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Electrodeposition of bright and purified aluminum coatings from organic solvent baths with additives

Research Project

Project/Area Number 24360308
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Material processing/treatments
Research InstitutionKyoto University

Principal Investigator

HIRATO Tetsuji  京都大学, エネルギー科学研究科, 教授 (70208833)

Co-Investigator(Kenkyū-buntansha) DOI Tosyiya  京都大学, エネルギー科学研究科, 教授 (30315395)
MIYAKE Masao  京都大学, エネルギー科学研究科, 准教授 (60361648)
IKENOUE Takumi  京都大学, エネルギー科学研究科, 助教 (00633538)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywordsめっき / 添加剤 / 金属薄膜 / 電気化学プロセス / 表面・界面制御 / 電気化学
Outline of Final Research Achievements

In this project, we examined the effects of trace ingredients in dimethylsulfone baths on the electrodeposition of Al, and developed additives working as brighteners and purifiers. Main results are as follows: 1) bright Al films could be electrodeposited from the baths with the addition of triethylenetetramine; 2) the influence of water in the baths on the electrodeposition of Al and a method for the removal of the water were elucidated; 3) the effects of the simultaneous addition of triethylenetetramine and dimethylamine hydrochloride were elucidated; 4) a novel organic solvent bath for the electrodeposition of Al was developed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (13 results)

All 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Invited: 2 results)

  • [Journal Article] Hull cell tests for evaluating the effects of polyethylene amines as brighteners in the electrodeposition of aluminum from dimethylsulfone-AlCl3 baths2014

    • Author(s)
      Masao Miyake, Yuki Kubo and Tetsuji Hirato
    • Journal Title

      Electrochimica Acta

      Volume: 120 Pages: 423-428

    • DOI

      10.1016/j.electacta.2013.12.046

    • NAID

      120005373077

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] ジメチルスルホン浴からのアルミニウム電析に及ぼす水分濃度の影響2014

    • Author(s)
      .岡本弘晃、三宅正男、平藤哲司
    • Journal Title

      Journal of MMIJ

      Volume: 130 Pages: 70-75

    • NAID

      130004949474

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ジメチルスルホン浴を用いるアルミニウム複合めっき2014

    • Author(s)
      平藤哲司
    • Journal Title

      表面技術

      Volume: 65 Pages: 73-76

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 非水溶媒を用いるアルミニウム電気めっき その2 -光沢材の評価と新しい電せきよう有機溶媒について-2014

    • Author(s)
      平藤哲司,三宅正男
    • Journal Title

      めっき技術

      Volume: 27 Pages: 9-14

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Electrodeposition of Bright Al Coatings from Dimethylsulfone-AlCl3 Baths with the Addition of Tetraethylenepentamine2013

    • Author(s)
      Masao MIYAKE, Yuki KUBO and Tetsuji HIRATO
    • Journal Title

      Journal of the Surface Finishing Society of Japan

      Volume: 64 Pages: 364-367

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition of bright Al coatings from dimethylsulfone-AlC13 baths with the addition of tetraethyleneDentamine2013

    • Author(s)
      Masao Miyake, Yuki Kubo, and Tetsuji Hirato
    • Journal Title

      Journal of the Surface Finishing Society of Japan

      Volume: 64(表面技術)(印刷中)

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] ジメチルスルホン浴からのアルミニウム電析に及ぼす酸素の影響2014

    • Author(s)
      岡本弘晃, 三宅正男, 平藤哲司
    • Organizer
      日本金属学会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジメチルスルホン浴を用いた TiO2 分散 Al めっき皮膜の作製及びその光触媒能評価2014

    • Author(s)
      高橋歩, 三宅正男, 平藤哲司
    • Organizer
      表面技術協会
    • Place of Presentation
      京都大学
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジメチルスルホン浴からの光沢アルミニウム電析のハルセル試験2012

    • Author(s)
      久保雄輝, 三宅正男, 平藤哲司
    • Organizer
      表面技術協会第126回講演大会
    • Place of Presentation
      室蘭工業大学
    • Year and Date
      2012-09-27
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジメチルスルホン浴を用いたマグネシウム合金上へのアルミニウム電析

    • Author(s)
      藤井久史, 三宅正男, 平藤哲司
    • Organizer
      表面技術協会 第 128 回講演大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルスルホン浴からのアルミニウム電析に及ぼす水分濃度の影響

    • Author(s)
      岡本弘晃, 三宅正男, 平藤哲司
    • Organizer
      資源・素材 2013 (札幌)
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 非水溶媒を用いたアルミニウム複合めっき

    • Author(s)
      平藤哲司
    • Organizer
      表面技術協会 将来めっき技術検討部会第13回例会
    • Place of Presentation
      (独)産業技術総合研究所 臨海副都心センター
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 非水溶媒を用いるアルミニウム電気めっき その2 -光沢材の評価と新しい電せきよう有機溶媒について-

    • Author(s)
      平藤哲司,三宅正男
    • Organizer
      電気鍍金研究会
    • Place of Presentation
      大阪鍍金会館
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2012-04-24   Modified: 2019-07-29  

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