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Nonvolatile memory devices with metallo-supramolecular polymers

Research Project

Project/Area Number 24350097
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionNational Institute for Materials Science

Principal Investigator

Higuchi Masayoshi  国立研究開発法人物質・材料研究機構, 先端的共通技術部門, グループリーダー (80306852)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2014: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Keywordsメタロ超分子ポリマー / 不揮発性メモリ / 整流特性 / メモリデバイス
Outline of Final Research Achievements

This research project was at first planned for three fiscal years from 2012 to 2014, but extended for one more fiscal year (2015), because we have found unique rectification properties in nonvolatile memory devices with metallo-supramolecular polymers. As the result, we have achieved to control the direction of current flow in the device by perpendicular alignment of metallo-supramolecular polymers, which are composed of asymmetrical organic modules and Pt(II) ions (ACS Appl. Mater. Interfaces, 2015, 7, 19034-19042).

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(12 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (10 results)

  • [Journal Article] Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification2015

    • Author(s)
      C. Chakraborty, R. K. Pandey, M. D. Hossain, Z. Futera, S. Moriyama, M. Higuchi
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 7 Pages: 19034-19042

    • DOI

      10.1021/acsami.5b03434

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] From Metal Complexes to Metallosupramolecular Polymers via Polycondensation : Synthesis, Structure and Electrochromic Properties of Co(III)- and Fe(III)-Based Metallosupramolecular Polymers with Aromatic Azo Ligands2013

    • Author(s)
      Anasuya Bandyopadhyay, Masayoshi Higuchi
    • Journal Title

      European Polymer Journal

      Volume: 49(In press)

    • DOI

      10.1016/j.eurpolymj.2013.03.015

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Multifunctional Fe(II)/Pt(II) Based Hetero-Metallo Supramolecular Polymer2015

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Alternate Fe(II)/Pt(II) Based Bi-metallic Supramolecular Polymer for Enhanced Optoelectrical Properties2015

    • Author(s)
      Chanchal Chakraborty, Masayoshi Higuchi
    • Organizer
      錯体化学会 第65回討論会
    • Place of Presentation
      奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effect of Structure on the Optoelectronic Properties of Bimetallic Metallo-supramolecular Polymers with Different Geometry2015

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pt(II)-Based Metallo-Supramolecular Polymers with Unidirectional Polarity for Enhanced Electronic Properties2014

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pt(II)-Based Metallo-Supramolecular Polymers with Controlled Unidirectional Polarity2014

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-18 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pt(II)-Based Metallo-Supramolecular Polymers with unidirectional polarity: Synthesis, Characterization and Electronic properties2014

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      NIMS Conference 2014
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2014-07-01 – 2014-07-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Metallo-supramolecular polymers with unidirectinal polarity2014

    • Author(s)
      Chanchal Chakraborty, Satoshi Moriyama, Masayoshi Higuchi
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and Characterization of Fe/Cu-Based Organic-HeterometallicHybrid Polymers2013

    • Author(s)
      Md.Delwar HOSSAIN, Masayoshi HIGUCHI
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県草津市)
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and Electrochromic Properties of Cu/Fe-Based Organic-Heterometallic Hybrid Polymers2013

    • Author(s)
      Md. Delwar Hossain, Masayoshi Higuchi
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会議場(京都府京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis, Characterization and Electronic Properties of Alternating Cu/Fe- and Ni/Fe-Based Heterometallo-Supramolecular Polymers2013

    • Author(s)
      Md. Delwar Hossain, Jian Zhang, Masayoshi Higuchi
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-23   Modified: 2019-07-29  

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