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Application of new microscope unit with an ionic liquid and immersion objective to various optical spectroscopic techniques

Research Project

Project/Area Number 24510163
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute of Information and Communications Technology

Principal Investigator

YAMADA Toshiki  独立行政法人情報通信研究機構, 未来ICT研究所ナノICT研究室, 主任研究員 (10359101)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords光学顕微鏡 / イオン性液体 / 単一分子分光 / 高真空 / 表面プラズモン / ラマン散乱
Outline of Final Research Achievements

A new microscope unit having an immersion objective with high numerical aperture and a non-volatile ionic liquid as a refractive index matching medium was applied to various optical spectroscopic techniques in high vacuum. We performed orientation imaging of single molecules by defocusing under conventional wide-field illumination and successfully obtained orientation images related to transition dipoles of single molecules in high vacuum and pure nitrogen gas. We also fabricated surface plasmon and Raman measurement systems with the new microscope unit. Furthermore we performed terahertz spectroscopy for ionic liquids in understanding their unique nature.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report

Research Products

(16 results)

All 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (10 results) (of which Invited: 1 results)

  • [Journal Article] Vibration Modes at Terahertz and Infrared Frequencies of Ionic Liquids Consisting of an Imidazolium Cation and a Halogen Anion2014

    • Author(s)
      Toshiki Yamada, Yukihiro Tominari, Shukichi Tanaka, Maya Mizuno, and Kaori Fukunaga
    • Journal Title

      Materials

      Volume: 7 Pages: 7409-7422

    • DOI

      10.3390/ma7117409

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of new microscope unit for single molecule spectroscopy under various ambient conditions2013

    • Author(s)
      Toshiki Yamada, Takahiro Kaji, Reiko Ueda
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 417

    • DOI

      10.1088/1742-6596/417/1/012056

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Organic-Inorganic Hybrid Devices (Single-Molecule Technology)2013

    • Author(s)
      Takahiro Kaji, Toshifumi Terui, Toshiki Yamada, Reiko Ueda, Shin-ichiro Inoue, Akira Otomo
    • Journal Title

      Journal of the National Institute of Communications Technology

      Volume: 60 Pages: 29-41

    • NAID

      130008037089

    • Related Report
      2013 Research-status Report
  • [Journal Article] 有機・無機ハイブリッドデバイス(単一分子技術)2013

    • Author(s)
      梶貴博、照井通文、山田俊樹、上田里永子、井上振一郎、大友明
    • Journal Title

      情報通信研究機構研究報告

      Volume: 59 Pages: 23-33

    • NAID

      130007759399

    • Related Report
      2013 Research-status Report
  • [Journal Article] Orientation Imaging of Single Molecule at Various Ambient Conditions2013

    • Author(s)
      Toshiki Yamada, Takahiro Kaji, Akira Otomo
    • Journal Title

      IEICE Trans. Electron.

      Volume: E96-C Pages: 381-382

    • NAID

      10031167369

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlled Spontaneous Emission of Single Molecules in a Two-Dimensional Photonic Band Gap2013

    • Author(s)
      Takahiro Kaji
    • Journal Title

      Journal of The American Chemical Society

      Volume: 135 Pages: 106-109

    • DOI

      10.1021/ja3115357

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] ナノフォトニック構造と有機・天然材料を用いた光デバイス開発2014

    • Author(s)
      梶 貴博、山田 俊樹、笠井 克幸、井上 振一郎、照井 通文、田中 秀吉、大友 明
    • Organizer
      2014年電子情報通信学会ソサイエティ大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Year and Date
      2014-09-23 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single molecule spectroscopy for quantum dots and organic molecules under various ambient conditions2013

    • Author(s)
      Toshiki Yamada, Takahiro Kaji, Rieko Ueda, Akira Otomo
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2013
    • Place of Presentation
      Ramada Hotel, Jeju island, South Korea
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Photonic-crystal-based platform to control spontaneous emission from single molecules2013

    • Author(s)
      Takahiro Kaji, Toshiki Yamada, Shoji Ito, Hiroshi Miyasaka, Rieko Ueda, Shin-ichiro Inoue, Akira Otomo
    • Organizer
      The 10th Conference on Lasers and Electro-Optics Pacific Rim, and The 18th OptoElectronics and Communications Conference/Photonics in Switching 2013 (CLEO-PR & OECC/PS 2013)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Related Report
      2013 Research-status Report
  • [Presentation] Photonic-crystal-based platform controlling spontaneous emission from single molecules2013

    • Author(s)
      Takahiro Kaji, Toshiki Yamada, Shoji Ito, Hiroshi Miyasaka, Rieko Ueda, Shin-ichiro Inoue, Akira Otomo
    • Organizer
      26th International Conference on Photochemistry (ICP 2013)
    • Place of Presentation
      KU Leuven, Leuven, Belgium
    • Related Report
      2013 Research-status Report
  • [Presentation] Control of spontaneous emission from single molecules in a photonic band gap of a two-dimensional photonic crystal slab2013

    • Author(s)
      Takahiro Kaji, Toshiki Yamada, Shoji Ito, Hiroshi Miyasaka, Reiko Ueda, Shin-ichiro Inoue, Akira Otomo
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
    • Place of Presentation
      福岡国際会議場、福岡県
    • Related Report
      2012 Research-status Report
  • [Presentation] 単一分子の発光制御を実現する2次元フォトニック結晶プラットフォームの開発2013

    • Author(s)
      梶貴博, 山田俊樹, 伊都将司, 宮坂博, 上田里永子, 井上振一郎, 大友明
    • Organizer
      2013年第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学、神奈川県
    • Related Report
      2012 Research-status Report
  • [Presentation] 2次元フォトニックバンドギャップ中の単一分子蛍光挙動の統計的解析2013

    • Author(s)
      梶貴博, 山田俊樹,上田里永子, 井上振一郎, 大友明
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス、滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] Single molecule spectroscopy under various ambient conditions2012

    • Author(s)
      Toshiki Yamada, Takahiro Kaji, Akira Otomo
    • Organizer
      The 7th International Symposium on Organic Molecular Electronics (ISOME2012)
    • Place of Presentation
      NTT Musashino R&D Center, Tokyo
    • Related Report
      2012 Research-status Report
  • [Presentation] Photonic crystals for enhancing fluorescence from single molecules2012

    • Author(s)
      Takahiro Kaji, Toshiki Yamada, Shoji Ito, Hiroshi Miyasaka, Reiko Ueda, Shin-ichiro Inoue, Akira Otomo
    • Organizer
      The 10th International Conference on Nano-Molecular Electronics (ICNME2012)
    • Place of Presentation
      Awaji Yumebutai International Conference Center, Hyogo
    • Related Report
      2012 Research-status Report
  • [Presentation] 2次元フォトニックバンドギャップによる単一分子の自然放出抑制2012

    • Author(s)
      梶貴博, 山田俊樹, 伊都将司, 宮坂博, 上田里永子, 井上振一郎, 大友明
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス、東京都
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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