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Development of Ni-B, Ni-C, Co-B and Co-C nanoparticles as electrode catalyst for fuel cell

Research Project

Project/Area Number 24360330
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

MURAMATSU Atsushi  東北大学, 多元物質科学研究所, 教授 (40210059)

Co-Investigator(Kenkyū-buntansha) KANIE Kiyoshi  東北大学, 多元物質科学研究所, 准教授 (60302767)
NAKAYA Masfumi  東北大学, 多元物質科学研究所, 助教 (80451681)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2014: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywords資源・エネルギー有効利用技術 / 燃料電池 / 白金代替
Outline of Final Research Achievements

Fuel cell system needs a lot of amount of platinum to prepare electrode its catalyst. However, platinum is very expensive and it is dwindling natural resources. Therefore, the development of the electrode catalyst without including platinum is strongly required. Here, we have developed the electrode catalyst by preparation of carbide or boride of Co or Ni nanoparticles, which are expected to show catalytic activity as electrode of fuel cell. By using liquid phase synthesis method, we succeeded in preparation of Ni-B, Ni-C, Co-B, and Co-C nanoparticles. They showed electrode catalytic activity on oxygen reduction reaction. Especially, carbide nanoparticles showed higher activity.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(42 results)

All 2014 2013 2012

All Journal Article (7 results) (of which Peer Reviewed: 4 results) Presentation (34 results) (of which Invited: 3 results) Book (1 results)

  • [Journal Article] High Performance ITO Nanoparticles as Nanoink for Printing as a Substitute Process of Sputtering2014

    • Author(s)
      Atsushi Muramatsu, Kiyoshi Kanie, Takafumi Sasaki, Masafumi Nakaya
    • Journal Title

      MRS Proceedings

      Volume: 14

    • DOI

      10.1557/opl.2014.693

    • Related Report
      2014 Annual Research Report
  • [Journal Article] PtCu Intermetallic Compound Supported on Alumina Active for Preferential Oxidation of CO in Hydrogen2013

    • Author(s)
      Komatsu Takayuki, Michiko Takasaki, Kenichi Ozawa, Shinya Furukawa, Atsushi Muramatsu
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY C

      Volume: 117 Pages: 10483-10491

    • DOI

      10.1021/jp4007729

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvothermal Synthesis of Shape-Controlled Perovskite MTiO3 (M = Ba, Sr, and Ca) Particles in H2O/polyols Mixed Solutions2013

    • Author(s)
      Takeshi Kimijima, Kiyoshi Kanie, Masafumi Nakaya, Atsushi Muramatsu
    • Journal Title

      Materials Transactions

      Volume: 55 Pages: 147-153

    • NAID

      130004825126

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ITOナノインク向け高結晶性単分散ITOナノ粒子のソルボサーマル合成と今後の展望2013

    • Author(s)
      蟹江澄志,佐々木隆史,中谷昌史,村松淳司
    • Journal Title

      ディスプレイ

      Volume: 19 Pages: 68-72

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Simple Cubic Packing of Gold Nanoparticles through Rational Design of Their Dendrimeric Corona2012

    • Author(s)
      Kiyoshi Kanie, Masaki Matsubara, XiangbingZeng, Feng Liu, Goran Ungar, Hiroshi Nakamura,Atsushi Muramatsu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134 Pages: 808-811

    • DOI

      10.1021/ja2095816

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Thiol-Capped Gold Nanoparticle with a Flow System Using Organosilane as a Reducing Agent2012

    • Author(s)
      Atsushi Sugie
    • Journal Title

      Tetrahedron Letters

      Volume: 53 Pages: 4457-4459

    • DOI

      10.1016/j.tetlet.2012.06.056

    • NAID

      120006220753

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] サーモトロピック液晶性部位を有する人工リン脂質:リオトロピック液晶性とその外場応答性評価2012

    • Author(s)
      蟹江澄志, 関口準二, Xiangbing Zeng, Goran Ungar,村松淳司
    • Journal Title

      液晶

      Volume: 16 Pages: 272-278

    • NAID

      10031120534

    • Related Report
      2012 Annual Research Report
  • [Presentation] The preparation of FeZSM-5 nanoparticles with compositional control and their catalytic activities2014

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      The 44th Petrol.-Petrochem. Symp. of JPI
    • Place of Presentation
      Asahikawa
    • Year and Date
      2014-10-16 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of (Fe, Al)-MFI zeolite nanoparticles for DTO reaction2014

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      6th international FEZA conference
    • Place of Presentation
      Germany, Leipzig
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of MFI zeolite nanoparticle and its application for light olefin synthesis2014

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      ADMD2014
    • Place of Presentation
      Sendai
    • Year and Date
      2014-07-23 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of Nickel compounds nanoparticles and their oxygen reduction reaction2014

    • Author(s)
      Changgyu An, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      TOCAT7
    • Place of Presentation
      Kyoto
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of iron-substituted MFI zeolites with tunable sizes and their catalytic activities2014

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      TOCAT7
    • Place of Presentation
      Kyoto
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of Nickel Borides and Carbides Supported on Carbon And their Electrocatalytic Activity for PEFC2013

    • Author(s)
      Changgyu An, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      10th Pacific Rim Conference on Ceramic and Glass Technology
    • Place of Presentation
      San Diego,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Nickel compounds nanoparticles And Oxygen reduction reaction2013

    • Author(s)
      Changgyu An, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] Liquid-Phase Reductive Deposition Selectively onto a Carrier as a Novel Nano-Particulate Heterogeneous Catalyst Preparation2013

    • Author(s)
      Atsushi Muramatsu, Masafumi Nakaya, Kiyoshi Kanie
    • Organizer
      The 6th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ニッケルカーバイド•ボライド粒子の合成とその酸素還元性2013

    • Author(s)
      Changgyu An, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2013 Annual Research Report
  • [Presentation] Regeneration and Promotion of Catalytic Activity of Zeolites for DME Conversion to Olefin2013

    • Author(s)
      Atsushi Muramatsu, Masafumi Nakaya, K. Omata, M. Yamada, Hiroki Kobayashi, Yuichiro Yamazaki
    • Organizer
      23rd Annual Saudi-Japan Symposium - 2013 Catalysts in Petroleum Refining & Petrochemicals
    • Place of Presentation
      Dhahran, Saudi Arabia
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Mechanism of Catalyst-life Lost and Activity Regeneration of ZSM-5 Catalysts in DTO Reaction2013

    • Author(s)
      Atsushi Muramatsu, Masafumi Nakaya, Yuichiro Yamazaki
    • Organizer
      2013 KSIEC(Korean Society of Industrial and Engineering Chemistry)
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Regeneration for Promotion to Catalytic Activity of H-ZSM-5 for DME Conversion to Olefin2013

    • Author(s)
      Atsushi Muramatsu, Masafumi Nakaya, K. Omata, M. Yamada, Hiroki Kobayashi, Yuichiro Yamazaki
    • Organizer
      XIth European Congress on Catalysis
    • Place of Presentation
      Lyon, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Mon-S5-01 Liquid-Phase Reductive Deposition Selectively onto a Carrier as a Novel Nano-Particulate Heterogeneous Catalyst Preparation2013

    • Author(s)
      Atsushi Muramatsu, Masafumi Nakaya, Kiyoshi Kanie
    • Organizer
      APCAT2013 (The 6th Asia-Pacific Congress on Catalysis)
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化鉄ナノ粒子の結晶構造制御とその磁気特性2013

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 鉄含有MFI型ゼオライトの合成及びその触媒活性評価2012

    • Author(s)
      小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
    • Organizer
      東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      仙台
    • Year and Date
      2012-12-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nanosized MFI-type Ferrisilicate catalysts for light olefin synthesis from dimethyl ether2012

    • Author(s)
      Hiroki Kobayashi, Yuichiro Yamazaki, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      International Symposium on Zeolite and Microporous Crystals
    • Place of Presentation
      Hiroshima
    • Year and Date
      2012-07-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] Gel-Sol Method Combinating with Solvothermal Synthesis for Uniform Highly Functional Nanoparticles of ITO and Lead-free Piezo Ceramics2012

    • Author(s)
      Atsushi Muramatsu
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials(ICEAN)
    • Place of Presentation
      Brisbane, Australia((招待講演))
    • Related Report
      2012 Annual Research Report
  • [Presentation] サイズ・形態制御されたチタン系酸化物ナノ粒子の液相合成とその光触媒能2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      セラミックス協会 第25回秋季シンポジウム
    • Place of Presentation
      名古屋(招待講演)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Rh-Te合金ナノ粒子の合成と構造解析2012

    • Author(s)
      柳橋宣利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 液相還元法によるRh-Te合金ナノ粒子の調製2012

    • Author(s)
      柳橋宣利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 形態制御BaZrO3 微粒子の水熱合成とEuドープによる蛍光特性評価鉄ナ2012

    • Author(s)
      制野友樹, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 鉄ナノ粒子の表面構造制御とその磁気特性2012

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Rh-Te合金ナノ粒子触媒の調製と共役ジエンのアセトキシ化反応2012

    • Author(s)
      柳橋宜利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金属カチオンドーバントがチタン酸カルシウム微粒子の光触媒活性に与える影響2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金属カチオンドーピングによるチタン酸カルシウム微粒子の欠陥構造制御と光触媒活性に与える影響2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 選択的オレフィン合成のためのMFI型フェリシリケート触媒の開発2012

    • Author(s)
      小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] チタン系酸化物の形態・結晶露出面が光触媒活性に与える効果2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第31回固体・表面光化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and Photocatalytic Activity of Ti-based Oxides with Various Sizes and Shapes2012

    • Author(s)
      Kimijima Takeshi, Nakaya Masafumi, Kanie Kiyoshi, Muramatsu Atsushi
    • Organizer
      ICC2012
    • Place of Presentation
      Germany, Munich
    • Related Report
      2012 Annual Research Report
  • [Presentation] Introduction of Liquid-Crystallinity into CdS Nanoparticles by Surface Dendron-Modification and their Luminescence Property2012

    • Author(s)
      Jun Yabuki, Kiyoshi Kanie, Maski Matsubara, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      24th International Liquid Crystal Conference
    • Place of Presentation
      Germany, Mainz
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nanosized MFl-type Ferrisilicate catalysts for light olefin synthesis2012

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      The 4th China-Japan Symposium on Ferroelectric Materials Miyagi and their Applications
    • Place of Presentation
      Miyagi
    • Related Report
      2012 Annual Research Report
  • [Presentation] Hydrothemally Prepared Sodium Potassium Niobate Fine Particles Using Niobium Pentachloride and their Piezoelectric Properties2012

    • Author(s)
      Kiyoshi Kanie, Hideto Mizutani, Atsuki Terabe, Yoshiki Numamoto, Shintaro Tsukamoto, Hirofumi Takahashi, Masafumi Nakaya, Junji Tani, Atsushi Muramatsu
    • Organizer
      The 4th China-Japan Symposium on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Miyagi
    • Related Report
      2012 Annual Research Report
  • [Presentation] Hydrothermal Synthesis of Shape-Controlled BaZrO3 Fine Particles and Photoluminescence Property by Eu-Dopin2012

    • Author(s)
      Yuki Seino, Kiyoshi Kanie, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Annual Research Report
  • [Presentation] Size control of MFI-type Ferrisilicate and its catalytic activity2012

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation of passivated Fe nanoparticle and its stability2012

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Annual Research Report
  • [Book] 透明導電膜 有力材料の実力と各種プロセス技術, 実用・製品化, 高結晶性ITOナノ粒子の液相合成と低抵抗ITOナノインク開発への取り組み2012

    • Author(s)
      蟹江澄志, 中谷昌史, 村松淳司
    • Publisher
      情報機構
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-23   Modified: 2019-07-29  

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