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Establishment of interzeolite conversion method as alternative zeolite synthesis method

Research Project

Project/Area Number 24350105
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionHiroshima University

Principal Investigator

SANO TSUNEJI  広島大学, 工学(系)研究科(研究院), 教授 (80251974)

Co-Investigator(Kenkyū-buntansha) SADAKANE Masahiro  広島大学, 大学院工学研究院, 准教授 (10342792)
IDE Yusuke  広島大学, 大学院工学研究院, 助教 (40449327)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Keywordsゼオライト転換 / 構造規定剤 / 構造類似性 / 水熱合成 / 構造ユニット / ゼオライト / ナノパーツ
Outline of Final Research Achievements

Many types of zeolites such as *BEA, CHA, LEV, RUT, and MFI were successfully synthesized by interzeolite conversion of FAU, *BEA, and LEV type zeolites as starting materials under various hydrothermal synthesis conditions. The crystallization rates of zeolites using such starting zeolites were notably elevated compared to rates observed in conventional hydrothermal syntheses using amorphous aluminosilicate gels. This characteristic enhancement in the crystallization rate results from the generation of locally ordered aluminosilicate species through the decomposition/dissolution of the starting zeolite, resulting in assembly and evolution into another type of zeolite. The structural similarity between the starting zeolite and the final crystallized zeolite is a crucial factor for interzeolite conversion. These findings strongly indicate that the interzeolite conversion route is an attractive strategy for zeolite synthesis.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (33 results)

All 2014 2013 2012

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (17 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Facile Synthesis of AEI Zeolite by Hydrothermal Conversion of FAU Zeolite in the Presence of Tetraethylphosphonium Cations2014

    • Author(s)
      Toshihiro Maruo, Naoki Yamanaka, Nao Tsunoji, Masahiro Sadakane Tsuneji Sano
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 3 Pages: 302-304

    • DOI

      10.1246/cl.130996

    • NAID

      130004868019

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal conversion of FAU and *BEA-type zeolites into MAZ-type zeolites in the presence of non-calcined seed crystals2014

    • Author(s)
      K. Honda, A. Yashiki, M. Sadakane, T. Sano
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 196 Pages: 254-260

    • DOI

      10.1016/j.micromeso.2014.05.028

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of high-silica AEI zeolites with enhanced thermal stability by hydrothermal conversion of FAU zeolites, and their activity in the selective catalytic reduction of NOx with NH32014

    • Author(s)
      園田拓志、圓尾俊博、山崎義貴、津野地直、定金正洋、佐野庸治
    • Journal Title

      Journal of Material Chemistry

      Volume: 3 Issue: 2 Pages: 857-865

    • DOI

      10.1039/c4ta05621c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Role of structural similarity between starting zeolite and product zeolite in the interzeolite conversion process2013

    • Author(s)
      Honda, M.Itakura, Y.Matsuura, A.Onda, Y.Ide, M.Sadakane, T.Sano
    • Journal Title

      J. Nanosci. Nanotechnol.

      Volume: 13 Pages: 3020-3026

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] First synthesis of SAPO molecular sieve with LTL-type structure by hydrothermal conversion of SAPO-37 with FAU-type structure2013

    • Author(s)
      Y. Umehara, M. Itakura, N. Yamanaka, M. Sadakane, T. Sano
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 179 Pages: 224-230

    • DOI

      10.1016/j.micromeso.2013.06.013

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of structure-directing agents on FAU-CHA interzeolite conversion and preparation of high pervaporation performance CHA zeolite membranes for the dehydration of acetic acid solution2013

    • Author(s)
      N. Yamanaka, M. Itakura, Y. Kiyozumi, M. Sadakane, T. Sano
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 86 Pages: 1333-1340

    • NAID

      130004153155

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High potential of interzeolite conversion method for zeolite synthesis2013

    • Author(s)
      T. Sano, M. Itakura, M. Sadakane
    • Journal Title

      J. Jpn. Petrol. Inst.

      Volume: 56 Pages: 183-197

    • NAID

      130003365154

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライト前駆体としての新規層状ケイ酸塩HUS-nの合成とその特性2013

    • Author(s)
      津野地直、井出裕介、定金正洋、佐野庸治
    • Journal Title

      工業材料

      Volume: 61 Pages: 18-21

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent2012

    • Author(s)
      Y. Ide
    • Journal Title

      Chem. Commun.

      Volume: 48 Issue: 56 Pages: 7073-7075

    • DOI

      10.1039/c2cc32743k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transformation ofLEV-type zeolite into less dense CHA-type zeolite2012

    • Author(s)
      I. Goto
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 158 Pages: 117-122

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acid stability evaluation of CHA-type zeolites synthesized by interzeolite conversion of FAU-typezeolite and their membrane application for dehydration of acetic acid aqueous solution2012

    • Author(s)
      N. Yamanaka
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 158 Pages: 141-147

    • DOI

      10.1016/j.micromeso.2012.03.030

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO_2-choline hydroxide-NaOH-H_2O system2012

    • Author(s)
      N. Tsunoji
    • Journal Title

      J. Mater. Chem.

      Volume: 22 Issue: 27 Pages: 13682-13690

    • DOI

      10.1039/c2jm31872e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of toluene on alkali metal ion-exchanged ZSM-5 and β-zeolites under humid conditions2012

    • Author(s)
      Y.Takamiatsu
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 85 Issue: 8 Pages: 869-876

    • DOI

      10.1246/bcsj.20120036

    • NAID

      130004153101

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] FAUゼオライト転換によるCHAゼオライトナノ結晶の合成2014

    • Author(s)
      高田知佳, 山中直樹, 園田拓志, 津野地直, 定金正洋, 佐野庸治
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] FAUゼオライト転換によるTi-CHAの合成2014

    • Author(s)
      國武祐輔, 園田拓志, 山中直樹, 津野地直, 定金正洋, 佐野庸治
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] テトラエチルホスホニウムカチオンを用いたゼオライト転換による高シリカAEI型ゼオライトの合成とその耐熱性2014

    • Author(s)
      園田拓志, 津野地直, 圓尾俊博, 高光泰之, 定金正洋, 佐野庸治
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 種々のホスホニウムカチオン存在下でのFAUゼオライト転換2014

    • Author(s)
      山崎義貴, 圓尾俊博, 園田拓志, 津野地直, 定金正洋, 佐野庸治
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and characteristics of high-silica AEI zeolite through hydrothermal conversion of FAU zeolite using tetraethyl-phosphonium hydroxide as SDA2014

    • Author(s)
      T. Maruo, T. Sonoda, N. Yamanaka, M. Sadakane, T. Sano
    • Organizer
      6th International FEZA Conference
    • Place of Presentation
      Leipzig (Germany)
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] First Synthesis of SAPO molecular sieve with LTL-type structure (HUZ-1) by hydrothermal conversion of SAPO-37 with FAU-type structure2013

    • Author(s)
      Y.Umehara, M.Itakura, N.Yamanaka, M.Sadakane, T.Sano
    • Organizer
      7th International Symposium on Acid-Base Catalysis
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of SDA on FAU-CHA Interzeolite Conversion2013

    • Author(s)
      N.Yamanaka, M.Itakura, Y.Kiyozumi, M.Sadakane, T.Sano
    • Organizer
      7th International Symposium on Acid-Base Catalysis
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of SDA on FAU-CHA Interzeolite Conversion2013

    • Author(s)
      N.Yamanaka, M.Itakura, Y.Kiyozumi, M.Sadakane
    • Organizer
      17th International Zeolite Conference
    • Place of Presentation
      モスクワ(ロシア)
    • Related Report
      2013 Annual Research Report
  • [Presentation] テトラエチルホスホニウムカチオン存在下でのFAUゼオライト転換によるAEIゼオライト合成2013

    • Author(s)
      圓尾俊博、山中直樹、津野地直、定金正洋、佐野庸治
    • Organizer
      ゼオライト学会第29回ゼオライト研究発表会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] FAU-CHA型ゼオライト転換に及ぼす有機構造規定剤の影響2013

    • Author(s)
      山中直樹、清住嘉道、定金正洋、佐野庸治
    • Organizer
      ゼオライト学会第29回ゼオライト研究発表会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ゼオライト転換過程を目指して2012

    • Author(s)
      板倉正也
    • Organizer
      第28回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2012-11-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] ゼオライト転換法CHA型ゼオライトの耐酸性評価2012

    • Author(s)
      山中直樹
    • Organizer
      第28回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2012-11-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] SiO2-choline hydroxide-NaOH-H2O系からの新規層状ケイ酸塩の合成2012

    • Author(s)
      津野地直
    • Organizer
      第28回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2012-11-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of high-silica CHA membrane by interzeolite conversion of FAU and Its pervaporation performance,2012

    • Author(s)
      Y. Kiyozumi
    • Organizer
      International Symposium on Zeolites and Microporous Materials (2012)
    • Place of Presentation
      アステールプラザ(広島市)
    • Year and Date
      2012-07-31
    • Related Report
      2012 Annual Research Report
  • [Presentation] Efficient Way to Synthesize Hiroshima University Silicate-1 (HUS-1) and the Selective Adsorption Property ofNi2+ from Seawater2012

    • Author(s)
      N. Tsunoji
    • Organizer
      International Symposium on Zeolites and Microporous Materials (2012)
    • Place of Presentation
      アステールプラザ(広島市)
    • Year and Date
      2012-07-31
    • Related Report
      2012 Annual Research Report
  • [Presentation] BEA-MFI and LEV-CHA interzeolite conversions in the absence of organic structure-directing agent and seed crystal2012

    • Author(s)
      M. Itakura
    • Organizer
      International Symposium on Zeolites and Microporous Materials (2012)
    • Place of Presentation
      アステールプラザ(広島市)
    • Year and Date
      2012-07-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] Evaluation of Acid Stability ofCHA Zeolite Synthesized by Interzeolite Conversion of FAU Zeolite2012

    • Author(s)
      N. Yamanaka
    • Organizer
      International Symposium on Zeolites and Microporous Materials (2012)
    • Place of Presentation
      アステールプラザ(広島市)
    • Year and Date
      2012-07-29
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] LEV型ゼオライトの製造方法、およびリンを含有するLEV型ゼオライ2014

    • Inventor(s)
      佐野庸治、定金正洋、高光泰之
    • Industrial Property Rights Holder
      佐野庸治、定金正洋、高光泰之
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-189859
    • Filing Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] MEI型ゼオライトの製造方法、およびリンを含有するMEI型ゼオライト2014

    • Inventor(s)
      佐野庸治、定金正洋、高光泰之
    • Industrial Property Rights Holder
      佐野庸治、定金正洋、高光泰之
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-189860
    • Filing Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] ゼオライト薄膜を有する複合膜およびその製造方法2013

    • Inventor(s)
      長谷川泰久、清住嘉道、佐野庸治
    • Industrial Property Rights Holder
      長谷川泰久、清住嘉道、佐野庸治
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-205622
    • Filing Date
      2013-09-30
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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