料電池及びその電極触媒用担体材料2012

    • Author(s)
      柿沼克良、内田誠、上野武夫、内田裕之、渡辺政廣
    • Journal Title

      化学装置

      Volume: 5 Pages: 27-32

    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化スズに高分散担持したPt-Co合金カソード触媒の合成と活性評価2016

    • Author(s)
      林 美月、柿沼 克良、飯山 明裕、内田 誠
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリオキシメチレンジメチルエーテル燃料を用いた液体燃料系触媒設計とMEA評価2016

    • Author(s)
      平山 尚樹,朴 英哲, 柿沼 克良,飯山 明裕,渡辺 政廣,内田 誠
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機オリゴマー燃料を用いた直接形燃料電池用Pt/Ta-SnO2アノード触媒の研究2015

    • Author(s)
      平山尚樹,柿沼克良,朴英哲,渡辺政廣,内田誠
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センター(愛知県)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effect of Added Graphitized Carbon Black on Both Performance and Durability2015

    • Author(s)
      Makoto Uchida, Yuji Chino, Koji Taniguchi, Yuichi Senoo, Katsuyoshi Kakinuma, Masanori Hara, Masahiro Watanabe
    • Organizer
      Electrochemical Society
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2015-10-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of Pt Catalysts Supported on Ta and Nb-SnO2 with Fused Aggregated Network Structure2015

    • Author(s)
      Katsuyoshi Kakinuma, Yuichi Senoo, Kohji Taniguchi, Masahiro Watanabe, Makoto Uchid
    • Organizer
      Electrochemical Society
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2015-10-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mitigation of Cathode Catalyst Degradation during Air/Air Startup Cycling via the Atmospheric Resistivity2015

    • Author(s)
      Haruhiko Shintani, Yuya Kojima, Katsuyoshi Kakinuma, Masahiro Watanabe, Makoto Uchida
    • Organizer
      Electrochemical Society
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2015-10-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Evaluation of Pt Catalysts Supported on Nb-Doped SnO2 in Membrane-Electrode Assemblies for PEFCs2015

    • Author(s)
      Yuji Chino, Yuichi Senoo, Katsuyoshi Kakinuma, Masahiro Watanabe, Makoto Uchida
    • Organizer
      Electrochemical Society
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2015-10-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mitigation of cathode catalyst degradation during air/air startup cycling via the atomospheric resistive swiching mechanism of a hydrogen anode with a platinum catalyst supported on tantalum-doped titanium dioxide2015

    • Author(s)
      H. Shintani, Y. Kojima, K. Kakinuma, M. Watanabe, M. Uchida
    • Organizer
      Internatioanl Fuel Cell Workshop 2016
    • Place of Presentation
      Kohu, Japan
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical evaluation of platinum catalysts supported on niobium-doped tin oxide in single cell for PEFC2015

    • Author(s)
      Y. Chino, K. Kakinuma, M. Watanabe, M. Uchida
    • Organizer
      Internatioanl Fuel Cell Workshop 2016
    • Place of Presentation
      Kohu, Japan
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pt担持TaドープTiO2触媒の合成とカソード活性評価2014

    • Author(s)
      小嶋裕也, 新谷晴彦, 柿沼克良, 内田誠, 内田裕之, 渡辺政廣
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館(京都府京都市)
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] ハーフセル及びMEAを用いたPt担持SnO2触媒の性能評価2014

    • Author(s)
      柿沼克良, 妹尾雄一, 千野裕二, 谷口浩司, 内田誠, 内田裕之, 出来成人, 渡辺政廣
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館(京都府京都市)
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Durability of Pt/Graphitized Carbon Black Catalysts Under Gas Exchange Start-up Operating Conditions for Fuel Cell Vehicles2014

    • Author(s)
      Y. Yamashita, S. Itami, J. Takano, M. Kodama, K. Kakinuma, M. Hara, H. Uchida, M. Watanabe, and M. Uchida,
    • Organizer
      226th ECS Meeting
    • Place of Presentation
      Cancun, (Mexico)
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Improvements of Electrical and Electrochemical Activities at Nb-SnO2 Supports by Aggregation and Pt Loading as Fuel Cell Cathode Catalysts2014

    • Author(s)
      K. Kakinuma, Y. Senoo, Y. Chino, K. Taniguchi, M. Uchida, H. Uchida, S. Deki, and M. Watanabe
    • Organizer
      226th ECS Meeting
    • Place of Presentation
      Cancun, (Mexico)
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single Cell Performances of Membrane Electrode Assemblies using Pt/Nb-SnO2–δ Cathode Catalysts for PEFCs2014

    • Author(s)
      Y. Chino, Y. Senoo, K. Taniguchi, M. Uchida, K. Kakinuma, H. Uchida, S. Deki, and M. Watanabe
    • Organizer
      64th Annual Meeting of the International Society of Electrochemistry (ISE
    • Place of Presentation
      Cancun, (Mexico)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single Cell Performances of Membrane Electrode Assembliesusing Pt/Doped-SnO2 Catalysts for Polymer Electrolyte Fuel Cells2014

    • Author(s)
      Y. Chino, K. Taniguchi, Y. Senoo, M. Uchida, K. Kakinuma, H. Uchida, and M. Watanabe
    • Organizer
      The 3rd International Seminar on Green Energy Conversion
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Performance and Durability of Titanium Nitride-Supported Platinum Catalysts for Polymer Electrolyte Fuel Cells2014

    • Author(s)
      H. Shintani, K. Kakinuma, M. Watanabe, and M. Uchida
    • Organizer
      The 3rd International Seminar on Green Energy Conversion
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Improvements in Electrical and Electrochemical Properties of Nb-Doped SnO2–δ Supports due to Aggregation and Pt Loading2014

    • Author(s)
      Y. Senoo, Y. Chino, K. Kakinuma, M. Uchida, H. Uchida, S. Deki, and M. Watanabe
    • Organizer
      The 3rd International Seminar on Green Energy Conversion
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Investigation of Cathode Catalyst Degradation under Gas Exchange Start-Up Operation for Fuel Cell Vehicles2014

    • Author(s)
      Y. Yamashita, S. Itami, J. Takano, M. Kodama, K. Kakinuma, M, Hara, M. Uchida, H. Uchida, and M.Watanabe
    • Organizer
      The 3rd International Seminar on Green Energy Conversion
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of both Pt Distribution and Carbon Microstructure of Cathode Catalyst on Fuel Cell Performance2014

    • Author(s)
      T. Tokiwa, M. Uchida, K. Kakinuma, H. Uchida, and M. Watanabe
    • Organizer
      The 3rd International Seminar on Green Energy Conversion
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] PEFC用高電位安定担体及びPt担持触媒の合成と評価2014

    • Author(s)
      柿沼克良, 内田誠, 内田裕之, 出来成人, 渡辺政廣
    • Organizer
      第21回燃料電池シンポジウム
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effects of short-side-chain perfluorosulfonic acid ionomers on low Pt loading of Pt/graphitized carbon black catalyst in fuel cell cathode catalyst layers2014

    • Author(s)
      朴英哲,柿沼克良,内田誠,内田裕之,渡辺政廣
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アグリゲート構造を有するPt/Nb-SnO2カソード触媒の導電率、電気化学特性2014

    • Author(s)
      妹尾雄一,柿沼克良,千野祐二,谷口浩司,内田誠,内田裕之,出来成人,渡辺政廣
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pt/Nb-SnO_2カソード触媒のアグリゲート構造と電気化学特性との相関2013

    • Author(s)
      妹尾雄一、千野裕二、柿沼克良、内田誠、内田裕之、出来成人、渡辺政廣
    • Organizer
      電気化学会創立第80周年記念大会
    • Place of Presentation
      東北大学川内キャンパス(宮城県)
    • Year and Date
      2013-03-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pt/TiCカソード触媒の電気化学特性と耐久性評価2013

    • Author(s)
      千綿司雄、柿沼克良、内田誠、内田裕之、出来成人、渡辺政廣
    • Organizer
      電気化学会創立第80周年記念大会
    • Place of Presentation
      東北大学川内キャンパス(宮城県)
    • Year and Date
      2013-03-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] Characterization of Pt catalysts on Nb-doped and Sb-doped SnO2-σ support materials with aggregated structure by rotating disk electrode and fuel cell measurement2013

    • Author(s)
      K. Kakinuma, M.Uchida, H.Uchida, S.Deki, M.Watanabe
    • Organizer
      6th International Conference on Polymer Batteries and Fuel Cells (PBFC 2013)
    • Place of Presentation
      UlmCongressCentrum(ドイツバーデン州ウルム)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Relationship between Aggregated Structure and Electrochemical Property of Pt Catalyst Supported on Nb-Doped Tin Oxide2013

    • Author(s)
      Y. Senoo, Y. Chino, K. Kakinuma, M. Uchida, H. Uchida, S. Deki, M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electrochemical Evaluation of Pt/SnO2-5 Catalysts for Polymer Electrolyte Fuel Cells in Half Cell and Membrane Electrode Assembly Measurements2013

    • Author(s)
      Y. Chino, M. Uchida, K. Kakinuma, H. Uchida, M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Durability of Pt/TiC Cathode Catalysts for PEFC2013

    • Author(s)
      M. Chiwata, M. Uchida, K. Kakinuma, H. Uchida, M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of Water Property and Morphology of Hydrocarbon Ionomer Membranes on Fuel Cell2013

    • Author(s)
      T. Mochizuki, K.Miyatake, K.Kakinuma, M.Uchida, H.Uchida, M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Investigation of Cathode Catalyst Durability under Gas Exchange Start-Up Operation for Fuel Cell Vehicles2013

    • Author(s)
      Y. Yamashita,S. Itami, T. Iwanari, J. Takano,M. Kodama,K. Kakinuma,M. Hara, M. Uchida,H. Uchida,M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Investigation of the Microstructure of Carbon-Supported Pt Catalysts for the Improvement of Fuel Cell Performance2013

    • Author(s)
      H. Tokiwa,M. Uchida, K. Kakinuma, H. Uchida, M. Watanabe
    • Organizer
      博士課程教育リーディングプログラム「グリーンエネルギー変換工学」第2回国際セミナー
    • Place of Presentation
      小海リエックス・ホテル (長野県南佐久郡小海町)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pt担持カーボン触媒の細孔構造とPt分布状態解析およびセル特性評価2013

    • Author(s)
      常磐春輝,柿沼克良,内田誠, 内田裕之,渡辺政廣
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場(大阪府大阪市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PEFC用Pt/SnO2系カソード触媒の電気化学特性評価2013

    • Author(s)
      柿沼克良, 妹尾雄一,千野裕二, 谷口浩司,内田誠, 内田裕之,出来成人, 渡辺政廣
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場(大阪府大阪市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electrochemical Properties of Pt Catalysts Supported on Nb-Doped SnO2 with Network Structure2013

    • Author(s)
      Y. Senoo, Y. Chino, M. Uchida, H. Uchida, S. Deki, M. Watanabe
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel(米国サンフランシスコ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electrochemical Characterization of Pt Catalysts Supported on Nb-SnO2-6 and Sb-SnO2-6 with Aggregated Structure in Membrane Electrode Assembly Measurements2013

    • Author(s)
      Y. Chino,M. Uchida, H. Uchida, S. Deki, M. Watanabe
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel(米国サンフランシスコ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of Interim Cyclic Voltammetry on Pt/CB Catalyst Degradation during Start-up/shutdown Cycling Evaluation2013

    • Author(s)
      Y. C. Park, K. Kakinuma, M. Hara, M. Uchida, H. Uchida, M. Watanabe
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel(米国サンフランシスコ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Durability of Cathode Catalysts under Gas Exchange Start-up Operation for Fuel Cell Vehicle2013

    • Author(s)
      Y. Yamashita, S. Itami, T. Iwanari, J. Takano, M. Kodama, K. Kakinuma, M. Hara, M. Uchida, H. Uchida, M. Watanabe
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel(米国サンフランシスコ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Performance and Durability of Titanium Nitride-Supported Platinum Catalysts for Polymer Electrolyte Fuel Cells2013

    • Author(s)
      H. Shintani, K. Kakinuma, M. Uchida, H. Uchida, Y. Tsuji, M. Watanabe
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel(米国サンフランシスコ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 噴霧プラズマ法によるNi高分散GdドープCeO_2の合成と可逆SOFC用水素極特性2012

    • Author(s)
      佐山悠樹、Paramote Puttinder, 西野華子、柿沼克良、渡辺政廣、内田裕之
    • Organizer
      第21回SOFC研究発表会
    • Place of Presentation
      科学技術館サンエンスホール(東京都)
    • Year and Date
      2012-12-17
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pt/SnO_2系カソード触媒を用いたPEFCの電気化学特性評価2012

    • Author(s)
      千野裕二、柿沼克良、内田誠、内田裕之、渡辺政廣
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク(福岡県)
    • Year and Date
      2012-11-16
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pt/TiC系カソード触媒の合成と電気化学特性評価2012

    • Author(s)
      千綿司雄、柿沼克良、内田誠、内田裕之、出来成人、渡辺政廣
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク(福岡県)
    • Year and Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二酸化ケイ素被覆した燃料電池用カソード触媒の耐久性評価2012

    • Author(s)
      有馬丈博、市川雄太、矢野啓、柿沼克良、出来成人、渡辺政廣、内田裕之
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク(福岡県)
    • Year and Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] 燃料電池自動車のガス置換起動時におけるカソード触媒の耐久性評価2012

    • Author(s)
      山下侑耶、柿沼克良, 他7名
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク(福岡県)
    • Year and Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electrochemical characterization of Pt catalysts supported on Sn_0.96Nb_0.04O_2-8 and Sn_0.96Sb_0.04O_2-8 with aggregated structure in rotating disk electrode and membrane electrode assembly measurements2012

    • Author(s)
      K.Kakinuma, 他7名
    • Organizer
      PRiME 2012
    • Place of Presentation
      ホノルル ハワイ (アメリカ)
    • Year and Date
      2012-10-12
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electrochemical activity and interfacial characteristics of new cathode catalystsfor polymer electrolyte fueI cells2012

    • Author(s)
      K.Kakinuma, 他8名
    • Organizer
      ICCCI 2012
    • Place of Presentation
      ホテル日航倉敷(岡山県)
    • Year and Date
      2012-09-04
    • Related Report
      2012 Annual Research Report
  • [Presentation] SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF Pt CATAL YST SUPPORTED ON Nb-DOPED TIN OXIDE WITH A NETWORK STRUCTURE2012

    • Author(s)
      Y.Senoo, Y.Chino, K.Kakinuma, 他4名
    • Organizer
      IFCW 2012
    • Place of Presentation
      甲府富士屋ホテル(山梨県)
    • Year and Date
      2012-08-03
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of Metal Oxide Thin Layers on Various Materials for Fuel Cells by the Liquid Phase Deposition(LPD) Method2012

    • Author(s)
      M.Ishida, M.Kodama, K.Kakinuma, S.Deki, M.Watanabe
    • Organizer
      IFCW 2012
    • Place of Presentation
      甲府富士屋ホテル(山梨県)
    • Year and Date
      2012-08-03
    • Related Report
      2012 Annual Research Report
  • [Remarks] 山梨大学 燃料電池ナノ材料研究センター 研究成果

    • URL

      http://fc-nano.yamanashi.ac.jp/kenkyu/seika/seika.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 山梨大学燃料電池ナノ材料研究センター 研究紹介 研究成果

    • URL

      http://fc-nano.yamanashi.ac.jp/kenkyu/seika/seika.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_Index.Main

    • Related Report
      2014 Annual Research Report
  • [Remarks] 山梨大学燃料電池ナノ材料研究センター 研究紹介 研究成果

    • URL

      http://fc-nano.yamanashi.ac.jp/kenkyu/seika/seika.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispDetail.Scholar

    • Related Report
      2013 Annual Research Report
  • [Remarks] 山梨大学燃料電池ナノ材料研究センター研究紹介研究成果

    • URL

      http://fc-nano.yamanashi.ac.jp/kenkyu/seika/seika.Html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispDetail.Scholar

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] セル、燃料電池スタック、燃料電池システムおよび膜-電極接合体2016

    • Inventor(s)
      新谷晴彦、柿沼克良、内田誠、渡辺政廣
    • Industrial Property Rights Holder
      国立大学法人山梨大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 合金電極触媒およびにそれを用いた燃料電池2016

    • Inventor(s)
      柿沼克良、内田誠、飯山明裕
    • Industrial Property Rights Holder
      国立大学法人山梨大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 燃料電池システム及びその運用方法2015

    • Inventor(s)
      内田誠、柿沼克良、飯山明裕、渡辺政廣
    • Industrial Property Rights Holder
      国立大学法人山梨大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-08-11
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 燃料電池のアノード用触媒、アノード及び燃料電池2015

    • Inventor(s)
      内田誠、柿沼克良、渡辺政廣
    • Industrial Property Rights Holder
      国立大学法人山梨大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 電極触媒および電極触媒の製造方法2015

    • Inventor(s)
      柿沼克良、内田誠、渡辺政廣
    • Industrial Property Rights Holder
      柿沼克良、内田誠、渡辺政廣
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 電極触媒及びその製造方法2014

    • Inventor(s)
      妹尾雄一、柿沼克良、内田誠、内田裕之、渡辺政廣
    • Industrial Property Rights Holder
      妹尾雄一、柿沼克良、内田誠、内田裕之、渡辺政廣
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 電極触媒及びその製造方法2013

    • Inventor(s)
      柿沼克良、内田誠、渡辺政廣、妹尾雄一
    • Industrial Property Rights Holder
      柿沼克良、内田誠、渡辺政廣、妹尾雄一
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-208672
    • Filing Date
      2013-10-03
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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