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Elucidation and control of nanoionics phenomena at oxide/metal heterointerfaces

Research Project

Project/Area Number 24360278
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

Tsuruoka Tohru  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主幹研究員 (20271992)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywords酸化物 / カチオン伝導 / 酸化還元反応 / ナノイオニクス / 量子化コンダクタンス / シナプス動作 / 抵抗変化メモリ / 原子スイッチ / 吸湿挙動 / アモルファス酸化物 / 金属イオン伝導 / 抵抗変化メモリー / ヘテロ界面
Outline of Final Research Achievements

We have investigated the switching mechanism and functionalities of Cu,Ag/Ta2O5/Pt atomic switch-type resistance change memories based on the transport of metal ions in oxide thin films and electrochemical reactions at metal/oxide interfaces, which are called ‘nanoionics phenomena’. We performed real-space observation of a conducting filament formed in the memory by atomic force and transmission electron microscopies, elucidation of detailed redox reaction at metal/oxide interfaces and moisture absorption effects of oxides by electrochemical methods, and demonstration of conductance quantization and synaptic behavior.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (42 results)

All 2016 2015 2014 2013 2012 Other

All Int'l Joint Research (1 results) Journal Article (20 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 18 results,  Acknowledgement Compliant: 6 results) Presentation (20 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results) Remarks (1 results)

  • [Int'l Joint Research] アーヘン工科大学(ドイツ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Humidity effects on the redox reactions and ionic transport in a Cu/Ta2O5/Pt atomic switch structures2016

    • Author(s)
      T. Tsuruoka, I. Valov, C. Mannequin, T. Hasegawa, R. Waser, M. Aono
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55

    • NAID

      210000146651

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Composition of thin Ta2O5 films deposited by different methods and the effect of humidity on their resistive switching behavior2016

    • Author(s)
      C. Mannequin, T. Tsuruoka, T. Hasegawa, M. Aono
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55

    • NAID

      210000146630

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Identification and role of non-stoichiometric oxygen in amorphous Ta2O5 thin films deposited by electron beam and sputtering processes2016

    • Author(s)
      C. Mannequin, T. Tsuruoka, T. Hasegawa, M. Aono
    • Journal Title

      Applied Surface Science

      Volume: 印刷中

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Redox reactions at Cu,Ag/Ta2O5 interfaces and the effects of Ta2O5 film density on the forming process in atomic switch structures2015

    • Author(s)
      T. Tsuruoka, I. Valov, S. Tappertzhofen, J. van de Hurk, T. Hasegawa, R. Waser, M. Aono
    • Journal Title

      Advanced Functional Materials

      Volume: 25 Issue: 40 Pages: 6347-6381

    • DOI

      10.1002/adfm.201500853

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Ultra-low voltage and ultra-low power consumption nonvolatile operation of a three-terminal atomic switch2015

    • Author(s)
      Q. Wang, Y. Itoh, T. Tsuruoka, M. Aono, T. Hasegawa
    • Journal Title

      Advanced Materials

      Volume: 27 Issue: 39 Pages: 6029-6033

    • DOI

      10.1002/adma.201502678

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Position detection and observation of a conducting filament hidden under a top electrode in a Ta2O5-based atomic switch2015

    • Author(s)
      A. Nayak, Q. WANG, Y. Itoh, T. Tsuruoka, T. Hasegawa, L. Boodhoo, H. Mizuta, M. Aono
    • Journal Title

      Nanotechnology

      Volume: 26 Issue: 14 Pages: 145702-145702

    • DOI

      10.1088/0957-4484/26/14/145702

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic moderation of an electric field using a SiO2 switching layer in TaOx-based ReRAM2015

    • Author(s)
      Q. WANG, Y. Itoh, T. Tsuruoka, Shintaro Otsuka, Tomohiro Shimizu, Shoso Shinguhara, T. Hasegawa, M. Aono
    • Journal Title

      Phys. Status Solidi-Rapid Res. Lett.

      Volume: 9 Issue: 3 Pages: 166-170

    • DOI

      10.1002/pssr.201409531

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanosecond fast switching processes observed in gapless-type, Ta2O5-based atomic switches2015

    • Author(s)
      T. Tsuruoka, T. Hasegawa, and M. Aono
    • Journal Title

      Mater. Res. Symp. Proc.

      Volume: 1729 Pages: 1-6

    • DOI

      10.1557/opl.2015.93

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Two types of on-state observed in the operation of a redox-based three-terminal device2014

    • Author(s)
      Q. WANG, Y. Itoh, T. Tsuruoka, T. Hasegawa, S. Watanabe, S. Yamaguchi, T. Hiramoto, M. Aono
    • Journal Title

      Key Eng. Mater.

      Volume: 596 Pages: 111-115

    • DOI

      10.4028/www.scientific.net/kem.596.111

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synaptic plasticity and memristive behavior operated by atomic switches2014

    • Author(s)
      T. Tsuruoka, T. Hasegawa, and M. Aono
    • Journal Title

      Proceedings of 4th Memristor and Memristive Symposium

      Volume: 2014 Pages: 1455-1455

    • DOI

      10.1109/cnna.2014.6888615

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 酸化物ナノ薄膜を用いた原子スイッチ型抵抗変化メモリーとその応用2014

    • Author(s)
      鶴岡徹,長谷川剛
    • Journal Title

      応用物理学会 シリコンテクノロジー分科会 第173回研究集会 電子情報通信学会技術研究報告

      Volume: 114 Pages: 85-90

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Quantized conductance and neuromorphic behavior of a gapless-type Ag-Ta2O5 atomic switch2013

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K. Terabe, and M. Aono
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1562 Pages: 725-725

    • DOI

      10.1557/opl.2013.725

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generic relevance of counter charges for cation-based nanoscale resistive switching memories2013

    • Author(s)
      S. Tappertzhofen, I. Valov, T. Tsuruoka, T. Hasegawa, R. Waser, and M. Aono
    • Journal Title

      ACS Nano

      Volume: 7 Issue: 7 Pages: 6396-6402

    • DOI

      10.1021/nn4026614

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Volatile and nonvolatile selective switching of a photo-assisted initialized atomic switch2013

    • Author(s)
      日野貴美、長谷川剛、田中啓文、鶴岡徹、寺部一弥、小川琢治、青野正和
    • Journal Title

      NANOTECHNOLOGY

      Volume: 24 Issue: 38 Pages: 384006-384006

    • DOI

      10.1088/0957-4484/24/38/384006

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synaptic plasticity and memory functions achieved in WO3-x-based nanoionics device by using principle of atomic switch operation2013

    • Author(s)
      R. Yang, K. Terabe, Y. Yao, T. Tsuruoka, T. Hasegawa, J. K. Gimzewski, and M. Aono
    • Journal Title

      Nanotechnology

      Volume: 24 Issue: 38 Pages: 384003-384003

    • DOI

      10.1088/0957-4484/24/38/384003

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonvolatile three-terminal operation based on oxygen vacancy drift in a Pt/Ta2O5-x/Pt,Pt structure2013

    • Author(s)
      Q. Wang, Y. Itoh, T. Hasegawa, T. Tsuruoka, S. Watanabe, S. Yamaguchi, and M. Aono
    • Journal Title

      Appl. Phys. Lett.

      Volume: 102 Issue: 23 Pages: 233508-233508

    • DOI

      10.1063/1.4811122

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rate-limiting processes in the fast SET operation of a gapless-type Cu-Ta_2O5 atomic switch2013

    • Author(s)
      T. Tsuruoka, T. Hasegawa, I. Valov, R. Waser, M. Aono
    • Journal Title

      AIP Advances

      Volume: 3 Issue: 3 Pages: 32114-32114

    • DOI

      10.1063/1.4795140

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlling the synaptic plasticity of a Cu_2S atomic switch2012

    • Author(s)
      A. Nayak, T. Ohno, T. Tsuruoka, K. Terabe, M. Aono
    • Journal Title

      Advanced Functional Materials

      Volume: 22 Issue: 17 Pages: 3606-3613

    • DOI

      10.1002/adfm.201200640

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conductance quantization and synaptic behavior of a Ta_2O_5-based atomic switch2012

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K.Terabe, M. Aono
    • Journal Title

      Nanotechnology

      Volume: 23 Issue: 43 Pages: 435705-435705

    • DOI

      10.1088/0957-4484/23/43/435705

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impacts of temperature and moisture on the resistive switching characteristics of a Cu-Ta_2O_5-based atomic switch2012

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K.Terabe, M. Aono
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1430 Pages: 901-901

    • DOI

      10.1557/opl.2012.901

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Cu/Ta2O5界面の酸化還元反応と抵抗スイッチ動作の湿度依存性2016

    • Author(s)
      鶴岡徹, Cedric Mannequin, 長谷川剛, 青野正和
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effects of the composition of Ta2O5 films on the resistive switching properties of Ta2O5 based atomic switches2016

    • Author(s)
      C.R. Mannequin, T. Tsuruoka, T. HASEGAWA, M. Aono
    • Organizer
      MANA International Symposium 2016
    • Place of Presentation
      つくば
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structural property of amorphous thin Ta2O5 films deposited by different methods and its impact on their resistive switching characteristics2015

    • Author(s)
      C.R. Mannequin, T. Tsuruoka, T. Hasegawa, M. Aono
    • Organizer
      MNC 2015
    • Place of Presentation
      富山
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox reactions and metal ion transport in Cu(Ag)/Ta2O5/Pt atomic switch structures2015

    • Author(s)
      T. Tsuruoka, Ilia Valov, T. Hasegawa, R. Waser, M. Aono
    • Organizer
      MNC 2015
    • Place of Presentation
      富山
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Impact of Film Morphology on the Switching Characteristics of Ta2O5-Based Atomic Switches2015

    • Author(s)
      C.R. Mannequin, T. Tsuruoka, T. Hasegawa, M. Aono
    • Organizer
      SSDM 2015
    • Place of Presentation
      北海道
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Operation Mechanism and Novel Functions of gapless-type atomic switches based on metal oxide and polymer thin films2015

    • Author(s)
      T. Tsuruoka, C.R. Mannequin, K. Krishnan, M. Aono
    • Organizer
      Trend in Nanotechnology 2015
    • Place of Presentation
      フランス,トゥールーズ
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 原子スイッチ型抵抗変化メモリ:動作機構解明と機能探索2015

    • Author(s)
      鶴岡徹
    • Organizer
      第99回STRJ-ERD会合
    • Place of Presentation
      東京
    • Year and Date
      2015-06-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Effects of the Oxide Film Density on the Resistive Switching Characteristics of Atomic Switches2015

    • Author(s)
      MANNEQUIN Cedric, 鶴岡徹, 長谷川剛, 青野正和
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nanosecond Fast Switching Processes Observed in Gapless-Type Ta2O5–Based Atomic Switches2014

    • Author(s)
      T. Tsuruoka, T. Hasegawa, M. Aono
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center, Boston
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Cu(Ag)/Ta2O5界面の酸化還元過程とフォーミングに対するTa2O5膜密度の影響2014

    • Author(s)
      鶴岡徹, Ilia Valov, 長谷川剛, Rainer Waser, 青野正和
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synaptic plasticity and memristive behavior operated by atomic switches2014

    • Author(s)
      T. Tsuruoka, T. Hasegawa, and M. Aono
    • Organizer
      4th Memristor and Memristive Symposium
    • Place of Presentation
      University of Notre Dome
    • Year and Date
      2014-07-28 – 2014-07-31
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 酸化物ナノ薄膜を用いた原子スイッチ型抵抗変化メモリーとその応用2014

    • Author(s)
      鶴岡徹,長谷川剛
    • Organizer
      シリコンテクノロジー分科会 第173回研究集会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-06-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synaptic plasticity observed in a gapless-type atomic switch using a thin Ta2O5 film2014

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K. Terabe, M. Aono
    • Organizer
      IUMRS-ICEM 2014
    • Place of Presentation
      Taipei
    • Year and Date
      2014-06-10 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Atomic switch: Resistance change memory based on cation transport and redox reactions in oxide thin layers2014

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K. Terabe, and M. Aono
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Cu-Ta2O5原子スイッチにおけるSET動作の律速過程2014

    • Author(s)
      鶴岡徹,長谷川剛,I. Valov,R. Waser,青野正和
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Quantized conductance and neuromorphic behavior of a gapless-type Ag-Ta2O5 atomic switch2013

    • Author(s)
      Tsuruoka, T. Hasegawa, K. Terabe, and M. Aono
    • Organizer
      2013 MRS Spring Meeting
    • Place of Presentation
      サンフランシスコ
    • Related Report
      2013 Annual Research Report
  • [Presentation] Controlling the synaptic plasticity of gap- and gapless-type atomic switches2013

    • Author(s)
      T. Tsuruoka
    • Organizer
      Discussion Workshop on New Horizons in Electrochemistry
    • Place of Presentation
      カプリ島
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Ag/Ta_2O_5/Pt構造における量子化コンダクタンスとシナプス的な振る舞い2012

    • Author(s)
      鶴岡徹, 長谷川剛, 寺部一弥, 青野正和
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      松山市
    • Year and Date
      2012-09-14
    • Related Report
      2012 Annual Research Report
  • [Presentation] Resistive switching memory based on nanoscale cation transport in oxide films2012

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K.Terabe, M. Aono
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2012
    • Place of Presentation
      ソウル(招待講演)
    • Year and Date
      2012-06-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] Impacts of temperature and moisture on the resistive switching characteristics of a Cu-Ta_2O_5-based atomic switch2012

    • Author(s)
      T. Tsuruoka, T. Hasegawa, K.Terabe, M. Aono
    • Organizer
      2012 MRS Spring Meeting
    • Place of Presentation
      サンフランシスコ
    • Year and Date
      2012-04-11
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/TSURUOKA_Touru-j.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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