| Project/Area Number |
24380092
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Wood science
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TAKANO Toshiyuki 京都大学, 大学院農学研究科, 教授 (50335303)
YOSHINAGA Arata 京都大学, 大学院農学研究科, 准教授 (60273489)
TANAKA Yoshimasa 長崎大学, 大学院医歯(薬)学総合研究科, 准教授 (90280700)
TOBIMATSU Yuki 京都大学, 大学院農学研究科, 助教 (20734221)
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| Co-Investigator(Renkei-kenkyūsha) |
SAOTOME Chikako 京都大学, 大学院医学研究科, 准教授 (00447963)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
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| Keywords | バイオマス / メチルセルロース / セルロース / ブロックコポリマー / 超分子 |
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| Outline of Final Research Achievements |
We synthesized biomass hybrid materials in a molecular level. Cellulose triacetate-b-poly(g-benzyl-L-glutamate) was synthesized, and, for the first time, exhibited microphase separation as cellulosic materials. Diblock methylcellulose derivatives having ionic oligo(amino acid)s and oligomers of hemicelluloses were also synthesized. As a result, we found sufficient conditions for methylcellulose-based supramolecular hydrogels: a sequence of, at least, 10 tri-O-methyl-glucosyl residues for hydrophobic blocks, and functional groups for hydrogen bonds for hydrophilic blocks. Moreover, thermoresponsive supramolecular hydrogels comprising end-functionalized methylcelluloses showed properties of slow drug release.
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