• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Organometallic Hybrid Phosphorescent Materials Aimed at Printable Organic Light-emitting Diodes Based on Innovative Device Structures

Research Project

Project/Area Number 24350101
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Organic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

YAGI SHIGEYUKI  大阪府立大学, 工学(系)研究科(研究院), 准教授 (40275277)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywords有機電子デバイス / OLED / りん光材料 / 有機金属錯体 / 溶液塗布法 / エキシマー発光 / キャリア輸送 / 白色電界発光 / OLED
Outline of Final Research Achievements

Aimed at development of solution-processable high-performance organic light-emitting diodes (OLEDs) with innovative device structures, we here prepared novel organometallic phosphorescent materials with carrier-transporting ability. Employing cyclometalated ligands with pi-extended conjugation systems and carrier-transporting dendrons, we successfully obtained phosphorescent organoplatinum(II) and organoiridium(III) complexes which are applicable to the emission layers in OLEDs. Using the developed hybrid phosphorescent materials as a single emission layer, solution-processed OLEDs were successfully fabricated. Furthermore, doping a red phosphorescent material into the emitting layer, white-emitting device was also obtained.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(43 results)

All 2015 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 1 results) Presentation (29 results) (of which Invited: 5 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Photo- and Electroluminescence from Organoplatinum(II) Complexes Bearing Oligofluorene-Based Cyclometalated Ligands2015

    • Author(s)
      Shigeyuki Yagi, Tatsuya Shigehiro, Tomonari Takata, Takeshi Maeda, Hiroyuki Nakazumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Starburst-Type Carbazole Trimers as Host Materials for Solution-Processed Phosphorescent OLEDs2015

    • Author(s)
      Naoki Okamura, Hiroshi Funagoshi, Shigeru Ikawa, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] White Polymer Light-emitting Diodes Co-doped with Three Phosphorescent Iridium(III) Complexes Aimed at Improvement of Color Rendering Properties2014

    • Author(s)
      Shigeru Ikawa, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi, Yoshiaki Sakurai
    • Journal Title

      J. Lumin.

      Volume: 155 Pages: 368-373

    • DOI

      10.1016/j.jlumin.2014.05.026

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo- and Electroluminescence from Deep Red- and Near Infrared-Phosphorescent tris-Cyclometalated Iridium(III) Complexes Bearing Largely p-Extended Ligands2013

    • Author(s)
      Shigeru Ikawa, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi, Hideki Fujiwara, Shiro Koseki, Yoshiaki Sakurai
    • Journal Title

      Inorganic Chemistry Communication

      Volume: 38 Pages: 14-19

    • DOI

      10.1016/j.inoche.2013.09.075

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo- and Electroluminescence from 2- (dibenzo [b, d] furan-4-yl) pyridinebased Heteroleptic Cyclometalated Platinum(II) Complexes2013

    • Author(s)
      T. Shigehiro, S. Yagi, T. Maeda, H. Nakazumi, H. Fujiwara, Y. Sakurai
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 532-542

    • DOI

      10.1021/jp307853t

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] White Polymer Light-emitting Diodes Co-doped with Phosphorescent Iridium Complexes2012

    • Author(s)
      S. Ikawa, S. Yagi, T. Maeda, H.Nakazumi
    • Journal Title

      Phys. Status Solidi C

      Volume: 9 Pages: 2553-2556

    • DOI

      10.1002/pssc.201200422

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Operating Voltage-independent White Electroluminescence from Phosphorescent Ir(III)2012

    • Author(s)
      Y. Sakurai, S. Yagi, S. Ikawa, H.Asuka
    • Journal Title

      Phys. Status Solidi C

      Volume: 9 Pages: 2557-2560

    • DOI

      10.1002/pssc.201200450

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 溶液塗布技術を利用したりん光型白色有機EL素子の開発2012

    • Author(s)
      八木繁幸,井川茂,中澄博行
    • Journal Title

      WEB ジャーナル

      Volume: 134 Pages: 14-17

    • Related Report
      2012 Annual Research Report
  • [Presentation] 2-フェニル-1H-イミダゾール系配位子を有する新規有機イリジウム錯体の合成と発光特性2015

    • Author(s)
      石黒和弥、岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 3,5-ジ(カルバゾール-9-イル)フェニル基を付与したデンドリマー型青色りん光性有機イリジウム錯体の合成と発光特性2015

    • Author(s)
      岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ホール輸送性ホスト機能を有するデンドリマー型青色りん光性イリジウム錯体の合成と発光特性2014

    • Author(s)
      岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      大阪府立大学21世紀科学研究機構分子エレクトロニックデバイス研究所第16回RIMEDシーズ発掘講演会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス(大阪府)
    • Year and Date
      2014-11-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photo- and Electroluminescence from 2-(Dibenzo[b,d]furan-4-yl)pyridine-Based Cyclometalated Platinum(II) Complexes2014

    • Author(s)
      Qiang Chen, Tatsuya Shigehiro, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi
    • Organizer
      大阪府立大学21世紀科学研究機構分子エレクトロニックデバイス研究所第16回RIMEDシーズ発掘講演会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス(大阪府)
    • Year and Date
      2014-11-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Luminescent Properties of 2-(Dibenzo[b,d]furan-4-yl)pyridine-Based Cyclometalated Platinum(II) Complexes in Polymer Thin Films2014

    • Author(s)
      Qiang Chen, Tatsuya Shigehiro, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi, Takeshi Tanaka, Yoshiaki Sakurai
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] カルバゾール含有デンドロンを有する新規青色りん光性有機イリジウム錯体の合成と発光特性2014

    • Author(s)
      岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 塗布型OLEDを指向したりん光性有機金属錯体の配位子デザイン2014

    • Author(s)
      八木繁幸
    • Organizer
      高分子学会印刷・情報記録・表示研究会および光反応・電子用材料研究会
    • Place of Presentation
      大阪府立大学I-seiteなんば(大阪府)
    • Year and Date
      2014-10-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Photo- and Electroluminescence from Organoplatinum(II) Complexes Bearing Oligofluorene-Based Cyclometalated Ligands2014

    • Author(s)
      Shigeyuki Yagi, Tatsuya Shigehiro, Tomonari Takata, Takeshi Maeda, Hiroyuki Nakazumi
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics (KJF-ICOMEP 2014)
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Starburst-Type Carbazole Trimers as Host Materials for Solution-Processed Phosphorescent OLEDs2014

    • Author(s)
      Naoki Okamura, Hiroshi Funagoshi, Shigeru Ikawa, Shigeyuki Yagi, Takeshi Maeda, Hiroyuki Nakazumi
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics (KJF-ICOMEP 2014)
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 塗布型有機ELを指向したりん光性有機金属錯体の機能設計2014

    • Author(s)
      八木繁幸
    • Organizer
      日本接着学会関西支部平成26年度第1回接着ワークショップ
    • Place of Presentation
      大阪市立工業研究所(大阪府)
    • Year and Date
      2014-07-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ホール輸送性デンドロンを有する新規青色りん光性イリジウム(III)錯体の合成と発光特性2014

    • Author(s)
      岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子EL素子中におけるシクロメタル化白金(II)錯体のエキシマー形成とその発光挙動2013

    • Author(s)
      重広龍矢,八木繁幸,前田壮志,中澄博行,櫻井芳昭
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県)
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] 種々の電子求引基を有する新規シクロメタル化白金錯体のエキシマー発光挙動2013

    • Author(s)
      岡村奈生己,八木繁辛,前田壮志
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県)
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] カルバゾール含有デンドロンを有する新規シクロメタル化イリジウム(III)錯体の合成と発光特性2013

    • Author(s)
      宮崎美帆、八木繁幸、前出壮志、中澄博行
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県)
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Excimer-based Photo- and Electroluminescence from Cyclometalated Platinum(II) Complexes Controlled by Cyclometalated and Ancillary Ligands2013

    • Author(s)
      Shigeyuki Yagi, Tatsuya Shigehiro, Naoki Okamura, Hideki Fujiwara, Yoshiaki Sakurai, Hiroyuki Nakazumi
    • Organizer
      11th International Symposium on Functional pi-Electron Systems (Fpi-11)
    • Place of Presentation
      Palais Des Congres D'Arcachon (Arcachon, France)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of Single-doped White Organic Light-emitting Diodes with High Color Rendering Properties Utilizing Excimer Emission from Cylometalated Platinum(II) Complexes2013

    • Author(s)
      Shigeyuki Yagi, Naoki Okamura, Takeshi Maeda, Hiroyuki Nakazumi
    • Organizer
      85th Japan Society of Colour Material (JSCM) Anniversary Conference
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カルバゾール系ホール輸送部位を有する新規シクロメタル化イリジウム(III)錯体の合成と電界発光挙動2013

    • Author(s)
      八木繁幸、宮﨑美帆、前田壮志、中澄博行
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学目白キャンパス(東京都豊島区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] フェニルピリジン配位子上に種々の置換基を有するシクロメタル化白金(II)錯体のエキシマー発光挙動2013

    • Author(s)
      岡村奈生己、八木繁幸、前田壮志、中澄博行
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学城北地区キャンパス(愛媛県松山市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポリビニルカルバゾール型素子中でのシクロメタル化白金錯体(II)の電気光学特性. エキシマー発光とその挙動2013

    • Author(s)
      櫻井芳昭、八木繁幸、重広龍矢、前田壮志、片桐真子、中澄博行
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 非ドープ型OLEDへの応用を目的としたカルバゾール含有デンドロンを有する新規ビスシクロメタル化イリジウム(III)錯体の合成と電界発光特性2013

    • Author(s)
      宮﨑美帆、八木繁幸、前田壮志、中澄博行
    • Organizer
      色材協会創立85周年記念研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 2-(ジベンゾ[b,d]フラン-4-イル)ピリジンをシクロメタル化配位子に用いた白金(II)錯体の発光挙動2013

    • Author(s)
      陳強、重広龍矢、八木繁幸、前田壮志、中澄博行
    • Organizer
      色材協会創立85周年記念研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of Novel Phosphorescent Platinum(II)Complexes Bearing Oligofluorene-based Cyclometalated Ligands2012

    • Author(s)
      S. Yagi, T. Takata, T. Shigehiro, T. Maeda, H. Nakazumi
    • Organizer
      12th International Kyoto Conference on Organic Chemistry (IKCOC-12)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府)
    • Year and Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] 同一シクロメタル化配位子を有するりん光性ビスシクロメタル化イリジウム錯体を用いた高分子白色電界発光素子の作製2012

    • Author(s)
      井川茂、八木繁幸、前田壮志、中澄博行、櫻井芳昭
    • Organizer
      2012年度色材研究発表会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス(大阪府)
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] フルオレン糸π共役拡張型シクロメタル化配位子を有するりん光性白金(II)錯体の合成と高分子電界発光素子への応用2012

    • Author(s)
      高田智成、重広龍矢、八木繁幸、前田壮志、中澄博行、櫻井芳昭
    • Organizer
      2012年度色材研究発表会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス(大阪府)
    • Year and Date
      2012-09-20
    • Related Report
      2012 Annual Research Report
  • [Presentation] White Polymer Light-emitting Diodes Co-doped with Phosphorescent Iridium Complexes Bearing the Same Cyclometalated Ligand2012

    • Author(s)
      S. Ikawa, S. Yagi, T. Maeda,H. Nakazumi
    • Organizer
      5th International Conference on Optical, Optoelectronic and Photonic Materials and Applications(IC00PMA2012)
    • Place of Presentation
      奈良県新公会堂(奈良県)
    • Year and Date
      2012-06-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] Operating Voltage-independent White Electroluminescence from Phosphorescent Ir(III>Complexes Embedded in Poly (N-vinylcarbazole)2012

    • Author(s)
      Y. Sakurai, S. Yagi, S. Ikawa, H. Asuka, T. Maeda, H. Nakazumi
    • Organizer
      5th International Conference on Optical, Optoelectronic and Photonic Materials and Applications(IC00PMA2012)
    • Place of Presentation
      奈良県新公会堂(奈良県)
    • Year and Date
      2012-06-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] White Electroluminescent Devices Using Phosphorescent Organometallic Complexes

    • Author(s)
      Shigeyuki Yagi
    • Organizer
      Lecture in University of Leeds
    • Place of Presentation
      University of Leeds (Leeds, UK)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 塗布型白色PLED用発光材料の開発

    • Author(s)
      八木繁幸
    • Organizer
      機能性材料に関する公開シンポジウム
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機EL素子への応用を指向したりん光性有機金属錯体の高機能化

    • Author(s)
      八木繁幸
    • Organizer
      東海コンファレンス 2013 in 岐阜
    • Place of Presentation
      岐阜大学(岐阜県岐阜市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 機能性色素の科学、第16章 ディスプレイ用色素2013

    • Author(s)
      八木繁幸、中澄博行
    • Total Pages
      23
    • Publisher
      化学同人
    • Related Report
      2013 Annual Research Report
  • [Remarks] 有機機能科学研究グループ

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 大阪府立大学大学院工学研究科物質・化学系専攻応用化学分野有機機能化学研究グループ

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] イリジウム錯体およびそれを用いた有機エレクトロルミネッセンス素子2015

    • Inventor(s)
      八木繁幸
    • Industrial Property Rights Holder
      公立大学法人大阪府立大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-02-18
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] イリジウム錯体およびそれを用いた有機エレクトロルミネッセンス素子2014

    • Inventor(s)
      八木繁幸
    • Industrial Property Rights Holder
      公立大学法人大阪府立大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-047889
    • Filing Date
      2014-03-11
    • Related Report
      2013 Annual Research Report

URL: 

Published: 2012-04-23   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi