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Thermodynamic study on solubility of actinide hydrous oxides and stability of the colloids

Research Project

Project/Area Number 24360393
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Nuclear engineering
Research InstitutionKyoto University

Principal Investigator

Sasaki Takayuki  京都大学, 工学(系)研究科(研究院), 教授 (60314291)

Co-Investigator(Kenkyū-buntansha) MORIYAMA Hirotake  京都大学, 原子炉実験所, 教授 (90127150)
KOBAYASHI Taishi  京都大学, 工学研究科, 助教 (80630269)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2012: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywords放射性廃棄物処分 / 4価アクチニド / コロイド / 錯生成 / 溶解度 / 熱力学モデル / 放射性廃棄物 / 有機物 / アクチニド / ゼータ電位
Outline of Final Research Achievements

Understanding of thermodynamic stability of actinide ions and its compounds including colloids is indispensable for safety assessment for the disposal of high level radioactive waste. In this project, basic studies in actinide aqueous solution chemistry have been performed to obtain the knowledge of formation constants, solubility products, and the chemical conditions of soluble species and precipitation. Through the systematic experimental study of the binary (An-OH) and the ternary (An-OH-inorganic ions, -humic substances) systems at a given solution condition, the apparent solubility data and the long term stability of species and solid phases were analyzed by the proposed thermodynamic models. The results are expected to contribute a reliability improvement of radioactive waste management in Japan and other countries.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (9 results)

All 2016 2015 2014 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (7 results)

  • [Journal Article] The Solubilities and Solubility Products of Zirconium Hydroxide and Oxide after Aging at 278, 313, and 333 K2016

    • Author(s)
      T. Kobayashi, T. Uemura, T. Sasaki, I. Takagi, H. Moriyama
    • Journal Title

      Radiochim. Acta

      Volume: 104 Issue: 3 Pages: 183-193

    • DOI

      10.1515/ract-2015-2461

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Discrete fragment model for apparent formation constants of actinide ions with humic substances2015

    • Author(s)
      T. Sasaki, H. Yoshida, S. Aoyama, T. Kobayashi, I. Takagi, H. Moriyama
    • Journal Title

      Radiochim. Acta

      Volume: 5 Issue: 6 Pages: 411-421

    • DOI

      10.1515/ract-2014-2296

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Th水酸化物溶解度および固相状態に及ぼす温度影響の解釈2016

    • Author(s)
      西川将吾、小林大志、佐々木隆之
    • Organizer
      日本原子力学会2016年春の年会
    • Place of Presentation
      東北大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 加熱温度下における4価Zr溶解度測定と解釈2015

    • Author(s)
      水越寛文,小林大志,佐々木隆之
    • Organizer
      日本原子力学会2015年春の年会
    • Place of Presentation
      茨城大学 日立キャンパス
    • Year and Date
      2015-03-20 – 2015-03-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] 加熱温度下における4価Zr溶解度測定と解釈2014

    • Author(s)
      小林大志, 上村拓也, 佐々木隆之
    • Organizer
      日本原子力学会春の学会
    • Place of Presentation
      東京都市大学(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 4価ジルコニウム水酸化物の固相状態と溶解度に及ぼす加熱の影響2013

    • Author(s)
      上村拓也, 小林大志, 佐々木隆之
    • Organizer
      日本原了-力学会2013年春の年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2013-03-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] フミン酸共存下におけるトリウムの溶解度 その22013

    • Author(s)
      松浦由佳, 小林大志, 佐々木隆之
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      八戸工業大学(青森県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Discrete fragment model for apparent formation constants of metal complexes with Humic Substances2013

    • Author(s)
      T. Sasaki, H. Yoshida, S. Aoyama, T. Kobayashi, I. Takagi, H. Moriyama
    • Organizer
      Migration2013
    • Place of Presentation
      ブライトンセンター(英国,ブライトン)
    • Related Report
      2013 Annual Research Report
  • [Presentation] フミン酸共存下におけるトリウムの溶解度2012

    • Author(s)
      松浦由佳, 小林大志, 佐々木隆之
    • Organizer
      日本原了・力学会2012年秋の大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2012-09-20
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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