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Development of the novel graphene material using by the supercritical fluid technology at lower temperatures

Research Project

Project/Area Number 24360305
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Material processing/treatments
Research InstitutionShizuoka University

Principal Investigator

KONG Chang Yi  静岡大学, 工学研究科, 准教授 (60334637)

Co-Investigator(Kenkyū-buntansha) SAKO Takeshi  静岡大学, 工学部, 教授 (20324329)
IWATA Futoshi  静岡大学, 工学部, 教授 (30262794)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2012: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Keywordsグラフェン / 還元型酸化グラフェン / 熱処理 / 超臨界流体 / 還元処理 / 炭素材料 / ナノ材料 / グラファイト / 酸化グラフェン / ナノ炭素材料
Outline of Final Research Achievements

A green method to synthesize the reduced graphene oxide using sub- and supercritical fluid has been developed, which is an environmentally friendly and a one step reduction process with efficient route. It was found that ethanol has higher reducing capability than other solvents such as CO2, hexane, acetonitrile, benzyl alcohol, methanol, ethanol, butanol and propanol examined in this study for graphene oxide reduction. It was found that substantial conversion of GO could be achieved in sub-critical condition of ethanol with HI at 300 C and 10 atm.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (21 results)

All 2015 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] 黒鉛からの高品質な還元型酸化グラフェンの創製2015

    • Author(s)
      孔 昌一
    • Journal Title

      機能材料

      Volume: 35 Pages: 49-55

    • Related Report
      2014 Annual Research Report
  • [Journal Article] A Green Approach for Highly Reduction of Graphene Oxide by Supercritical Fluid2014

    • Author(s)
      C. Y. Kong, Y. Shiratori, T. Sako and F. Iwata
    • Journal Title

      Adv. Mater. Res.

      Volume: 1004-1005 Pages: 1013-1016

    • DOI

      10.4028/www.scientific.net/amr.1004-1005.1013

    • NAID

      120005550334

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Flexible Graphene-Graphene Composites of Superior Thermal and Electrical Transport Properties2014

    • Author(s)
      Z.-L. Hou, W.-L. Song, P. Wang, M. J. Meziani; C. Y. Kong, A. Anderson, H. Maimaiti, G. E. LeCroy, H. Qian, Y. -P. Sun
    • Journal Title

      ACS Appl. Mater. Interf.

      Volume: 6 Issue: 17 Pages: 15026-15032

    • DOI

      10.1021/am502986j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polymeric Nanocomposites with Graphene Sheets - Materials and Device for Superior Thermal Transport Properties2012

    • Author(s)
      W.-L. Song, L. M. Veca, C. Y. Kong, S. Ghose, J. W. Connell, P. Wang, L. Cao, Y. Lin, M. J. Meziani, H. Qian, G. E. LeCroy, Y.-P. Sun
    • Journal Title

      Polymer

      Volume: 53 Issue: 18 Pages: 3910-3916

    • DOI

      10.1016/j.polymer.2012.07.008

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polymer/Carbon Nanocomposites for Enhanced Thermal Transport Properties - Carbon Nanotubes versus Graphene Sheets a8 Nanoscale Fillers2012

    • Author(s)
      W.-L. Song, W. Wang, L. M. Veca, C. Y. Kong, M.-S. Cao, P. Wang, M. J. Meziani, H. Qian, G. E. LeCroy, L. Cao, Y.-P. Sun
    • Journal Title

      J. Mater. Chem.

      Volume: 22 Issue: 33 Pages: 17133-17139

    • DOI

      10.1039/c2jm32469e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Linear and Nonlinear Optical Properties of Modified Graphene-based Materials2012

    • Author(s)
      L. Cao, S. Sahu, P. Anilkumar, C. Y. Kong, Y. -P. Sun
    • Journal Title

      MRS Bulletin

      Volume: 37 Issue: 12 Pages: 1283-1289

    • DOI

      10.1557/mrs.2012.178

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hexagonal Boron Nitride Nanomaterials : Advances towards Bioapplications2012

    • Author(s)
      F. Lu, F. Wang, L. Cao, C. Y. Kong, X. Huang
    • Journal Title

      Nanosci. Nanotechnol. Lett.

      Volume: 4 Issue: 10 Pages: 949-961

    • DOI

      10.1166/nnl.2012.1444

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supercritical Fluid Conversion of Graphene Oxides2012

    • Author(s)
      C. Y. Kong, W.-L. Song, M. J. Meziani, K. N. Tackett II, L. Cao, A. J. Farr, A. Anderson, Y.-P. Sun
    • Journal Title

      J. Supercrit. Fluids

      Volume: 61 Pages: 206-211

    • DOI

      10.1016/j.supflu.2011.09.008

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高温エタノールによる還元型酸化グラフェンの合成2015

    • Author(s)
      白鳥 祐基, 孔 昌一, 岩田 太, 佐古 猛
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京都江東区豊洲3-7-5)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] ヨウ化銅を用いるペロブスカイト太陽電池における高効率化2015

    • Author(s)
      松野剛光, 桝谷 智矢, 孔 昌一, 昆野昭則
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(横浜市保土ケ谷区常盤台79-1)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機無機ハイブリット太陽電池におけるヨウ化銅層の導入と応用2014

    • Author(s)
      松野剛光, 孔 昌一, 昆野昭則
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道大学高等教育推進機構(札幌市北区北17条西8丁目)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高温高圧エタノールを用いた酸化グラフェンの還元2014

    • Author(s)
      白鳥 祐基, 孔 昌一, 岩田 太, 佐古 猛
    • Organizer
      化学工学会第46回秋季会
    • Place of Presentation
      九州大学 伊都キャンパス, 会場所在地:福岡市西区元岡74
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 還元型酸化グラフェン作製法の開発2014

    • Author(s)
      孔 昌一, 岩田 太, 佐古 猛
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] An Environmentally Friendly Approach to Produce Highly Reduced Graphene Oxides2013

    • Author(s)
      C. Y. Kong, T. Sako and F. Iwata
    • Organizer
      the 5th International Conference on Recent Progress in Graphene Research (EPGR 2013)
    • Place of Presentation
      Tokyo(東京工業大学)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 還元型酸化グラフェンの創製とその性能評価2013

    • Author(s)
      森貴哉, 岩田太, 佐古猛, 孔昌一
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      浜松・静岡大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高温高圧流体によるグラフェンの作製2012

    • Author(s)
      孔昌一, 平野亘, 佐古猛, 岩田太
    • Organizer
      化学工学会横浜大会2012
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高温高圧流体による酸化グラフェンの還元2012

    • Author(s)
      孔昌一, 坂田翔平, 佐古猛, 岩田太
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学(大阪府大阪市)
    • Related Report
      2012 Annual Research Report
  • [Remarks] 静岡大学教員データベース

    • URL

      https://tdb.shizuoka.ac.jp/RDB/public/Default2.aspx?id=10358&l=0

    • Related Report
      2014 Annual Research Report
  • [Remarks] 静岡大学教員データベース

    • URL

      https://tdb.shizuoka.ac.jp/RDB/public/Default2.aspx?id=10358&l=0

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://cheme.eng.shizuoka.ac.jp/~koulab/kong/publication/publication.html

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] グラフェン膜の製造方法、並びにグラフェン膜及びこれを用いた積層体2014

    • Inventor(s)
      孔昌一
    • Industrial Property Rights Holder
      孔昌一
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-186752
    • Filing Date
      2014-08-12
    • Related Report
      2014 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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