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Nonlinear Dynamics of Hybrid Polymer Nanoassemblies

Research Project

Project/Area Number 24350112
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

MITSUISHI Masaya  東北大学, 多元物質科学研究所, 教授 (70333903)

Co-Investigator(Renkei-kenkyūsha) YAMAMOTO Shunsuke  東北大学, 多元物質科学研究所, 助教 (70707257)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2012: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Keywords超薄膜 / 高分子構造・物性 / ハイブリッド / ナノシート / 集積体 / 光機能 / 電子機能
Outline of Final Research Achievements

Ferroelectric polymer, poly(vinylidene fluoride) (PVDF) ultrathin films were prepared by the Langmuir-Blodgett technique. The film consists of high content of beta crystalline phases generated at the air-water interface. With the help of amphiphilic polymer poly(N-dodecylacrylamide), the films were successfully transferred on solid substrates by the vertical dipping method. Silsesquioxane polymer nanosheets were converted into SiO2 nanofilms on flexible substrates through UV irradiation at ambient condition. Reversible conductivity switching was also demonstrated.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (49 results)

All 2015 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 5 results) Presentation (35 results) (of which Invited: 7 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Solvent dependent properties of poly(vinylidene fluoride) monolayers at the air-water interface2015

    • Author(s)
      Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi
    • Journal Title

      Soft Matter

      Volume: 11 Issue: 10 Pages: 1962-1972

    • DOI

      10.1039/c4sm02800g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Superhydrophobic Porous Surfaces: Dissolved Oxygen Sensing2015

    • Author(s)
      Yu Gao, Tao, Chen, Shunsuke Yamamoto, Tokuji Miyashita, Masaya Mitsuishi
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 7 Issue: 6 Pages: 3468-3472

    • DOI

      10.1021/am509147h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Flexible SiO2 Nanofilms Assembled on Poly(ethylene terephthalate) Substrates through a Room Temperature Fabrication Process for Nanoscale Integration2015

    • Author(s)
      Shunsuke Yamamoto, Kazuki Sonobe, Tokuji Miyashita and Masaya Mitsuishi
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 6 Pages: 1286-1293

    • DOI

      10.1039/c4tc02131b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Luminescence Properties of Platinum Porphyrin Embedded in Multilayered Polymer Nanosheets2014

    • Author(s)
      Masaya Mitsuishi, Tao Chen, Yu Gao, and Tokuji Miyashita
    • Journal Title

      International Journal of the Society of Materials Engineering for Resources

      Volume: 20 Pages: 6-11

    • NAID

      130005095353

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ハイブリッド系高分子ナノシート材料の開発2014

    • Author(s)
      山本俊介, 宮下徳治, 三ツ石方也
    • Journal Title

      化学工業

      Volume: 65 Pages: 937-943

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Luminescence Propterties of Platinum Porphyrin Embedded in Multilayered Polymer Nanosheets2014

    • Author(s)
      Masaya Mitsuishi, Tao Chen, Yu Gao, Tokuji Miyashita
    • Journal Title

      International Journal of the Society of Materials Engineering for Resources

      Volume: 20

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of back energy transfer in blue phosphorescent materials for organic light emitting diodes by time-resolved optical waveguide spectroscopy2013

    • Author(s)
      H. Hirayama, Y. Sugawara, Y. Miyashita, M. Mitsuishi, T. Miyashita
    • Journal Title

      Applied Physics Letters

      Volume: 102 Issue: 8 Pages: 88124-88124

    • DOI

      10.1063/1.4792838

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高分子によるナノシートデザイン 構造から光・電子制御まで2013

    • Author(s)
      三ツ石方也, 宮下徳治
    • Journal Title

      化学と工業

      Volume: 66 Pages: 906-908

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Facile Preparation of Highly Oriented Poly(vinylidene fluoride) Langmuir-Blodgett Nanofilms Assisted by Amphiphilic Polymer Nanosheets2012

    • Author(s)
      Huie Zhu
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 22 Pages: 9076-9084

    • DOI

      10.1021/ma301711g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Flexible SiO2 Nanofilms Assembled on Poly(ethylene terephthalate) Substrates through a Room Temperature Fabrication Process2015

    • Author(s)
      Shunsuke Yamamoto, Kazuki Sonobe, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      ACS 249th National Meeting
    • Place of Presentation
      Denver, USA
    • Year and Date
      2015-03-22 – 2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高分子ナノシートから作製したSiO2超薄膜の抵抗変化動作2015

    • Author(s)
      北中孝尚、山本俊介、宮下徳治、三ツ石方也
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] π共役系材料の精密集積化と機能性素子への応用2015

    • Author(s)
      山本俊介
    • Organizer
      平成26年度東北地区先端高分子セミナー
    • Place of Presentation
      仙台
    • Year and Date
      2015-03-09 – 2015-03-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 高分子ナノシートから作製した光酸化SiO2超薄膜の電気特性2014

    • Author(s)
      北中孝尚、山本俊介、宮下徳治、三ツ石方也
    • Organizer
      第14回東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      仙台
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Crystal structuring of poly(vinylidene fluoride) at the air-water interface from α phase to β phase2014

    • Author(s)
      Huie Zhu, Jun Matsui, Shunsuke Yamamoto, Tokuji Miyashita and Masaya Mitsuishi
    • Organizer
      The 10th SPSJ International Polymer Conference
    • Place of Presentation
      筑波
    • Year and Date
      2014-12-03 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] A highly sensitive dissolved oxygen sensor based on superhydrophobic porous film2014

    • Author(s)
      Yu Gao, Shunsuke Yamamoto, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] シロキサンからなるナノ材料を用いたハイブリッド高分子薄膜の構築2014

    • Author(s)
      三ツ石 方也
    • Organizer
      第33回無機高分子研究討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-13 – 2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 高分子ナノシートをテンプレートとした酸化物超薄膜の作製2014

    • Author(s)
      山本俊介、園部和輝、三ツ石方也、宮下徳治
    • Organizer
      2014高分子学会東北支部研究発表会
    • Place of Presentation
      郡山
    • Year and Date
      2014-11-13 – 2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] シルセスキオキサン含有高分子ナノシートを用いたSiO2超薄膜のフレキシブル基板上への作製2014

    • Author(s)
      山本俊介、園部和輝、三ツ石方也、宮下徳治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] カルバゾール基を有する両親媒性高分子の合成と高密度集積化の検討2014

    • Author(s)
      仁科七重、山本俊介、三ツ石方也、宮下徳治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎
    • Year and Date
      2014-09-23 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 一次元金属回折格子上での高分子ナノ集積体中の光の伝搬特性2014

    • Author(s)
      印藤健也、森田晋平、山本俊介、田和圭子、西井準治、宮下徳治、三ツ石方也
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Highly Oriented Poly(vinylidene fluoride) Langmuir-Blodgett Nanofilms with Greatly Improved Ferroelectricity2014

    • Author(s)
      Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      18th International Symposium on Advanced Display Materials and Devices
    • Place of Presentation
      仙台
    • Year and Date
      2014-07-23 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高分子超薄膜による表面・界面機能設計2014

    • Author(s)
      三ツ石方也、宮下徳治
    • Organizer
      第32回高分子表面研究会講座
    • Place of Presentation
      東京
    • Year and Date
      2014-07-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Ultra-Thin SiO2 Films from Langmuir-Blodgett Films with Silsesquioxane Units2014

    • Author(s)
      Shunsuke Yamamoto, Kazuki Sonobe, Masaya Mitsuishi, Tokuji Miyashita
    • Organizer
      2014 IUPAC World Polymer Congress
    • Place of Presentation
      Chiangmai, Thailand
    • Year and Date
      2014-07-06 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Bottom-up Design of Hybrid Polymer Nanoassemblies2014

    • Author(s)
      Masaya Mitsuishi, Kenya Indo, Shimpei Morita, Shunsuke Yamamoto, Tokuji Miyashita, Keiko Tawa, and Junji Nishii
    • Organizer
      NIMS Conference 2014
    • Place of Presentation
      筑波
    • Year and Date
      2014-07-01 – 2014-07-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 金属回折格子上での高分子ナノ集積体の光伝播特性2014

    • Author(s)
      印藤健也、森田晋平、山本俊介、田和圭子、西井準治、宮下徳治、三ツ石方也
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] シルセスキオキサン含有高分子ナノシートの光酸化によるSiO2超薄膜の生成機構とその電気的特性2014

    • Author(s)
      山本俊介、園部和輝、三ツ石方也、宮下徳治
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] カルバゾール基を有する両親媒性高分子の単分子膜挙動と高密度集積化2014

    • Author(s)
      仁科七重、山本俊介、三ツ石方也、宮下徳治
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ferroelectric Nanocapacitors of Poly(vinylidene fluoride) Langmuir-Blodgett Nanofilms for Nonvolatile Memories2013

    • Author(s)
      Huie Zhu
    • Organizer
      M&BE7
    • Place of Presentation
      福岡
    • Year and Date
      2013-03-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] ドーパミンを含む高分子ナノシートの多層集積への応用2013

    • Author(s)
      内山駿, 三ツ石方也, 宮下徳治
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノ構造制御されたフッ素系高分子薄膜による発光型酸素センサーへの応用2013

    • Author(s)
      高宇, 陳涛, 三ツ石方也, 宮下徳治
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 精密集積された高分子ハイブリッドナノ集積体による偏光識別2013

    • Author(s)
      印藤健也, 三ツ石方也, 宮下徳治, 田和圭子, 西井準治
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] シルセスキオキサンを利用したSiO2超薄膜の開発2013

    • Author(s)
      三ツ石方也
    • Organizer
      高分子・ハイブリッド材料研究センター 2013 PHyMシンポジウム
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] 強誘電性高分子材料の超薄膜化2013

    • Author(s)
      三ツ石方也
    • Organizer
      PDTec研究会第8回技術交流会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] シルセスキオキサン含有高分子ナノシートから作製するSiO2超薄膜2013

    • Author(s)
      山本俊介, 園部和輝, 三ツ石方也, 宮下徳治
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] ドーパミンを含む高分子ナノシートによるハイブリッド集積に関する考察2013

    • Author(s)
      内山駿, 山本俊介, 三ツ石方也, 宮下徳治
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] Tunable Ferroelectricity of Highly Oriented PVDF Homopolymer Ultrathin Films from Relaxor-like Ferroelectrics to Ferroelectrics2013

    • Author(s)
      Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面プラズモン共鳴/導波モード励起を利用した発光ナノデバイスによる偏光識別2013

    • Author(s)
      印藤健也, 森田晋平, 山本俊介, 田和圭子, 西井準治, 三ツ石方也, 宮下徳治
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノ構造制御技術を利用した機能性高分子超薄膜の開発2013

    • Author(s)
      三ツ石方也
    • Organizer
      第13回東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子ナノシートを用いたSiO2超薄膜のフレキシブル基板上への作製2013

    • Author(s)
      山本俊介, 園部和輝, 三ツ石方也, 宮下徳治
    • Organizer
      第13回東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ultrathin Polymer Films Organized for Luminescence Oxygen Sensor Application2013

    • Author(s)
      Masaya Mitsuishi
    • Organizer
      ICMR 2013 AKITA
    • Place of Presentation
      Akita
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Hybrid Polymer Nanoassemblies for Photonics Applications2013

    • Author(s)
      Masaya Mitsuishi, Yu Gao, Shunsuke Yamamoto, Tokuji Miyashita
    • Organizer
      KJFP2013
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] A Highly Sensitive and Superhydrophobic Optical Film Sensor for Dissolved Oxygen2013

    • Author(s)
      Yu Gao, Shunsuke Yamamoto, Masaya Mitsuishi, Tokuji Miyashita
    • Organizer
      KJFP2013
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] 機能性高分子超薄膜による発光制御を利用した光機能発現2012

    • Author(s)
      三ツ石 方也
    • Organizer
      平成24年度化学系学協会東北大会
    • Place of Presentation
      秋田大学(招待講演)
    • Year and Date
      2012-09-16
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高分子超薄膜と高効率・高機能2012

    • Author(s)
      三ツ石 方也
    • Organizer
      第40回東北地区若手研究会夏季ゼミナール
    • Place of Presentation
      仙台(招待講演)
    • Year and Date
      2012-07-02
    • Related Report
      2012 Annual Research Report
  • [Book] 第7章第6節ボトムアップ的手法によるハイブリッド高分子ナノ集積体を利用した光変換技術, 『光』の制御技術とその応用事例集2014

    • Author(s)
      三ツ石方也, 宮下徳治
    • Publisher
      (株)技術情報協会
    • Related Report
      2014 Annual Research Report
  • [Remarks] 三ツ石研究室 東北大学

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mitsuishi/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 三ツ石研究室 東北大学

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mitsuishi/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/modules/laboratory/index.php?laboid=90

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 抵抗変化メモリ素子および抵抗変化メモリ素子の製造方法2015

    • Inventor(s)
      山本俊介, 三ツ石方也, 宮下徳治, 北中孝尚
    • Industrial Property Rights Holder
      国立大学東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-035643
    • Filing Date
      2015-02-25
    • Related Report
      2014 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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