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Application of Mechanochemical Reaction to the Synthesis of Novel Microporous Materials

Research Project

Project/Area Number 24360335
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionThe University of Kitakyushu

Principal Investigator

YAMAMOTO Katsutoshi  北九州市立大学, 国際環境工学部, 准教授 (60343042)

Research Collaborator IKEDA Takuji  産業技術総合研究所, 化学プロセス研究部門, 主任研究員 (60371019)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2012: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Keywords多孔質材料 / 新規構造 / ヘテロ配位 / ヘテロ金属 / アルカリ土類金属 / メカノケミカル / 吸着 / メカノケミカル反応 / ゼオライト / 触媒 / バリウム / SAPO-34 / MTO反応 / ナノ材料 / 自己組織化 / 触媒・化学プロセス
Outline of Final Research Achievements

A novel synthesis method for crystalline silicate materials was developed by applying mechanochemical reaction. By using this novel method to introduce alkaline earth metal species such as Ca and Sr into silicate framework, various unknown silicate materials were successfully synthesized. Some of their crystal structure were determined by X-ray structural analysis and proved to have unique micropore structures, which led to the selective adsorption of water or carbon dioxide molecules. This novel synthesis method can be applied to the synthesis of conventional zeolite materials. This method facilitated the synthesis of metallosilicate zeolites that were hardly synthesized by a conventional method and enabled the synthesis of a silicoaluminophosphate zeolite under a wide variety of conditions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (11 results)

All 2014 2013 2012

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (8 results) (of which Invited: 1 results)

  • [Journal Article] Synthesis and crystal structure analysis of a novel strontosilicate AES-19 having two dimensional eight-membered ring micropores2013

    • Author(s)
      Katsutoshi Yamamoto, Takuji Ikeda, Chiaki Ideta
    • Journal Title

      Micropor. Mesopor. Mater.

      Volume: 172 Pages: 13-19

    • DOI

      10.1016/j.micromeso.2013.01.004

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal structure of new strontium-containing layered silicate AES-18 obtained by mechanochemical reaction2013

    • Author(s)
      T. Ikeda, C. Ideta, K and Yamamoto
    • Journal Title

      Z. Kristallogra.

      Volume: 228 Issue: 4 Pages: 96809688-96809688

    • DOI

      10.1524/zkri.2013.1591

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ヘテロ配位種の導入による新規シリケート物質の創製2013

    • Author(s)
      山本勝俊,池田卓史
    • Journal Title

      ゼオライト

      Volume: 30 Pages: 1-8

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] SAPO-34の結晶子サイズ制御とオレフィン合成における触媒活性2014

    • Author(s)
      天野信也、山本勝俊
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川
    • Year and Date
      2014-10-16 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] SAPO-34結晶子サイズの微細化2014

    • Author(s)
      天野信也、山本勝俊
    • Organizer
      第29回石油学会九州・沖縄地区講演会
    • Place of Presentation
      北九州
    • Year and Date
      2014-09-01 – 2014-09-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] メカノケミカル法によるSAPO物質の合成2013

    • Author(s)
      天野信也・山本勝俊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州市・北九州国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヘテロ配位金属種を骨格に持つ多孔性物質の合成2013

    • Author(s)
      山本勝俊
    • Organizer
      第21回ゼオライト夏の学校
    • Place of Presentation
      京都市・関西セミナーハウス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ヘテロ配位種の導入による新規シリケート物質の創製2012

    • Author(s)
      山本勝俊
    • Organizer
      第28回ゼオライト研究発表会
    • Place of Presentation
      東京都江戸川区・タワーホール船堀
    • Year and Date
      2012-11-30
    • Related Report
      2012 Annual Research Report
  • [Presentation] ヘテロ元素の骨格導入による多孔質シリケート材料の合成2012

    • Author(s)
      山本勝俊
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田市・秋田キャッスルホテル
    • Year and Date
      2012-10-11
    • Related Report
      2012 Annual Research Report
  • [Presentation] 様々なSAPO物質の合成と物性評価2012

    • Author(s)
      山本勝俊
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田市・秋田キャッスルホテル
    • Year and Date
      2012-10-11
    • Related Report
      2012 Annual Research Report
  • [Presentation] Hetero-coordinated atom-containing zeotypes synthesized via mechanochemical route2012

    • Author(s)
      山本勝俊
    • Organizer
      ZMPC2012
    • Place of Presentation
      広島市・アステールプラザ
    • Year and Date
      2012-08-01
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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